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Journal ArticleDOI

Palladium-catalyzed reactions of organic halides with olefins

Richard F. Heck
- 01 Apr 1979 - 
- Vol. 10, Iss: 37, pp 146-151
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This article is published in Accounts of Chemical Research.The article was published on 1979-04-01. It has received 818 citations till now. The article focuses on the topics: Palladium.

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Mechanism of the Reaction of Vinyl Chloride with (α-diimine)PdMe+ Species

TL;DR: The computational results and the observation of small amounts of propene-d2 argue against mechanisms involving 2,1-insertion followed by α-Cl elimination and a 1,2 H-shift.
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Sulfur extrusion with tin radical: synthesis of 4',5'-didehydro-5'-deoxy-5'-(tributylstannyl)adenosine, an intermediate for potential inhibitors against S-adenosyl homocysteine hydrolase.

TL;DR: Various types of carbon substituents were introduced to the 5'-position of the 5-deoxy-beta-d-erythro-pent-4-enofuranosyl structure to open up a new route to potential inhibitors of AdoHcy hydrolase.
Journal ArticleDOI

Theoretical study on the leaching of palladium in a CO atmosphere

TL;DR: In this article, the authors studied computationally the leaching of palladium from the ideal surface Pd(111) and its various structural defects at different coverages of CO, using density functional calculations on slab models.
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