Journal ArticleDOI
Palladium-catalyzed reactions of organic halides with olefins
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This article is published in Accounts of Chemical Research.The article was published on 1979-04-01. It has received 818 citations till now. The article focuses on the topics: Palladium.read more
Citations
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Reactivity of palladium olefin complexes with heteroditopic NHC–pyridine as spectator ligand toward olefin exchange
TL;DR: In this paper, the pyridine wing of the (1-methyl-3-((6-methylpyridine-2-yl)methyl)-imidazole) (Me- NHC -CH 2 -Py) moiety was used as a spectator ligand in Pd(0) complexes stabilized by deactivated olefins.
Journal ArticleDOI
Gold-Catalyzed Heck Reaction.
TL;DR: In this paper , a gold-catalyzed Heck reaction facilitated by the ligand-enabled Au(I)/Au(III) redox catalysis was reported, where the elementary organometallic steps such as migratory insertion and β-hydride elimination were realized in the catalytic fashion for the first time in gold chemistry.
Journal ArticleDOI
Stereoselective homogeneous catalytic arylation of methyl methacrylate: Experimental and computational study
TL;DR: In this article, the authors investigated mechanistic aspects of migratory insertion, β-hydride elimination and reductive elimination of this phosphine-free Heck reaction, which is in agreement with their experimental findings.
Book ChapterDOI
Polymerase Synthesis of Base-Modified DNA
TL;DR: The methods of polymerase synthesis include primer extension, PCR, nicking enzyme amplifications, and other methods which enable the synthesis of diverse types of long or short and double-stranded DNA or single-Stranded oligonucleotides.
Journal ArticleDOI
Polymer‐supported palladium: A hybrid system for multifunctional catalytic application
TL;DR: In this paper, a polymer-supported palladium was synthesized by applying a single-step wet chemical synthesis route and the resultant composite material was characterized by means of various techniques.
References
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Journal ArticleDOI
Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides
Richard F. Heck,J. P. Nolley +1 more
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Arylation of Olefin with Aryl Iodide Catalyzed by Palladium
Journal ArticleDOI
Gas-phase reactions of organic anions as studied by the flowing afterglow technique
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The heck reaction as a sharpening stone of palladium catalysis.
Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides
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