Journal ArticleDOI
Palladium-catalyzed reactions of organic halides with olefins
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This article is published in Accounts of Chemical Research.The article was published on 1979-04-01. It has received 818 citations till now. The article focuses on the topics: Palladium.read more
Citations
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Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms
Journal ArticleDOI
From Noble Metal to Nobel Prize: Palladium-Catalyzed Coupling Reactions as Key Methods in Organic Synthesis
TL;DR: The coupling protocol for aryl halides with olefins can be considered as a milestone for the development and application of organometallic catalysis in organic synthesis and set the stage for numerous further applications.
Journal ArticleDOI
The Controlled Display of Biomolecules on Nanoparticles: A Challenge Suited to Bioorthogonal Chemistry
W. Russ Algar,Duane E. Prasuhn,Michael H. Stewart,Travis L. Jennings,Juan B. Blanco-Canosa,Philip E. Dawson,Igor L. Medintz +6 more
TL;DR: This review includes a critical discussion on the design considerations for NP-bioconjugates and the unique challenges associated with chemistry at the biological-nanoscale interface-the liabilities of traditional bioconjugation chemistries being particularly prominent therein.
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C-H activation: a complementary tool in the total synthesis of complex natural products.
David Y.-K. Chen,So Won Youn +1 more
TL;DR: Recently completed total syntheses showcasing creative and ingenious incorporation of C-Hactivation as a strategic manoeuver are compared with their "non-C-H activation" counterparts, illuminating a new paradigm in strategic synthetic design.
References
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Journal ArticleDOI
Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides
Richard F. Heck,J. P. Nolley +1 more
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Arylation of Olefin with Aryl Iodide Catalyzed by Palladium
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Gas-phase reactions of organic anions as studied by the flowing afterglow technique
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