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Scalable Coating and Properties of Transparent, Flexible, Silver Nanowire

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TLDR
The overall properties of transparent Ag NW electrodes meet the requirements of transparent electrodes for many applications and could be an immediate ITO replacement for flexible electronics and solar cells.
Abstract
We report a comprehensive study of transparent and conductive silver nanowire (Ag NW) electrodes,includingascalablefabricationprocess,morphologies,andoptical,mechanicaladhesion,andflexibility properties, and various routes to improve the performance. We utilized a synthesis specifically designed for long andthinwiresforimprovedperformanceintermsofsheetresistanceandopticaltransmittance.Twenty/sqand 80% specular transmittance, and 8 ohms/sq and 80% diffusive transmittance in the visible range are achieved, whichfallinthesamerangeasthebestindiumtinoxide(ITO)samplesonplasticsubstratesforflexibleelectronics andsolarcells.TheAgNWelectrodesshowopticaltransparenciessuperiortoITOfornear-infraredwavelengths(2- foldhighertransmission).Owingtolightscatteringeffects,theAgNWnetworkhasthelargestdifferencebetween diffusive transmittance and specular transmittance when compared with ITO and carbon nanotube electrodes, a propertywhichcouldgreatlyenhancesolarcellperformance.AmechanicalstudyshowsthatAgNWelectrodeson flexiblesubstratesshowexcellentrobustnesswhensubjectedtobending.Wealsostudytheelectricalconductance ofAgnanowiresandtheirjunctionsandreportafacileelectrochemicalmethodforaAucoatingtoreducethewire- to-wire junction resistance for better overallfilm conductance. Simple mechanical pressing was also found to increasetheNWfilmconductanceduetothereductionofjunctionresistance.Theoverallpropertiesoftransparent Ag NW electrodes meet the requirements of transparent electrodes for many applications and could be an immediate ITO replacement forflexible electronics and solar cells.

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Citations
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Effect of varying the density of Ag nanowire networks on their reliability during bending fatigue

TL;DR: In this article, the effect of varying the density of Ag nanowire networks on their reliability was explored during cyclic bending and it was shown that the reliability of the Ag network degraded as the densities of nanowires decreased, which is in contrast to E-beam evaporated dense Cu thin films.
Journal ArticleDOI

Synthesis of ultrathin semicircle-shaped copper nanowires in ethanol solution for low haze flexible transparent conductors

TL;DR: In this article, ultrathin semicircle-shaped copper nanowires (SCuNWs) with a diameter of ∼ 15 nm and a length of ∼ 30 μm (aspect ratio of ∼ 2,000) were synthesized in ethanol solution.
Journal ArticleDOI

Fabrication of a transparent conducting electrode based on graphene/silver nanowires via layer-by-layer method for organic photovoltaic devices.

TL;DR: A solution-processed transparent conducting electrode was fabricated via layer-by-layer (LBL) deposition of graphene oxide (GO) and silver nanowires (Ag NWs) and provided highly controllable thin films in terms of optical transmittance and sheet resistance.
Journal ArticleDOI

Versatility of bilayer metal oxide coatings on silver nanowire networks for enhanced stability with minimal transparency loss

TL;DR: It is demonstrated that by depositing a second oxide coating, which acts as an antireflective layer, it is possible to obtain highly stable and transparent composite electrodes, which are compatible with high-throughput scalable fabrication.
Journal ArticleDOI

Preparation of Aluminum Nanomesh Thin Films from an Anodic Aluminum Oxide Template as Transparent Conductive Electrodes

TL;DR: The results demonstrate that the proposed strategy can serve as a potential method to fabricate low-cost TCEs to replace conventional indium tin oxide materials.
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