Journal ArticleDOI
The use of conductivity measurements in organic solvents for the characterisation of coordination compounds
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This article is published in Coordination Chemistry Reviews.The article was published on 1971-10-01. It has received 8264 citations till now. The article focuses on the topics: Coordination complex.read more
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RuII( p-cymene) Compounds as Effective and Selective Anticancer Candidates with No Toxicity in Vivo.
Oscar A Lenis-Rojas,M. Paula Robalo,M. Paula Robalo,Ana Isabel Tomaz,Andreia Carvalho,Alexandra R. Fernandes,Fernanda Marques,Mónica Folgueira,Julián Yáñez,Digna Vázquez-García,Margarita López Torres,Alberto Fernández,Jesús J. Fernández +12 more
TL;DR: Both compounds present no cytotoxic effect in normal human primary fibroblasts when they are used at the IC50 concentration in A2780 and MCF7 cancer cells and the lack of in vivo toxicity is shown.
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Reactions of 3,5-Pyrazoledicarboxylic Acid with Organotin Chlorides and Oxides. Coordination Polymers Containing Organotin Macrocycles
TL;DR: In this paper, the reaction of 3,5-pyrazoledicarboxylic acid (LH3) with di-and triorganotin substrates has been investigated.
Journal ArticleDOI
Synthesis, characterization and in vitro biological activity of cobalt(II), copper(II) and zinc(II) Schiff base complexes derived from salicylaldehyde and D,L-selenomethionine
TL;DR: In this article, the analytical data showed that the Schiff base ligand acts as tridentate towards divalent metal ions (cobalt, copper, zinc) via the azomethine-N, carboxylate oxygen and phenolato oxygen by a stoichiometric reaction of M:L (1:1) to form metal complexes.
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Synthesis of copper(I) complexes containing enantiopure pybox ligands. First assays on enantioselective synthesis of propargylamines catalyzed by isolated copper(I) complexes.
TL;DR: Diffusion studies using (1)H and (19)F-DOSY experiments provide evidence that the different nuclearity of compounds 1 and 5 is maintained in the solution state and confirm that these ionic compounds exist in solution as stable, discrete, cationic complexes.
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Novel Cu(II) quinoxaline N1,N4-dioxide complexes as selective hypoxic cytotoxins
María H. Torre,Dinorah Gambino,Jeannette Araujo,Hugo Cerecetto,Mercedes González,María Laura Lavaggi,Amaya Azqueta,Adela López de Cerain,Antonio Monge Vega,Ulrich Abram,Antonio J. Costa-Filho +10 more
TL;DR: The Cu(II)-quinoxaline complexes are reported as a family of hypoxic cytotoxins for the first time and showed excellent selective cytotoxicity in hypoxia.
References
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Journal ArticleDOI
Five-Coordinated High-Spin Complexes of Bivalent Cobalt, Nickel, andCopper with Tris(2-dimethylaminoethyl)amine
M. Ciampolini,N. Nardi +1 more
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Metal complexes as ligands—IV [1,2,3]: Bi- and Tri- nuclear complexes derived from metal complexes of tetradentate salicylaldimines
TL;DR: In this paper, a series of bi-and tri-nuclear complexes formed by using the donor properties of the two cis-oxygen atoms in metal (M) complexes of tetradentate Shiff bases (TSB) derived from salicylaldehyde or o-hydroxyacetophenone are reported.
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The Preparation and Characterization of Four-Coordinate Complexes Related by Electron-Transfer Reactions
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The Donor Properties of Pyridine N-Oxide
TL;DR: The coordination chemistry of pyridine N-oxide with a variety of acceptors has been investigated in this article, where the new substances Co(ClO4)26L, Co(NO3)24L), CoCl23L and CoCl2LH20, NiClO 4H2O, NiBr26L and NiBr2L H2O have been isolated and characterized by molecular conductance measurements in non-aqueous solvents, magnetic susceptibility measurements, and infrared spectra.