Journal ArticleDOI
The use of conductivity measurements in organic solvents for the characterisation of coordination compounds
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This article is published in Coordination Chemistry Reviews.The article was published on 1971-10-01. It has received 8264 citations till now. The article focuses on the topics: Coordination complex.read more
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Syntheses, structures, catecholase activity, spectroscopy and electrochemistry of a series of manganese(III) complexes: Role of auxiliary anionic ligand on catecholase activity
TL;DR: In this article, the synthesis, characterization, catechol oxidase activity, electrochemistry and electrospray ionization mass spectroscopy (ESI-MS positive) of five mononuclear manganese(III) compounds [MnIIIL(OAc)(H2O)]·DMF (1), [mnIIil(Cl)(H 2O), 2H 2 O ), [mnc2O(2H 2 )·2O (2), [Mnc3O(N3), H2O), [
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Synthesis and characterisation of zinc, cadmium and mercury complexes of benzilbisthiosemicarbazone. Structure of cadmium derivative
Elena López-Torres,Ma Antonia Mendiola,Jesús Rodrı́guez-Procopio,Mª Teresa Sevilla,Enrique Colacio,José Ma Moreno,Isabel Sobrados +6 more
TL;DR: In this paper, the first time for this kind of ligands, a distorted octahedral geometry was obtained for the benzilbisthiosemicarbazone LH6 with cadmium, mercury and zinc nitrates in ethanol.
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Spectroscopic and biological approach of Ni(II) and Cu(II) complexes of 2-pyridinecarboxaldehyde thiosemicarbazone.
TL;DR: On the basis of spectral studies an octahedral geometry has been assigned for Ni(II) complexes whereas tetragonal geometry for Cu(II), except [Cu(L)(2)SO(4)] which posseses five coordinated geometry.
Journal ArticleDOI
Novel platinum(II) and palladium(II) complexes with cyclin-dependent kinase inhibitors: synthesis, characterization and antitumour activity.
TL;DR: The Pt(II) and Pd( II) complexes have been tested in vitro due to their presumable anticancer activity against the following human cancer cell lines: K-562, MCF7, G-361 and HOS.
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Synthesis, characterization and potent superoxide dismutase-like activity of novel bis(pyrazole)-2,2'-bipyridyl mixed ligand copper(II) complexes.
Andrei S. Potapov,Evgenia A. Nudnova,Galina A. Domina,Liliya N. Kirpotina,Mark T. Quinn,Andrei I. Khlebnikov,Igor A. Schepetkin +6 more
TL;DR: Density functional theory calculations showed that introduction of a bipypidyl ligand into the complexes dramatically lowered the lowest unoccupied molecular orbital (LUMO) energy level, which explains the increased SOD-like activity of these complexes compared to non-bipy species.
References
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Five-Coordinated High-Spin Complexes of Bivalent Cobalt, Nickel, andCopper with Tris(2-dimethylaminoethyl)amine
M. Ciampolini,N. Nardi +1 more
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Metal complexes as ligands—IV [1,2,3]: Bi- and Tri- nuclear complexes derived from metal complexes of tetradentate salicylaldimines
TL;DR: In this paper, a series of bi-and tri-nuclear complexes formed by using the donor properties of the two cis-oxygen atoms in metal (M) complexes of tetradentate Shiff bases (TSB) derived from salicylaldehyde or o-hydroxyacetophenone are reported.
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The Preparation and Characterization of Four-Coordinate Complexes Related by Electron-Transfer Reactions
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The Donor Properties of Pyridine N-Oxide
TL;DR: The coordination chemistry of pyridine N-oxide with a variety of acceptors has been investigated in this article, where the new substances Co(ClO4)26L, Co(NO3)24L), CoCl23L and CoCl2LH20, NiClO 4H2O, NiBr26L and NiBr2L H2O have been isolated and characterized by molecular conductance measurements in non-aqueous solvents, magnetic susceptibility measurements, and infrared spectra.