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The use of conductivity measurements in organic solvents for the characterisation of coordination compounds

W.J. Geary
- 01 Oct 1971 - 
- Vol. 7, Iss: 1, pp 81-122
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This article is published in Coordination Chemistry Reviews.The article was published on 1971-10-01. It has received 8264 citations till now. The article focuses on the topics: Coordination complex.

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Citations
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Spectroscopic and physicochemical studies on nickel(II) complexes of isatin-3,2′-quinolyl-hydrazones and their adducts

TL;DR: On the basis of spectral studies a four coordinated tetrahedral geometry is assigned for Ni(L)X type complexes whereas the adducts were found to have a six coordinated distorted octahedral geometry.
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Synthesis of a New Polydentate Ligand Obtained by Coupling 2,6-Bis(imino)pyridine and (Imino)pyridine Moieties and Its Use in Ethylene Oligomerization in Conjunction with Iron(II) and Cobalt(II) Bis-halides

TL;DR: In this article, the synthesis, characterization, and coordinating properties of a new potentially pentadentate nitrogen ligand, CyAr2N5, that combines in the same molecular structure 2,6-bis(imino)pyridine and (imino pyridine moieties, was described.
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Synthesis and characterization of Mixed‐Ligand Complexes of Cu(II), Ni(II), Co(II), Zn(II), Sm(III), and U(VI)O2, with a Schiff Base Derived from the Sulfa Drug Sulfamerazine and 2,2′‐Bipyridine

TL;DR: In this paper, a new series of mixed-ligand complexes with the Schiff base derived from salicylaldehyde and the sulfa drug sulfamerazine have been synthesized and characterized by IR, NMR, diffuse reflectance spectra and magnetic, thermal, and molar conductance measurements.
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Synthesis, spectral characterization and crystal structure of copper(II) complexes of 2-benzoylpyridine-N(4)-phenylsemicarbazone

TL;DR: In this article, a series of nine new copper(II) complexes [Cu2L2(OAc)2]� H2O( 1), [CuLNCS]� ½H2 O( 2), [CNO3]� CuLNO3], [CNHS]µ, µ, 1.
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[Pt]2Pb Trinuclear Systems: Impact of the Anionic Platinum Fragment on the Lead Environment and Photoluminescence†

TL;DR: The photoluminescence (PL) studies of all 1- 5 complexes revealed a dependence of PL on the structure type and showed that the local environment of Pb (II) is highly sensitive to the nature of the anionic platinate(II) precursors.
References
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Metal complexes as ligands—IV [1,2,3]: Bi- and Tri- nuclear complexes derived from metal complexes of tetradentate salicylaldimines

TL;DR: In this paper, a series of bi-and tri-nuclear complexes formed by using the donor properties of the two cis-oxygen atoms in metal (M) complexes of tetradentate Shiff bases (TSB) derived from salicylaldehyde or o-hydroxyacetophenone are reported.
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The Donor Properties of Pyridine N-Oxide

TL;DR: The coordination chemistry of pyridine N-oxide with a variety of acceptors has been investigated in this article, where the new substances Co(ClO4)26L, Co(NO3)24L), CoCl23L and CoCl2LH20, NiClO 4H2O, NiBr26L and NiBr2L H2O have been isolated and characterized by molecular conductance measurements in non-aqueous solvents, magnetic susceptibility measurements, and infrared spectra.