Journal ArticleDOI
The use of conductivity measurements in organic solvents for the characterisation of coordination compounds
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This article is published in Coordination Chemistry Reviews.The article was published on 1971-10-01. It has received 8264 citations till now. The article focuses on the topics: Coordination complex.read more
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Zigzag-Chain and Cyclic-Tetrameric Compounds Derived by Deprotonation of Mononuclear Copper(II) Complexes with N,N‘-Bis(2-substituted-imidazol-4-ylmethyl- idene)-1,4-diaminobutane (2-Substituent = H, Me): Synthesis, Characterization, Structure, Substituent Effect, and Interconvertibility
TL;DR: Two copper(II) complexes with N,N'-bis(2-substituted-imidazol-4-ylmethylidene)-1,4-diaminobutane (2- substituent = H, 1; Me, 2) were synthesized, and their deprotonation assembly behavior was studied.
Journal ArticleDOI
Novel carbohydrate-appended metal complexes for potential use in molecular imaging.
Tim Storr,Makoto Obata,Cara L. Fisher,Cara L. Fisher,Simon R. Bayly,Simon R. Bayly,David E. Green,David E. Green,Izabela Brudziñska,Yuji Mikata,Brian O. Patrick,Michael J. Adam,Shigenobu Yano,Chris Orvig +13 more
TL;DR: Two analogues of Re organometallic carbohydrate compounds, [Re(L(2))(CO)(3)Br] and [Re (L(3)(Br)(CO)( 3)Br], were characterized in the solid state by X-ray crystallography and represent the first reported structures of Reorganised carbohydrate compounds.
Journal ArticleDOI
Characterization studies of adenine complexes with 3d metal perchlorates
A.N. Speca,Chester M. Mikulski,Frank J. Iaconianni,Louis L. Pytlewski,Nicholas M. Karayannis +4 more
TL;DR: A series of adenine (LH) complexes with 3d metal perchlorates were prepared by refluxing solutions of the metal salts in ethanol-triethyl orthoformate with the ligand for 2-5 days as discussed by the authors.
Journal ArticleDOI
Synthesis, structure and SOD-like activity of a ternary Cu(II) complex with 1,10-phenanthroline and L-valinate
TL;DR: The ternary Cu(II) complex with 1,10-phenanthroline (phen) and L-valinate (L-Val) has been synthesized and investigated by elemental analysis, molar conductivity, UV/vis, IR, TG-DTG, and X-ray diffraction methods as discussed by the authors.
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The Radical Trap in Atom Transfer Radical Polymerization Need Not Be Thermodynamically Stable. A Study of the MoX3(PMe3)3 Catalysts
Sébastien Maria,François Stoffelbach,Jose A. Mata,Jean-Claude Daran,Philippe Richard,Rinaldo Poli +5 more
TL;DR: Electrochemical studies of MoI(3)(PMe(3) in the presence of X(-) (X = Cl or Br) reveal the occurrence of facile halide-exchange processes, leading to the conclusion that the MoI (3)X(PMe (3))( 3) products are also redox unstable.
References
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Five-Coordinated High-Spin Complexes of Bivalent Cobalt, Nickel, andCopper with Tris(2-dimethylaminoethyl)amine
M. Ciampolini,N. Nardi +1 more
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Metal complexes as ligands—IV [1,2,3]: Bi- and Tri- nuclear complexes derived from metal complexes of tetradentate salicylaldimines
TL;DR: In this paper, a series of bi-and tri-nuclear complexes formed by using the donor properties of the two cis-oxygen atoms in metal (M) complexes of tetradentate Shiff bases (TSB) derived from salicylaldehyde or o-hydroxyacetophenone are reported.
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The Preparation and Characterization of Four-Coordinate Complexes Related by Electron-Transfer Reactions
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The Donor Properties of Pyridine N-Oxide
TL;DR: The coordination chemistry of pyridine N-oxide with a variety of acceptors has been investigated in this article, where the new substances Co(ClO4)26L, Co(NO3)24L), CoCl23L and CoCl2LH20, NiClO 4H2O, NiBr26L and NiBr2L H2O have been isolated and characterized by molecular conductance measurements in non-aqueous solvents, magnetic susceptibility measurements, and infrared spectra.