Journal ArticleDOI
Palladium-catalyzed reactions of organic halides with olefins
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This article is published in Accounts of Chemical Research.The article was published on 1979-04-01. It has received 818 citations till now. The article focuses on the topics: Palladium.read more
Citations
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Development of new methods in modern selective organic synthesis: preparation of functionalized molecules with atomic precision
Valentine P. Ananikov,Valentine P. Ananikov,Levon L. Khemchyan,Yu. V. Ivanova,Valerii I. Bukhtiyarov,Valerii I. Bukhtiyarov,A. M. Sorokin,Igor P. Prosvirin,Sergey Z. Vatsadze,Aleksei V. Medved’ko,V. N. Nuriev,Alexander D. Dilman,Vitalij V. Levin,Igor V. Koptyug,Igor V. Koptyug,Kirill V. Kovtunov,Kirill V. Kovtunov,Vladimir V. Zhivonitko,Vladimir V. Zhivonitko,Vladimir A. Likholobov,A. V. Romanenko,P. A. Simonov,P. A. Simonov,Valentine G. Nenajdenko,Valentine G. Nenajdenko,Olga I. Shmatova,Vasily M. Muzalevskiy,Mikhail S. Nechaev,Mikhail S. Nechaev,Andrey F. Asachenko,Oleg S. Morozov,Pavel B. Dzhevakov,Sergey N. Osipov,Daria V. Vorobyeva,Maxim A. Topchiy,Maria A. Zotova,Sergei A. Ponomarenko,Sergei A. Ponomarenko,Oleg V. Borshchev,Y.N. Luponosov,Andrey A. Rempel,Andrey A. Rempel,Albina A. Valeeva,Albina A. Valeeva,A. Yu. Stakheev,O. V. Turova,Igor S. Mashkovsky,S. V. Sysolyatin,V. V. Malykhin,Galina A. Bukhtiyarova,Alexander O. Terent'ev,Igor B. Krylov +51 more
TL;DR: The state-of-the-art achievements in selective organic synthesis indicate the appearance of a new trend of organic molecules, biologically active compounds, pharmaceutical substances and smart materials with absolute selectivity as discussed by the authors.
Journal ArticleDOI
Brønsted–Lowry Acid Strength of Metal Hydride and Dihydrogen Complexes
TL;DR: A simple additive ligand acidity constant equation (LAC for short) allows the estimation of the acid dissociation constant Ka(LAC) of diamagnetic transition metal hydride and dihydrogen complexes, which is remarkably successful in systematizing diverse reports of over 450 reactions of acids with metal complexes and bases.
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Structural and mechanistic studies of Pd-catalyzed CC bond formation: The case of carbonylation and Heck reaction
TL;DR: In this paper, the extraordinary catalytic activity of palladium in C C bond forming processes is reviewed in respect to Heck and carbonylation reactions and examples of catalytic systems based on palladium complexes with phosphorus ligands and phosphine-free systems and based on the Pd(0) colloid are presented.
Journal ArticleDOI
Mechanism, Reactivity, and Selectivity in Palladium-Catalyzed Redox-Relay Heck Arylations of Alkenyl Alcohols
Li-Ping Xu,Margaret J. Hilton,Xinhao Zhang,Per-Ola Norrby,Per-Ola Norrby,Yun-Dong Wu,Matthew S. Sigman,Olaf Wiest,Olaf Wiest +8 more
TL;DR: The enantioselective Pd-catalyzed redox-relay Heck arylation of acyclic alkenyl alcohols allows access to various useful chiral building blocks from simple olefinic substrates by investigating the reaction mechanism, including the relay function, yielding the final carbonyl group transformation.
References
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Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides
Richard F. Heck,J. P. Nolley +1 more
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Arylation of Olefin with Aryl Iodide Catalyzed by Palladium
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Gas-phase reactions of organic anions as studied by the flowing afterglow technique
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