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Journal ArticleDOI

The use of conductivity measurements in organic solvents for the characterisation of coordination compounds

W.J. Geary
- 01 Oct 1971 - 
- Vol. 7, Iss: 1, pp 81-122
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This article is published in Coordination Chemistry Reviews.The article was published on 1971-10-01. It has received 8264 citations till now. The article focuses on the topics: Coordination complex.

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Spectral, XRD, SEM and biological activities of transition metal complexes of polydentate ligands containing thiazole moiety

TL;DR: Metal complexes of o-vanillidene-2-aminobenzothiazole have been prepared and characterized by elemental and spectral data as well as magnetic susceptibility measurements and thermo gravimetric analysis (TG/DTA), revealing the non-electrolytic nature of these complexes.
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Synthesis and characterization of Zn(II) and Cd(II) complexes of S-benzyl-β-N-(2-pyridyl)methylenedithiocarbazate (HNNS): Bioactivity of the HNNS schiff base and its Zn(II), Cu(II) and Cd(II) complexes and the X-ray structure of the [Zn(NNS)2] complex

TL;DR: A tridentate Schiff base having HNNS donor sequence was prepared by condensing S-benzyldithiocarbazate (NH2NHCSSCH2Ph) with pyridine-2-carboxaldehyde Complexes of this ligand with Cu(II), Cd (II) and Zn(II) were synthesized and characterized by elemental analyses and various physico-chemical techniques as discussed by the authors.
Journal ArticleDOI

Ligandless, anionic, arylpalladium halide intermediates in the Heck reaction.

TL;DR: These anionic complexes insert olefins much faster than the corresponding neutral, P(t-Bu)(3)-ligated complexes, indicating that the anionic complex forms rapidly and reversibly in situ from the neutral species prior to migratory insertion.
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Synthesis, Structure and Light-Harvesting Properties of Some New Transition-Metal Dithiocarbamates Involving Ferrocene

TL;DR: Nine new transition-metal dithiocarbamates involving ferrocene (Fc), namely, [M(FcCH(2)Bzdtc)(2)] (M=Ni(II) (1) and UO (2) (VI) (9), have been synthesised and characterised by micro analyses, IR spectroscopy, (13)C NMR spectroscopic, and in three cases by single-crystal X-ray analysis
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Ni(II) and Cu(II) complexes with ONNO asymmetric tetradentate Schiff base ligand: synthesis, spectroscopic characterization, theoretical calculations, DNA interaction and antimicrobial studies

TL;DR: In this article, a novel Schiff base was synthesized from the condensation of 2-hydroxy-1-naphthaldehyde and isatin with 4-nitro-o-phenylenediamine.
References
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Journal ArticleDOI

Metal complexes as ligands—IV [1,2,3]: Bi- and Tri- nuclear complexes derived from metal complexes of tetradentate salicylaldimines

TL;DR: In this paper, a series of bi-and tri-nuclear complexes formed by using the donor properties of the two cis-oxygen atoms in metal (M) complexes of tetradentate Shiff bases (TSB) derived from salicylaldehyde or o-hydroxyacetophenone are reported.
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The Donor Properties of Pyridine N-Oxide

TL;DR: The coordination chemistry of pyridine N-oxide with a variety of acceptors has been investigated in this article, where the new substances Co(ClO4)26L, Co(NO3)24L), CoCl23L and CoCl2LH20, NiClO 4H2O, NiBr26L and NiBr2L H2O have been isolated and characterized by molecular conductance measurements in non-aqueous solvents, magnetic susceptibility measurements, and infrared spectra.