Journal ArticleDOI
The use of conductivity measurements in organic solvents for the characterisation of coordination compounds
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This article is published in Coordination Chemistry Reviews.The article was published on 1971-10-01. It has received 8264 citations till now. The article focuses on the topics: Coordination complex.read more
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Synthesis, characterization and antiproliferative activity of metal complexes with the Schiff base derived from the condensation 1:2 of 2,6-diformyl-4-methylphenol and 5,6-diamino-1,3-dimethyluracil.
Nuria A. Illán-Cabeza,Francisco Hueso-Ureña,Miguel N. Moreno-Carretero,José Manuel Martínez-Martos,María Jesús Ramírez-Expósito +4 more
TL;DR: The antiproliferative behaviour against the five human tumor cell lines suggested a modulator behaviour, according to the concentration, of cell growth due to their estrogen-like characteristics.
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New water-soluble azido- and derived tetrazolato-platinum(II) complexes with PTA. Easy metal-mediated synthesis and isolation of 5-substituted tetrazoles.
Piotr Smoleński,Suman Mukhopadhyay,M. Fátima C. Guedes da Silva,M. Fátima C. Guedes da Silva,M. Adília Januário Charmier,M. Adília Januário Charmier,Armando J. L. Pombeiro +6 more
TL;DR: 5-R-1H-Tetrazoles N4CR were easily liberated from the tetrazolato complexes and isolated in high yields, in a single-pot process, upon reaction with aqueous diluted HCl, with concomitant formation of the water soluble cis-[Pt(Cl)2(PTA-H)2] complex 7.
Journal ArticleDOI
Diruthenium(ii,iii) metallodrugs of ibuprofen and naproxen encapsulated in intravenously injectable polymer-lipid nanoparticles exhibit enhanced activity against breast and prostate cancer cells.
Samara R. Alves Rico,Samara R. Alves Rico,Azhar Z. Abbasi,Geise Ribeiro,Taksim Ahmed,Xiao Yu Wu,Denise de Oliveira Silva +6 more
TL;DR: The enhanced anticancer activity of the metallodrug-loaded SPLNs in these cell lines can be associated with the advantages of the nanoformulations, assigned mainly to the stability of the colloidal nanoparticles suitable for i.v. injection and enhanced cellular uptake.
Journal ArticleDOI
The synthesis and characterization of α- and β-1, 1-diiodo-3,4-benzo-1-telluracyclopentane, C8H8Tel2
TL;DR: In this paper, two crystalline modifications of C8H8TeI2 have been isolated from 2-methoxyethanol, the yellow-orange or α form and the orange-red or β form.
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Subtle bite-angle influences on N(2)S(2)Ni complexes.
Jason J. Smee,Matthew L. Miller,Craig A. Grapperhaus,Joseph H. Reibenspies,Marcetta Y. Darensbourg +4 more
TL;DR: The electrochemical properties of the dithiolate complexes based on dach and daco are nearly identical, while the (propyl-bmedach)NiBr(2) complex shows a 140 mV destabilization of the Ni(I) oxidation state relative to its daco analogue.
References
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Five-Coordinated High-Spin Complexes of Bivalent Cobalt, Nickel, andCopper with Tris(2-dimethylaminoethyl)amine
M. Ciampolini,N. Nardi +1 more
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Metal complexes as ligands—IV [1,2,3]: Bi- and Tri- nuclear complexes derived from metal complexes of tetradentate salicylaldimines
TL;DR: In this paper, a series of bi-and tri-nuclear complexes formed by using the donor properties of the two cis-oxygen atoms in metal (M) complexes of tetradentate Shiff bases (TSB) derived from salicylaldehyde or o-hydroxyacetophenone are reported.
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The Preparation and Characterization of Four-Coordinate Complexes Related by Electron-Transfer Reactions
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The Donor Properties of Pyridine N-Oxide
TL;DR: The coordination chemistry of pyridine N-oxide with a variety of acceptors has been investigated in this article, where the new substances Co(ClO4)26L, Co(NO3)24L), CoCl23L and CoCl2LH20, NiClO 4H2O, NiBr26L and NiBr2L H2O have been isolated and characterized by molecular conductance measurements in non-aqueous solvents, magnetic susceptibility measurements, and infrared spectra.