Journal ArticleDOI
Palladium-catalyzed reactions of organic halides with olefins
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This article is published in Accounts of Chemical Research.The article was published on 1979-04-01. It has received 818 citations till now. The article focuses on the topics: Palladium.read more
Citations
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Recent Advances of Catalytic Enantioselective Heck Reactions and Reductive-Heck Reactions
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Cobalt-Catalyzed C(sp2)–H Allylation of Biphenyl Amines with Unbiased Terminal Olefins
Alessio Baccalini,Stefania Vergura,Pravas Dolui,Siddhartha Maiti,Subhabrata Dutta,Soham Maity,Farheen Fatima Khan,Goutam Kumar Lahiri,Giuseppe Zanoni,Debabrata Maiti +9 more
TL;DR: A C-H functionalization protocol of aromatic amines with unactivated olefins with exclusive allylic selectivity for the distal ring of the biphenyl system by exploiting a readily available cobalt(II) catalyst is disclosed.
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Palladium(0)-Catalyzed Tandem Cyclization of Allenenes: Direct Construction of Tricyclic Heterocycles through Aromatic C ? H Activation
Hiroaki Ohno,Kumiko Miyamura,Tsuyoshi Mizutani,Yoichi Kadoh,Yusuke Takeoka,Hisao Hamaguchi,Tetsuaki Tanaka +6 more
TL;DR: The substituent on the olefin terminus has proven to be essential for the success of the tandem cyclization and the reaction with heterocyclic aryl halides afforded tri- or tetracyclic heteroaromatic products in good yields.
Journal ArticleDOI
Iminopyridyl-palladium dendritic catalyst precursors: evaluation in Heck reactions
TL;DR: In this article, a poly(propyleneimine)-iminopyridyl-palladium dendrimers, bearing palladium moieties on the periphery, were found to be effective catalyst precursors for Heck coupling.
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Pd-PEPPSI Complexes Bearing Bulky [(1,2-Di-(tert-butyl)acenaphthyl] (DtBu-An) on N-Heterocarbene Backbones: Highly Efficient for Suzuki–Miyaura Cross-Coupling under Aerobic Conditions
TL;DR: The Pd-PEPPSI complexes C1 and C2 bearing 1,2-di(tert-butyl)acenaphthyl (DtBu-An) backbones were synthesized and characterized, and their use in Suzuki–Miyaura cross-coupling was investigated.
References
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Journal ArticleDOI
Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides
Richard F. Heck,J. P. Nolley +1 more
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Arylation of Olefin with Aryl Iodide Catalyzed by Palladium
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Gas-phase reactions of organic anions as studied by the flowing afterglow technique
Related Papers (5)
The heck reaction as a sharpening stone of palladium catalysis.
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