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Journal ArticleDOI

Palladium-catalyzed reactions of organic halides with olefins

Richard F. Heck
- 01 Apr 1979 - 
- Vol. 10, Iss: 37, pp 146-151
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This article is published in Accounts of Chemical Research.The article was published on 1979-04-01. It has received 818 citations till now. The article focuses on the topics: Palladium.

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Journal ArticleDOI

Reactivity of palladium olefin complexes with heteroditopic NHC–pyridine as spectator ligand toward olefin exchange

TL;DR: In this paper, the pyridine wing of the (1-methyl-3-((6-methylpyridine-2-yl)methyl)-imidazole) (Me- NHC -CH 2 -Py) moiety was used as a spectator ligand in Pd(0) complexes stabilized by deactivated olefins.
Journal ArticleDOI

Gold-Catalyzed Heck Reaction.

TL;DR: In this paper , a gold-catalyzed Heck reaction facilitated by the ligand-enabled Au(I)/Au(III) redox catalysis was reported, where the elementary organometallic steps such as migratory insertion and β-hydride elimination were realized in the catalytic fashion for the first time in gold chemistry.
Journal ArticleDOI

Stereoselective homogeneous catalytic arylation of methyl methacrylate: Experimental and computational study

TL;DR: In this article, the authors investigated mechanistic aspects of migratory insertion, β-hydride elimination and reductive elimination of this phosphine-free Heck reaction, which is in agreement with their experimental findings.
Book ChapterDOI

Polymerase Synthesis of Base-Modified DNA

TL;DR: The methods of polymerase synthesis include primer extension, PCR, nicking enzyme amplifications, and other methods which enable the synthesis of diverse types of long or short and double-stranded DNA or single-Stranded oligonucleotides.
Journal ArticleDOI

Polymer‐supported palladium: A hybrid system for multifunctional catalytic application

TL;DR: In this paper, a polymer-supported palladium was synthesized by applying a single-step wet chemical synthesis route and the resultant composite material was characterized by means of various techniques.
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