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Journal ArticleDOI

The use of conductivity measurements in organic solvents for the characterisation of coordination compounds

W.J. Geary
- 01 Oct 1971 - 
- Vol. 7, Iss: 1, pp 81-122
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This article is published in Coordination Chemistry Reviews.The article was published on 1971-10-01. It has received 8264 citations till now. The article focuses on the topics: Coordination complex.

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Citations
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The unexpected formation of biologically active Cu(II) Schiff mono-base complexes with 2-thiophene-carboxaldehyde and dipropylenetriamine: crystal and molecular structure of CudptaSCl2.

TL;DR: It was shown that the Cu(II) Schiff mono-bases exhibit increased activity as compared to the starting materials and in vitro studies of plasmid DNA (pDNA) and double stranded DNA (dsDNA) interaction with the compounds under study support this difference.
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Synthesis and characterization of triazenide and triazene complexes of ruthenium and osmium.

TL;DR: Variable-temperature NMR studies were carried out using 15N-labeled triazene complexes prepared from the 1,3-Ph15N=N15N(H)Ph ligand and the X-ray crystal structure determination of the OsH(PhN=NH){PPh(OEt)2}4]BPh4 complex is reported.
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Synthesis, properties, and crystal structures of a series of dinuclear manganese(III) complexes with 1,5-bis(salicylideneamino)3-pentanol and various anions : formation of a tetranuclear manganese(III) complex

TL;DR: In this article, the molecular structures of 1−5, 7, and 8 were determined by the single-crystal X-ray structure analyses, and the spectral and magnetic properties were discussed in relation to the crystal structures.
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Chemosensors containing appended benzothiazole group(s): selective binding of Cu(2+) and Zn(2+) ions by two related receptors.

TL;DR: Amide-benzothiazole based receptors act as highly selective chemosensors for Cu(II) and Zn(ii) ions both in solution and in the solid state.
References
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Journal ArticleDOI

Metal complexes as ligands—IV [1,2,3]: Bi- and Tri- nuclear complexes derived from metal complexes of tetradentate salicylaldimines

TL;DR: In this paper, a series of bi-and tri-nuclear complexes formed by using the donor properties of the two cis-oxygen atoms in metal (M) complexes of tetradentate Shiff bases (TSB) derived from salicylaldehyde or o-hydroxyacetophenone are reported.
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The Donor Properties of Pyridine N-Oxide

TL;DR: The coordination chemistry of pyridine N-oxide with a variety of acceptors has been investigated in this article, where the new substances Co(ClO4)26L, Co(NO3)24L), CoCl23L and CoCl2LH20, NiClO 4H2O, NiBr26L and NiBr2L H2O have been isolated and characterized by molecular conductance measurements in non-aqueous solvents, magnetic susceptibility measurements, and infrared spectra.