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Scalable Coating and Properties of Transparent, Flexible, Silver Nanowire

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TLDR
The overall properties of transparent Ag NW electrodes meet the requirements of transparent electrodes for many applications and could be an immediate ITO replacement for flexible electronics and solar cells.
Abstract
We report a comprehensive study of transparent and conductive silver nanowire (Ag NW) electrodes,includingascalablefabricationprocess,morphologies,andoptical,mechanicaladhesion,andflexibility properties, and various routes to improve the performance. We utilized a synthesis specifically designed for long andthinwiresforimprovedperformanceintermsofsheetresistanceandopticaltransmittance.Twenty/sqand 80% specular transmittance, and 8 ohms/sq and 80% diffusive transmittance in the visible range are achieved, whichfallinthesamerangeasthebestindiumtinoxide(ITO)samplesonplasticsubstratesforflexibleelectronics andsolarcells.TheAgNWelectrodesshowopticaltransparenciessuperiortoITOfornear-infraredwavelengths(2- foldhighertransmission).Owingtolightscatteringeffects,theAgNWnetworkhasthelargestdifferencebetween diffusive transmittance and specular transmittance when compared with ITO and carbon nanotube electrodes, a propertywhichcouldgreatlyenhancesolarcellperformance.AmechanicalstudyshowsthatAgNWelectrodeson flexiblesubstratesshowexcellentrobustnesswhensubjectedtobending.Wealsostudytheelectricalconductance ofAgnanowiresandtheirjunctionsandreportafacileelectrochemicalmethodforaAucoatingtoreducethewire- to-wire junction resistance for better overallfilm conductance. Simple mechanical pressing was also found to increasetheNWfilmconductanceduetothereductionofjunctionresistance.Theoverallpropertiesoftransparent Ag NW electrodes meet the requirements of transparent electrodes for many applications and could be an immediate ITO replacement forflexible electronics and solar cells.

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Citations
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Floating compression of Ag nanowire networks for effective strain release of stretchable transparent electrodes

TL;DR: It is demonstrated that floating a AgNW network on water and subsequent in-plane compression allows convenient development of a wavy configuration in the Ag NW network, which can release the applied strain.
Journal ArticleDOI

Transparent Conductive Dielectric-Metal-Dielectric Structures for Electrochromic Applications Fabricated by High-Power Impulse Magnetron Sputtering.

TL;DR: It is demonstrated for the first time that a new method, known as high-power impulse magnetron sputtering (HiPIMS), can produce trilayer bifunctional EC and TC devices, eliminating the need for the additional protective layer.
Journal ArticleDOI

Self-assembled large scale metal alloy grid patterns as flexible transparent conductive layers

TL;DR: This work pioneers the scalable synthesis of transparent conductive films (TCFs) by exploiting the coffee-ring effect deposition coupled with reactive inkjet printing and subsequent chemical copper plating and shows excellent adhesion and preserve their structural integrity and good contact with the substrate for severe bending.
Journal ArticleDOI

Effective passivation of Ag nanowire network by transparent tetrahedral amorphous carbon film for flexible and transparent thin film heaters

TL;DR: The developed effective passivation method of flexible Ag nanowire (NW) network electrodes using transparent tetrahedral amorphous carbon (ta-C) film prepared by filtered cathode vacuum arc (FCVA) coating effectively protect Ag NW network electrode and improved the ambient stability of AgNW network without change of sheet resistance of Ag NWnetwork.
Journal ArticleDOI

Synthesis of dimension-controlled silver nanowires for highly conductive and transparent nanowire films

TL;DR: In this paper, high-quality silver nanowires with specific dimensions were synthesized by a polyol method with detailed control of the synthesis conditions, and a modified percolation model, which emphasized the importance of the nanowire junction density was in good agreement with the experimental observations.
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