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Scalable Coating and Properties of Transparent, Flexible, Silver Nanowire

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TLDR
The overall properties of transparent Ag NW electrodes meet the requirements of transparent electrodes for many applications and could be an immediate ITO replacement for flexible electronics and solar cells.
Abstract
We report a comprehensive study of transparent and conductive silver nanowire (Ag NW) electrodes,includingascalablefabricationprocess,morphologies,andoptical,mechanicaladhesion,andflexibility properties, and various routes to improve the performance. We utilized a synthesis specifically designed for long andthinwiresforimprovedperformanceintermsofsheetresistanceandopticaltransmittance.Twenty/sqand 80% specular transmittance, and 8 ohms/sq and 80% diffusive transmittance in the visible range are achieved, whichfallinthesamerangeasthebestindiumtinoxide(ITO)samplesonplasticsubstratesforflexibleelectronics andsolarcells.TheAgNWelectrodesshowopticaltransparenciessuperiortoITOfornear-infraredwavelengths(2- foldhighertransmission).Owingtolightscatteringeffects,theAgNWnetworkhasthelargestdifferencebetween diffusive transmittance and specular transmittance when compared with ITO and carbon nanotube electrodes, a propertywhichcouldgreatlyenhancesolarcellperformance.AmechanicalstudyshowsthatAgNWelectrodeson flexiblesubstratesshowexcellentrobustnesswhensubjectedtobending.Wealsostudytheelectricalconductance ofAgnanowiresandtheirjunctionsandreportafacileelectrochemicalmethodforaAucoatingtoreducethewire- to-wire junction resistance for better overallfilm conductance. Simple mechanical pressing was also found to increasetheNWfilmconductanceduetothereductionofjunctionresistance.Theoverallpropertiesoftransparent Ag NW electrodes meet the requirements of transparent electrodes for many applications and could be an immediate ITO replacement forflexible electronics and solar cells.

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Citations
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Effect of RGO deposition on chemical and mechanical reliability of Ag nanowire flexible transparent electrode

TL;DR: In this paper, the role of reduced graphene oxide (RGO) in chemical stability and its effect on the mechanical reliability was studied for a Ag nanowire/RGO hybrid transparent electrode.
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Optimized ITO-free tri-layer electrode for organic solar cells

TL;DR: In this article, the optical properties of ZnO/Ag/ZnO (ZAZ) multilayer structures were numerically modeled and calculated by a FDTD method.
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Development of Hierarchical Polymer@Pd Nanowire-Network: Synthesis and Application as Highly Active Recyclable Catalyst and Printable Conductive Ink.

TL;DR: A facile one‐pot approach for preparing hierarchical nanowire‐networks of hollow polymer@Pd nanospheres is reported, and the catalyst can be recycled via simple filtration and washing, maintaining its high activity owing to the micrometer‐sized hierarchical structure of the nanomaterial.
Journal ArticleDOI

Nanoscale Chemical and Electrical Stabilities of Graphene-covered Silver Nanowire Networks for Transparent Conducting Electrodes

TL;DR: By transferring island Gr on top of the AgNW network, this work was able to create samples in which both covered and uncovered AgNWs are simultaneously accessible to various surface-characterization techniques, and the AIMD simulation elucidated the specific mechanistic pathway and a strong propensity for AgNW sulfidation, even in the presence of ambient oxidant gases.
Journal ArticleDOI

Seed concentration control of metal nanowire diameter.

TL;DR: Two types of metallic NW films were tested for their performance as transparent electrodes after additional metal deposition for their stabilization and conductivity enhancement, and the thin NW bundles exhibit superior transparent conductor properties.
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