Journal ArticleDOI
Palladium-catalyzed reactions of organic halides with olefins
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This article is published in Accounts of Chemical Research.The article was published on 1979-04-01. It has received 818 citations till now. The article focuses on the topics: Palladium.read more
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En route to metal-mediated and metal-catalysed reactions in water
Feng Zhou,Chao-Jun Li +1 more
TL;DR: This perspective report presents the key approaches for the development of various organometallic reactions in aqueous media.
Journal ArticleDOI
A regioselectivity switch in Pd-catalyzed hydroallylation of alkynes.
Ding-Wei Ji,Ding-Wei Ji,Yancheng Hu,Hao Zheng,Hao Zheng,Chao-Yang Zhao,Chao-Yang Zhao,Qing-An Chen,Vy M. Dong +8 more
TL;DR: Through rational evaluation of ligands and promoters, the reactivity of a key Pd(ii) species towards transmetalation or β-H elimination is manipulated.
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An efficient palladium catalyzed Mizoroki–Heck cross-coupling in water
TL;DR: In this paper, the homogeneous Pd-catalysed Mizoroki-Heck coupling reaction was successfully performed in water in the absence of any additives under aerobic conditions, and various key reaction parameters that affect the yield of the desired cross-coupling product were optimized.
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Computational Studies of the Relative Rates for Migratory Insertions of Alkenes into Square-Planar, Methyl, −Amido, and −Hydroxo Complexes of Rhodium
Jesse W. Tye,John F. Hartwig +1 more
TL;DR: Application of Bader's atoms-in-molecules analysis and natural localized molecular orbital analysis implies that the barriers for alkene insertion into M-X bonds are controlled by the degree of M- X bonding in the transition state, which correlates with the degree in the initial product.
Journal ArticleDOI
The coordination chemistry of acrylonitrile
TL;DR: In this article, the structure and possible modes of coordination of acrylonitrile adducts are discussed, including the type (a) complexes, bonded through the nitrile nitrogen and type (b) and (c) complexes containing bridging Iigands: the molybdenum(0) complex Mo,(CO),(PBu,),(~-CH,CHCN), and the copper(I) complex Cu,Cl,(Ir-CH-CHCN)Ni[P(OR],
References
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Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides
Richard F. Heck,J. P. Nolley +1 more
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Arylation of Olefin with Aryl Iodide Catalyzed by Palladium
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Gas-phase reactions of organic anions as studied by the flowing afterglow technique
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