Journal ArticleDOI
Palladium-catalyzed reactions of organic halides with olefins
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This article is published in Accounts of Chemical Research.The article was published on 1979-04-01. It has received 818 citations till now. The article focuses on the topics: Palladium.read more
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2-(1-Aryliminoethyl)cycloheptapyridylpalladium complexes: Synthesis, characterization and the use in the Heck-reaction
TL;DR: A series of 2-acetylcycloheptapyridine derivatives (L1-L7) were prepared in good yield by the condensation reaction of 2]-cyclohexylcyclopyridine with various anilines, and then reacted with PdCl2(CH3CN)2 in dichloromethane to form the respective palladium(II) complexes (C1-C7) as mentioned in this paper.
Journal ArticleDOI
Reversible Insertion of Unactivated Alkenes into Silicon(II)–Tin Bonds
Ricardo Rodríguez,Yohan Contie,David Gau,Nathalie Saffon-Merceron,Karinne Miqueu,Jean-Marc Sotiropoulos,Antoine Baceiredo,Tsuyoshi Kato +7 more
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Bis(carboxylato) complexes of platinum(II). Structural and bonding analysis of [Pt(O2CR)2(L–L)][L–L = 2PPh3, Ph2PCH2PPh2 or Fe(C5H4PPh2)2; R = Me, CF3, Pri or Ph]
Agnes L. Tan,Pauline M. N. Low,Zhongyuan Zhou,Weiming Zheng,Bo-Mu Wu,Thomas C. W. Mak,T. S. Andy Hor +6 more
TL;DR: In this article, the crystal and molecular structures of [PtCl2(L-L)][L−L = 2 PPh3, Ph2PCH2PPh2(dppm) or Fe(C5H4PPh 2)2 (dppf)] with Ag(O2CR)(R = Me, CF3, Pri or Ph) at room temperature were determined by single-crystal X-ray diffractometry.
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Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides.
Sangita Karanjit,Atchaleeya Jinasan,Ekasith Samsook,Raghu Nath Dhital,Kenichi Motomiya,Yoshinori Sato,Yoshinori Sato,Kazuyuki Tohji,Hidehiro Sakurai +8 more
TL;DR: The stabilization effect of Au towards Pd changed the reactivity of Pd in Au/Pd bimetallic nanoclusters, altering the reaction mechanism from homogeneous to heterogeneous in dechlorination reaction of aryl chlorides.
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Synthesis of E-Alkyl Alkenes from Terminal Alkynes via Ni-Catalyzed Cross-Coupling of Alkyl Halides with B-Alkenyl-9-borabicyclo[3.3.1]nonanes.
TL;DR: The first Ni-catalyzed Suzuki-Miyaura coupling of alkyl halides with alkenyl-(9-BBN) reagents is reported, allowing the expedited synthesis of functionalizedAlkyl alkenes from readily available alkynes with complete (E)-selectivity in one pot.
References
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Journal ArticleDOI
Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides
Richard F. Heck,J. P. Nolley +1 more
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Arylation of Olefin with Aryl Iodide Catalyzed by Palladium
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Gas-phase reactions of organic anions as studied by the flowing afterglow technique
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