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The use of conductivity measurements in organic solvents for the characterisation of coordination compounds
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This article is published in Coordination Chemistry Reviews.The article was published on 1971-10-01. It has received 8264 citations till now. The article focuses on the topics: Coordination complex.read more
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Facile synthesis of silver(i)-carbene complexes. useful carbene transfer agents
TL;DR: In this paper, the crystal structure of compound 1 revealed that linear [Ag(Et2-Bimy)2]+ and [AgBr2]- groups were associated through a short AgI−AgI contact (2.956 A).
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The Hydrophilic Phosphatriazaadamantane Ligand in the Development of H2 Production Electrocatalysts: Iron Hydrogenase Model Complexes
Rosario Mejia-Rodriguez,Daesung Chong,Joseph H. Reibenspies,Manuel P. Soriaga,Marcetta Y. Darensbourg +4 more
TL;DR: The complexes were solution electrocatalysts that decreased over-voltage for H(+) reduction from HOAc in CH(3)CN by up to 600 mV, and the most effective electrocatalyst is the asymmetric 1-PTA species, which promotes H(2) formation from HO Ac at the Fe(0)Fe(I) redox level.
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Cd(II) and Cu(II) complexes of polydentate Schiff base ligands: synthesis, characterization, properties and biological activity
TL;DR: In this paper, the synthesis of the Schiff base ligands, 4-[(4-bromo-phenylimino)-methyl]-benzene-1,2,3-triol (A1), 4]-(3,5-di-tert-butyl-4-hydroxy-phenymalin)-methyl]benzenes- 1,2-diol (A5), and their Cd(II) and Cu(II)-metal complexes, stability constants and potentiometric studies.
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Synthesis, spectral characterization, in vitro antibacterial, antifungal and cytotoxic activities of Co(II), Ni(II) and Cu(II) complexes with 1,2,4-triazole Schiff bases.
TL;DR: A series of metal complexes of cobalt(II), nickel( II) and copper(II) have been synthesized with newly synthesized biologically active 1,2,4-triazole Schiff bases derived from the condensation of 3-substituted-4-amino-5-mercapto-1-2, 4-Triazole and 8-formyl-7-hydroxy-4
References
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Journal ArticleDOI
678. Substituted Group VI carbonyls. Part III. The action of halogens on carbonyldi(tertiary arsine)tungsten and further studies on halogenocarbonylmolybdenum complexes
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Antimony pentachloride oxidation of arenetricarbonyl complexes of molybdenum and tungsten and a new route to substituted halogenocarbonyls
M. H. B. Stiddard,R. E. Townsend +1 more
TL;DR: The complexes M(CO)3 arene (M = Cr, Mo, or W, arene = hexamethylbenzene (hmb); M = Mo or W and hmb = mesitylene, durene, or p-cymene) react with antimony pentachloride in dichloromethane to give the orange-red ionic products as mentioned in this paper.
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Complex halides of transition metals—II(1) the hexachloromolybdate (V) ion
B.J. Brisdon,R.A. Walton +1 more
TL;DR: In this paper, tetraethylammonium hexachloromolybdate (V) was prepared from the corresponding pentahalides and their spectra in this solvent and in the solid state have been measured and compared with the spectrum of the hexabromotungstate anion.
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Co-ordination complexes of titanium(II)
TL;DR: In this paper, it was shown that reaction of sodium tetrachlorotitanate(II) with trimethylamine resulted in oxidation of the halide and the formation of TiCl3,2NMe3.