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Journal ArticleDOI

The use of conductivity measurements in organic solvents for the characterisation of coordination compounds

W.J. Geary
- 01 Oct 1971 - 
- Vol. 7, Iss: 1, pp 81-122
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This article is published in Coordination Chemistry Reviews.The article was published on 1971-10-01. It has received 8264 citations till now. The article focuses on the topics: Coordination complex.

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Citations
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Facile synthesis of silver(i)-carbene complexes. useful carbene transfer agents

TL;DR: In this paper, the crystal structure of compound 1 revealed that linear [Ag(Et2-Bimy)2]+ and [AgBr2]- groups were associated through a short AgI−AgI contact (2.956 A).
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The Hydrophilic Phosphatriazaadamantane Ligand in the Development of H2 Production Electrocatalysts: Iron Hydrogenase Model Complexes

TL;DR: The complexes were solution electrocatalysts that decreased over-voltage for H(+) reduction from HOAc in CH(3)CN by up to 600 mV, and the most effective electrocatalyst is the asymmetric 1-PTA species, which promotes H(2) formation from HO Ac at the Fe(0)Fe(I) redox level.
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Cd(II) and Cu(II) complexes of polydentate Schiff base ligands: synthesis, characterization, properties and biological activity

TL;DR: In this paper, the synthesis of the Schiff base ligands, 4-[(4-bromo-phenylimino)-methyl]-benzene-1,2,3-triol (A1), 4]-(3,5-di-tert-butyl-4-hydroxy-phenymalin)-methyl]benzenes- 1,2-diol (A5), and their Cd(II) and Cu(II)-metal complexes, stability constants and potentiometric studies.
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Synthesis, spectral characterization, in vitro antibacterial, antifungal and cytotoxic activities of Co(II), Ni(II) and Cu(II) complexes with 1,2,4-triazole Schiff bases.

TL;DR: A series of metal complexes of cobalt(II), nickel( II) and copper(II) have been synthesized with newly synthesized biologically active 1,2,4-triazole Schiff bases derived from the condensation of 3-substituted-4-amino-5-mercapto-1-2, 4-Triazole and 8-formyl-7-hydroxy-4
References
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Journal ArticleDOI

Some octahedral complexes of uranium(IV)

TL;DR: In this article, the electronic spectra and magnetic susceptibilities of the complexes [UCl6]2, [UCL4Br2]2], [UBr4(Ph3PO)2] and [Ucl4(Et3PO]2] have been measured and relative values for the nephelauxetic effects and the ligand fields of the ligands have been derived.
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Metal-promoted reactions of 2-cyanopyridine: iron(II), cobalt(II), nickel(II), and copper(II) complexes of O-methylpyridine-2-carboximidate

TL;DR: In this article, the reaction of 2-cyanopyridine with copper(II) chloride in methanol solution can give three different products, viz., [(2-CNpy)2CuCl2], (I); [(Mepy)CuCl 2], (II); (III), (II) and (III) were also prepared directly from O-methylpyridine-2-carboximidate.
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The synthesis and characterisation of diacidobis(ethylenediamine)ruthenium(III) complexes and related compounds

TL;DR: In this paper, the structure of bis(ethylenediamine)ruthenium(III) compounds has been resolved into its optical enantiomorphs, and its structure related to that of other bis(methylenediamines) rutheniamine compounds, all of which are assigned a cis configuration.