Journal ArticleDOI
The use of conductivity measurements in organic solvents for the characterisation of coordination compounds
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This article is published in Coordination Chemistry Reviews.The article was published on 1971-10-01. It has received 8264 citations till now. The article focuses on the topics: Coordination complex.read more
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Gold(I) and Silver(I)/Gold(I) Complexes Derived from C6Me4(C⋮CH)2-1,2
TL;DR: C6Me4(C⋮CH)2-1,2 [Ar(C) 2] reacts with PPN[Au(acac)2] (acac = acetylacetonato, PPN = (Ph3P)2N) (2:1) or with [AuCl(SMe2)] and NEt3 (1:2:2):2] to give PPN(Au{C ⋮CArCC(c) 2 ]n (1) as discussed by the authors.
Journal ArticleDOI
Adducts of titanium tetrahalides with neutral Lewis bases. Part I. Structure and stability: a vibrational and multinuclear NMR study
TL;DR: In this article, Ramaman, infra-red and multinuclear NMR spectroscopy were used to establish the structure of several TiX 4 ·2L adducts (X=F, Cl, Br; L=Lewis base) in inert solvents.
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Synthesis, structure and magnetic properties of a new chloro-bridged dimeric copper complex, bis(μ-chloro)bis(8-amino-5-aza-4-methyl-3-octene-2-onato)dicopper(II)
Edmund Kwiatkowski,Marek Kwiatkowski,A. Olechnowicz,Jerzy Mroziński,Douglas M. Ho,Edward Deutsch +5 more
TL;DR: In this article, the synthesis, structure and important properties of the title compound are reported, formulated as Cu2L2Cl2 (L=singly deprotonated 8-amino-5-aza-4-methyl-3-octene-2-one ligand), which has a dimeric structure composed of two CuLCl subunits linked via bridging chlorine atoms.
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Synthesis and structural characterization of adducts of silver(I) carboxylate salts AgX (X = CF3COO, CH3COO) with ER3 (E = P, As; R = Ph, cy, o-tolyl) and oligodentate aromatic bases derivative of 2,2'-bipyridyl, L, AgX:PR3:L (1: 1:1)
Effendy,Effendy,Fabio Marchetti,Claudio Pettinari,Riccardo Pettinari,Brian W. Skelton,Allan H. White +6 more
TL;DR: In this article, the carboxylate anions have been found to be uni-, or semi-bidentate, or also completely ionic, as in the complexes Ag(PPh 3 )(bpy)(H 2 O)](tfa) and [Ag(pPh 3 ),(dpk ǫ·h 2 O) (tfa), (hydrated).
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Synthesis and characterisation of two double EE azido and thiocyanato bridged dimeric Cu(II) complexes with tridentate Schiff bases as blocking ligands
TL;DR: Two new double end-to-end azido and thiocyanato bridged copper(II) dimers as mentioned in this paper have been synthesized and their molecular structures have been determined by X-ray crystallography.
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Five-Coordinated High-Spin Complexes of Bivalent Cobalt, Nickel, andCopper with Tris(2-dimethylaminoethyl)amine
M. Ciampolini,N. Nardi +1 more
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Metal complexes as ligands—IV [1,2,3]: Bi- and Tri- nuclear complexes derived from metal complexes of tetradentate salicylaldimines
TL;DR: In this paper, a series of bi-and tri-nuclear complexes formed by using the donor properties of the two cis-oxygen atoms in metal (M) complexes of tetradentate Shiff bases (TSB) derived from salicylaldehyde or o-hydroxyacetophenone are reported.
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The Preparation and Characterization of Four-Coordinate Complexes Related by Electron-Transfer Reactions
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The Donor Properties of Pyridine N-Oxide
TL;DR: The coordination chemistry of pyridine N-oxide with a variety of acceptors has been investigated in this article, where the new substances Co(ClO4)26L, Co(NO3)24L), CoCl23L and CoCl2LH20, NiClO 4H2O, NiBr26L and NiBr2L H2O have been isolated and characterized by molecular conductance measurements in non-aqueous solvents, magnetic susceptibility measurements, and infrared spectra.