Palladium-catalyzed reactions of organic halides with olefins

doi:10.1021/AR50136A006

Journal ArticleDOI

Palladium-catalyzed reactions of organic halides with olefins

Richard F. Heck

- 01 Apr 1979 -

Accounts of Chemical Research

- Vol. 10, Iss: 37, pp 146-151

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This article is published in Accounts of Chemical Research.The article was published on 1979-04-01. It has received 818 citations till now. The article focuses on the topics: Palladium.

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Palladium-Catalyzed Cascade Carbonylation to α,β-Unsaturated Piperidones via Selective Cleavage of Carbon-Carbon Triple Bonds.

Yao Ge, +7 more

- 04 Oct 2021 -

Angewandte Chemie

TL;DR: In this article, a direct and selective synthesis of α,β-unsaturated piperidones by a new palladium-catalyzed cascade carbonylation is described, where easily available propargylic alcohols react with aliphatic amines to provide a broad variety of interesting heterocycles.

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Reference EntryDOI

Palladium‐ or Nickel‐Catalyzed Cross‐Coupling Reactions with Organozincs and Related Organometals

Ei-ichi Negishi, +4 more

- 15 Dec 2009 -

Patai's Chemistry of Functional Groups

TL;DR: The Pd- or Ni-Catalyzed Cross-Coupling with Organometals Containing Zn, Mg, Al and Zr was discussed in this paper.

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Journal ArticleDOI

Synthesis, characterization and first application of chiral C2‐symmetric bis(phosphinite)–Pd(II) complexes as catalysts in asymmetric intermolecular Heck reactions

Duygu Elma Karakaş, +4 more

- 01 Apr 2016 -

Applied Organometallic Chemistry

TL;DR: In this paper, a series of chiral C2-symmetric bis(phosphinite) ligands and their palladium(II) complexes have been synthesized and for the first time used as catalysts in the palladium-catalysed asymmetric intermolecular Heck coupling reactions of 2,3-dihydrofuran with iodobenzene or aryl triflate.

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Neue polymere Werkstoffe für ophthalmologische Implantate: Photoinduzierte Brechungsindexänderung und hochbrechende konkomitierend UV absorbierende Chromophore

Martin Schraub

TL;DR: In this paper, the authors have shown that polymers containing coumarins, stilbenes, chalcones and chalcone derivatives can achieve a [2π+2π] dimerization reaction.

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Journal ArticleDOI

The mechanism of oxidative addition of Pd(0) to Si-H bonds: electronic effects, reaction mechanism, and hydrosilylation.

Michael R. Hurst, +2 more

- 13 Oct 2021 -

Chemical Science

TL;DR: In this paper, a systematic investigation of the formation of silyl palladium hydride complexes as a function of silane identity, focusing on electronic influence of the silanes is presented.

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