Journal ArticleDOI
Palladium-catalyzed reactions of organic halides with olefins
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This article is published in Accounts of Chemical Research.The article was published on 1979-04-01. It has received 818 citations till now. The article focuses on the topics: Palladium.read more
Citations
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Low valent palladium benzoquinone complexes bearing different spectator ligands. The versatile coordinative capability of benzoquinone
TL;DR: In this article, the hapticity of benzoquinone palladium complexes was inferred from the features of their 1 H and 13 C NMR spectra, and it was shown that the coordinative choice is not easily predictable, although the η 2 coordination seems to be predominant in the presence of rigid ancillary ligands.
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Intermediate ion stability and regioselectivity in propene polymerization using neutral salicyladiminato nickel(II) and palladium(II) complexes as catalysts
TL;DR: In this paper, the Heck reaction has been studied with regard to transition metal catalysis of the addition of propene and the formation of unsaturated polymers, and it is shown that whether the initial addition is trans to O or to N of the bidentate ligand is of crucial importance to the subsequent reactions.
Journal ArticleDOI
A new polymerization reaction : Synthesis of soluble polyketones and poly(arylenevinylene)s
Dekun Wang,Peng Wei,Zhe Wu +2 more
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A highly efficient and recyclable fluorous palladium catalyst for Heck reactions in water
TL;DR: In this article, a fluorous nano-palladium catalyst has been synthesized and characterized for the Heck reaction of aryl halides with substituted styrenes in water under air.
Journal ArticleDOI
Palladium‐catalyzed Heck coupling of 2‐vinylpyridine with aryl chlorides
Ming Li,Ruimao Hua +1 more
TL;DR: An efficient PdCl2(PCy3)2-catalyzed cross-coupling reaction of 2-vinylpyridine with aryl chlorides to afford trans-2-styrylpyridines with a variety of functional groups on the benzene ring is described in this article.
References
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Journal ArticleDOI
Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides
Richard F. Heck,J. P. Nolley +1 more
Journal ArticleDOI
Arylation of Olefin with Aryl Iodide Catalyzed by Palladium
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Gas-phase reactions of organic anions as studied by the flowing afterglow technique
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The heck reaction as a sharpening stone of palladium catalysis.
Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides
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