Journal ArticleDOI
The use of conductivity measurements in organic solvents for the characterisation of coordination compounds
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This article is published in Coordination Chemistry Reviews.The article was published on 1971-10-01. It has received 8264 citations till now. The article focuses on the topics: Coordination complex.read more
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Ni(II), Pd(II) and Pt(II) complexes of (1H-1,2,4-triazole-3-ylimino)methyl]naphthalene-2-ol. Structural, spectroscopic, biological, cytotoxicity, antioxidant and DNA binding
TL;DR: The results obtained indicated that the Schiff base ligand is more effective than its metal complexes towards the tested cell line and the anticancer activity of the ligand was evaluated in liver carcinoma (HEPG2) cell line.
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Ligational behavior of thiosemicarbazone, semicarbazone and thiocarbohydrazone ligands towards VO(IV), Ce(III), Th(IV) and UO2(VI) ions: synthesis, structural characterization and biological studies.
TL;DR: The antibacterial and antifungal activities of these complexes were also tested against Rhizobium bacteria and Fusarium-Oxysporium fungus and the metal complexes of H(4)L(1) ligand showed a higher antibacterial effect than the free ligand while the other ligands showed aHigher effect than their metal complexes.
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Synthesis and Characterization of a Cu14 Hydride Cluster Supported by Neutral Donor Ligands
Thuy-Ai D. Nguyen,Bryan R. Goldsmith,Homaira T. Zaman,Guang Wu,Baron Peters,Trevor W. Hayton +5 more
TL;DR: The copper hydride clusters [Cu14 H12 (phen)6(PPh3)4][X]2 (X=Cl or OTf; OTf=trifluoromethanesulfonate, phen=1,10-phenanthroline) are obtained in good yields by the reaction of [(Ph3P)CuH]6 with phen, in the presence of a halide or pseudohalide source.
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Mononuclear and binuclear Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) complexes of schiff-base ligands derived from 7-formyl-8-hydroxyquinoline and diaminonaphthalenes
TL;DR: In this article, the structure of Schiff-base ligands derived from 7-formyl-8-hydroxyquinoline with diaminonaphthalenes was characterized by elemental and thermal analysis, conductance measurements and IR spectroscopy.
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Structure and properties of bivalent nickel and copper complexes with pyrazine-amide-thioether coordination: stabilization of trivalent nickel.
TL;DR: Compared to pyridine, pyrazine is a better stabilizer of the Ni(ii) or Cu(i) state according to a tetragonally elongated octahedral geometry.
References
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Five-Coordinated High-Spin Complexes of Bivalent Cobalt, Nickel, andCopper with Tris(2-dimethylaminoethyl)amine
M. Ciampolini,N. Nardi +1 more
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Metal complexes as ligands—IV [1,2,3]: Bi- and Tri- nuclear complexes derived from metal complexes of tetradentate salicylaldimines
TL;DR: In this paper, a series of bi-and tri-nuclear complexes formed by using the donor properties of the two cis-oxygen atoms in metal (M) complexes of tetradentate Shiff bases (TSB) derived from salicylaldehyde or o-hydroxyacetophenone are reported.
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The Preparation and Characterization of Four-Coordinate Complexes Related by Electron-Transfer Reactions
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The Donor Properties of Pyridine N-Oxide
TL;DR: The coordination chemistry of pyridine N-oxide with a variety of acceptors has been investigated in this article, where the new substances Co(ClO4)26L, Co(NO3)24L), CoCl23L and CoCl2LH20, NiClO 4H2O, NiBr26L and NiBr2L H2O have been isolated and characterized by molecular conductance measurements in non-aqueous solvents, magnetic susceptibility measurements, and infrared spectra.