Journal ArticleDOI
The use of conductivity measurements in organic solvents for the characterisation of coordination compounds
About:
This article is published in Coordination Chemistry Reviews.The article was published on 1971-10-01. It has received 8264 citations till now. The article focuses on the topics: Coordination complex.read more
Citations
More filters
Journal ArticleDOI
The characterization of both the coordinated and non-coordinated saccharinate ion. The syntheses and crystal structures of aqua(2-formylpyridine thiosemicarbazonato)(saccharinato-N)copper(II) hemihydrate and 2,2′-bipyridyl-(2-formylpyridine thiosemicarbazonato)copper(II) saccharinate dihydrate
Eric W. Ainscough,Edward N. Baker,Andrew M. Brodie,Roger J. Cresswell,John D. Ranford,Joyce M. Waters +5 more
TL;DR: In this paper, the preparation of the complex [CuL(sacc)- (H2O)]·0.5H 2O (HL=2-formylpyridine thiosemicarbazone, Hsacc = saccharin) from the reaction of Na(Sacc) with [{cuL(CH3COO)}2] is described.
Journal ArticleDOI
In vivo anticancer, anti-inflammatory, and toxicity studies of mixed-ligand Cu(II) complexes of dien and its Schiff dibases with heterocyclic aldehydes and 2-amino-2-thiazoline. Crystal structure of [Cu(dien) (Br)(2a-2tzn)](Br)(H2O).
A.Th. Chaviara,Panayiotis C. Christidis,A. Papageorgiou,E. Chrysogelou,Dimitra Hadjipavlou-Litina,C.A. Bolos +5 more
TL;DR: Results regarding toxicity, antitumor, and anti-inflammatory activities of the investigated compounds are promising and allow the selection of a lead compound for further biological studies.
Journal ArticleDOI
Synthesis, characterization of 1,2,4-triazole Schiff base derived 3d-metal complexes: Induces cytotoxicity in HepG2, MCF-7 cell line, BSA binding fluorescence and DFT study.
TL;DR: Result indicates that metal complexes shows increase cytotoxicity in proliferation to cell lines as compared to free ligand.
Journal ArticleDOI
The Use of Conductivity Measurements for the Characterization of Cationic Palladium(II) Complexes and for the Determination of Kinetic and Thermodynamic Data in Palladium‐Catalyzed Reactions
TL;DR: In this article, conductivity measurements are used to characterize the cationic character of aryl-, vinyl-, hydrido-, and (η3-allyl)palladium(II) complexes generated by oxidative addition of triflates, carboxylates, and carbonates, respectively, with palladium(0) complexes in DMF.
Journal ArticleDOI
Heterometallic One-Dimensional Arrays Containing Cyanide-Bridged Lanthanide(III) and Transition Metals.
TL;DR: X-ray crystal structure determinations reveal that arrays 1, 2, and 3 consist of cyanide-bridged "diamond"-shaped Ln(2)Ni(2), metal cores linked together in an infinite array through cyanide bridges by [Ni(CN)(4)](2)(-) anions generating a single-strand chain.
References
More filters
Journal ArticleDOI
Five-Coordinated High-Spin Complexes of Bivalent Cobalt, Nickel, andCopper with Tris(2-dimethylaminoethyl)amine
M. Ciampolini,N. Nardi +1 more
Journal ArticleDOI
Metal complexes as ligands—IV [1,2,3]: Bi- and Tri- nuclear complexes derived from metal complexes of tetradentate salicylaldimines
TL;DR: In this paper, a series of bi-and tri-nuclear complexes formed by using the donor properties of the two cis-oxygen atoms in metal (M) complexes of tetradentate Shiff bases (TSB) derived from salicylaldehyde or o-hydroxyacetophenone are reported.
Journal ArticleDOI
The Preparation and Characterization of Four-Coordinate Complexes Related by Electron-Transfer Reactions
Journal ArticleDOI
The Donor Properties of Pyridine N-Oxide
TL;DR: The coordination chemistry of pyridine N-oxide with a variety of acceptors has been investigated in this article, where the new substances Co(ClO4)26L, Co(NO3)24L), CoCl23L and CoCl2LH20, NiClO 4H2O, NiBr26L and NiBr2L H2O have been isolated and characterized by molecular conductance measurements in non-aqueous solvents, magnetic susceptibility measurements, and infrared spectra.