Palladium-catalyzed reactions of organic halides with olefins

doi:10.1021/AR50136A006

Journal ArticleDOI

Palladium-catalyzed reactions of organic halides with olefins

Richard F. Heck

- 01 Apr 1979 -

Accounts of Chemical Research

- Vol. 10, Iss: 37, pp 146-151

About:

This article is published in Accounts of Chemical Research.The article was published on 1979-04-01. It has received 818 citations till now. The article focuses on the topics: Palladium.

Citations

PDF

Open Access

More filters

Journal ArticleDOI

Heck Reactions in Aqueous Miniemulsions

Hazit A. Zayas, +3 more

- 28 Sep 2012 -

Australian Journal of Chemistry

TL;DR: In this paper, a Heck cross-coupling reaction, one of the most used approaches to form C-C bonds using a palladium catalyst, in a miniemulsion was demonstrated.

...read moreread less

The medicinal chemistry of 2-aminotetralin-derived benzamides: a novel class of potential atypical antipsychotic agents

Evert Jan Homan

Journal ArticleDOI

Mechanistic Insights of a Selective C-H Alkylation of Alkenes by a Ru–based Catalyst and Alcohols

Albert Poater, +3 more

TL;DR: In this article, the authors investigated the whole reaction pathway using several computational DFT approaches including alternative pathways, higher in energy, and showed that the upper barrier of the catalytic cycle can be observed in the presence of a cationic Ru-alkenyl species, which is initially formed from two equivalents of the olefin substrate via vinylic C−H activation and an alkane elimination step.

...read moreread less

Patent

Preparation of 4-substituted aryl olefins.

Kevin J. Edgar

TL;DR: In this article, the authors described a process for the preparation of 4-substituted aryl olefins from 4 -substitized aryls iodides in an ester solvent.

...read moreread less

OtherDOI