Journal ArticleDOI
The use of conductivity measurements in organic solvents for the characterisation of coordination compounds
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This article is published in Coordination Chemistry Reviews.The article was published on 1971-10-01. It has received 8264 citations till now. The article focuses on the topics: Coordination complex.read more
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Synthesis, characterization, DFT and biological studies of isatinpicolinohydrazone and its Zn(II), Cd(II) and Hg(II) complexes.
TL;DR: In vitro antibacterial studies of the complexes proved them as growth inhibiting agents and the investigation revealed that H2IPH acts as binegative tetradentate in Zn(II), neutral tridentate in Cd( II) and as neutral bidentate towards Hg(II) complex.
Journal ArticleDOI
Diphosphine−Palladium and −Platinum Complexes as Catalysts for the Baeyer−Villiger Oxidation of Ketones: Effect of the Diphosphine, Oxidation of Acyclic Ketones, and Mechanistic Studies
TL;DR: A variety of Pd and Pt complexes of the type [(P−P)M(μ-OH)]22+ (M = Pd, Pt; P−P = a series of tetraphenyldiphosphines) were tested in the Baeyer−Villiger oxidation of ketones with hydrogen peroxide as mentioned in this paper.
Journal ArticleDOI
Novel homo- and hetero-nuclear copper(II) complexes of tetradentate Schiff bases: synthesis, characterization, solvent-extraction and catalase-like activity studies.
TL;DR: The homo- and hetero-nuclear copper(II) complexes were each tested for their ability to catalyse the disproportionation of hydrogen peroxide in the presence of the added base imidazole and showed strong binding ability toward copper( II) ion.
Journal ArticleDOI
Synthesis, magnetic and special studies of some novel metal complexes of Cu(II), Ni(II), Co(II), Zn[II), Nd(III), Th(IV), and UO2(VI) with schiff bases derived from sulfa drugs, viz., Sulfanilamide/Sulfamerazine and o-vanillin
R. C. Maurya,Pratibha Patel +1 more
TL;DR: In this article, two scruff base ligands viz ℴ-vanillin-sulfanilamide (ℴVSaH) and order vanillin sulfamerazine (VSmrzH), and their bipositive, tripositive tetrapositive and uranyl metal complexes were synthesized and characterized by elemental analysis, IR spectra, thermal analysis, magnetic suceptibility measurements, diffuse reflectance spectra and molar conductance measurements.
Journal ArticleDOI
Ship-in-a-bottle synthesis, characterization and catalytic oxidation of cyclohexane by Host (nanopores of zeolite-Y)/guest (Mn(II), Co(II), Ni(II) and Cu(II) complexes of bis(salicyaldehyde)oxaloyldihydrazone) nanocomposite materials
TL;DR: In this article, the monomer transition metal complexes, [ML] (Mn, Co, Ni, Ni and Cu), have been synthesized from the reaction of metal acetate with bis(salicyaldehyde)oxaloyldihydrazone, H 2 L; in 1:1 molar ratio in ethanol under reflux.
References
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Five-Coordinated High-Spin Complexes of Bivalent Cobalt, Nickel, andCopper with Tris(2-dimethylaminoethyl)amine
M. Ciampolini,N. Nardi +1 more
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Metal complexes as ligands—IV [1,2,3]: Bi- and Tri- nuclear complexes derived from metal complexes of tetradentate salicylaldimines
TL;DR: In this paper, a series of bi-and tri-nuclear complexes formed by using the donor properties of the two cis-oxygen atoms in metal (M) complexes of tetradentate Shiff bases (TSB) derived from salicylaldehyde or o-hydroxyacetophenone are reported.
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The Preparation and Characterization of Four-Coordinate Complexes Related by Electron-Transfer Reactions
Journal ArticleDOI
The Donor Properties of Pyridine N-Oxide
TL;DR: The coordination chemistry of pyridine N-oxide with a variety of acceptors has been investigated in this article, where the new substances Co(ClO4)26L, Co(NO3)24L), CoCl23L and CoCl2LH20, NiClO 4H2O, NiBr26L and NiBr2L H2O have been isolated and characterized by molecular conductance measurements in non-aqueous solvents, magnetic susceptibility measurements, and infrared spectra.