Journal ArticleDOI
The use of conductivity measurements in organic solvents for the characterisation of coordination compounds
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This article is published in Coordination Chemistry Reviews.The article was published on 1971-10-01. It has received 8264 citations till now. The article focuses on the topics: Coordination complex.read more
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Tuning the fluorescence emission in mononuclear heteroleptic trigonal silver(I) complexes
TL;DR: In this paper, the photophysical properties of these species have been investigated, both in solution and in the solid state: they showed intense fluorescence when excited with UV light, with λmax of emission comprised between 440-460 nm (in solution) and 460-498 nm (solid state) and lifetime decay of a few nanoseconds.
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Transition metal complexes with sterically demanding ligands. I. Synthesis and X-ray crystal structure of 1,5-cyclooctadiene palladium methyl triflate, (COD)Pd(Me)(OTf) and its cationic penta-coordinate adducts with sterically demanding 2,9-diaryl-substituted 1,10-phenanthroline ligands
Peter Burger,JanM Baumeister +1 more
TL;DR: In this paper, the synthesis, use and X-ray crystal structure of the cyclooctadiene Pd-triflate methyl complex 1 was described and evidence for ionization of the triflate ligand in 1 in solution was presented through IR, 19F-NMR and conductivity measurements.
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Mono-, bi- and multi-nuclear silver complexes constructed from bis(benzimidazole)-2-oxapropane ligands and methacrylate: syntheses, crystal structures, DNA-binding properties and antioxidant activities
TL;DR: In this article, the reaction of AgNO3 with three structurally related ligands in the absence of light gave three new silver coordination complexes, namely, [Ag2(methacrylate)2(Etobb)2]·CH3CN 1, Ag(mETHACrylate)(Bobb) 2 and Ag2(n 3]n 3, where Etobb = 1,3-bis(1-ethylbenzimidazol-2-yl)-2-oxapropane, Bobb = 1-3-
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Synthesis, Biological, Spectral, and Thermal Investigations of Cobalt(II) and Nickel(II) Complexes of N-Isonicotinamido -2',4'-Dichlorobenzalaldimine.
TL;DR: A new series of 12 complexes of cobalt (II) and nickel(II) with N-isonicotinamido-2′,4′-dichlorobenzalaldimine (INH-DCB) with the general composition MX2 · n(INH)-DCB have been synthesized.
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Mn(II) complexes of some acylhydrazones with NNO donor sites: Syntheses, a spectroscopic view on their coordination possibilities and crystal structures
TL;DR: Mn(II) complexes derived from a set of acylhydrazones were synthesised and characterized by elemental analyzes, IR, UV-vis and X-band EPR spectral studies as well as conductivity and magnetic susceptibility measurements as mentioned in this paper.
References
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Five-Coordinated High-Spin Complexes of Bivalent Cobalt, Nickel, andCopper with Tris(2-dimethylaminoethyl)amine
M. Ciampolini,N. Nardi +1 more
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Metal complexes as ligands—IV [1,2,3]: Bi- and Tri- nuclear complexes derived from metal complexes of tetradentate salicylaldimines
TL;DR: In this paper, a series of bi-and tri-nuclear complexes formed by using the donor properties of the two cis-oxygen atoms in metal (M) complexes of tetradentate Shiff bases (TSB) derived from salicylaldehyde or o-hydroxyacetophenone are reported.
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The Preparation and Characterization of Four-Coordinate Complexes Related by Electron-Transfer Reactions
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The Donor Properties of Pyridine N-Oxide
TL;DR: The coordination chemistry of pyridine N-oxide with a variety of acceptors has been investigated in this article, where the new substances Co(ClO4)26L, Co(NO3)24L), CoCl23L and CoCl2LH20, NiClO 4H2O, NiBr26L and NiBr2L H2O have been isolated and characterized by molecular conductance measurements in non-aqueous solvents, magnetic susceptibility measurements, and infrared spectra.