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Scalable Coating and Properties of Transparent, Flexible, Silver Nanowire

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TLDR
The overall properties of transparent Ag NW electrodes meet the requirements of transparent electrodes for many applications and could be an immediate ITO replacement for flexible electronics and solar cells.
Abstract
We report a comprehensive study of transparent and conductive silver nanowire (Ag NW) electrodes,includingascalablefabricationprocess,morphologies,andoptical,mechanicaladhesion,andflexibility properties, and various routes to improve the performance. We utilized a synthesis specifically designed for long andthinwiresforimprovedperformanceintermsofsheetresistanceandopticaltransmittance.Twenty/sqand 80% specular transmittance, and 8 ohms/sq and 80% diffusive transmittance in the visible range are achieved, whichfallinthesamerangeasthebestindiumtinoxide(ITO)samplesonplasticsubstratesforflexibleelectronics andsolarcells.TheAgNWelectrodesshowopticaltransparenciessuperiortoITOfornear-infraredwavelengths(2- foldhighertransmission).Owingtolightscatteringeffects,theAgNWnetworkhasthelargestdifferencebetween diffusive transmittance and specular transmittance when compared with ITO and carbon nanotube electrodes, a propertywhichcouldgreatlyenhancesolarcellperformance.AmechanicalstudyshowsthatAgNWelectrodeson flexiblesubstratesshowexcellentrobustnesswhensubjectedtobending.Wealsostudytheelectricalconductance ofAgnanowiresandtheirjunctionsandreportafacileelectrochemicalmethodforaAucoatingtoreducethewire- to-wire junction resistance for better overallfilm conductance. Simple mechanical pressing was also found to increasetheNWfilmconductanceduetothereductionofjunctionresistance.Theoverallpropertiesoftransparent Ag NW electrodes meet the requirements of transparent electrodes for many applications and could be an immediate ITO replacement forflexible electronics and solar cells.

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Citations
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Quantitative determination of fragmentation kinetics and thermodynamics of colloidal silver nanowires by in situ high-energy synchrotron X-ray diffraction

TL;DR: In this article, a real-time analysis of the in situ measurements provides quantitative understanding of kinetics and thermodynamics involved in the fragmentation of the colloidal silver nanowires, as well as an in situ technique based on time-resolved high-energy synchrotron X-ray diffraction.
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Structure–property relationship of assembled nanowire materials

TL;DR: In this article, the structure-property relationship of assembled nanowire materials compared with the disordered NW statement is comprehensively reviewed and the programmability of ordered assemblies with predictable architectures for large-scale devices is also briefly commented on.
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Effect of AlOx protection layer on AgNWs for flexible transparent heater.

TL;DR: The AlOx covered Ag nanowire film is a promising candidate for the application of the flexible transparent heaters and it is demonstrated that the thin AlOx layer leads to increased contact area at the junction ofAg nanowires, which contributes to lower sheet resistance and improved adhesion of Ag Nanowires.
Journal ArticleDOI

Orthogonally weaved silver nanowire networks for very efficient organic optoelectronic devices

TL;DR: In this paper, the authors demonstrate a simple but effective method to control the orientation of silver nanowires (AgNWs) by judiciously controlling the process parameters in the bar-coating method.
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Femtosecond laser-induced non-thermal welding for a single Cu nanowire glucose sensor

TL;DR: In this paper, a femtosecond (FS) and continuous-wave (CW) laser welding of single copper nanowires to a silver film using a tightly focused laser beam combined with manipulation of CuNWs through the dielectrophoresis (DEP) method was reported.
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