Jan Reedijk

TL;DR: High-nuclearity mixed valence manganese(II/III) coordination clusters, have been synthesised and magnetothermal studies reveal that all three compounds show interesting long-range magnetic ordering at low temperature, originating from negligible magnetic anisotropy of the compounds; compound 2 shows the largest magnetocaloric effect among the three compounds.

TL;DR: A brief summary of the key role for certain heavy-metal compounds in medicine is discussed, with a special focus on very recent findings in the following four topics: platinum anti-tumor compounds, platinum mononuclear compounds, dinuclear compounds and trinuclear compounds with promising activity.

TL;DR: In this article, the Pt-cysteine type bonds in [PtCl(dien)GS] + and in trans-Pt(NH 3 ) 2 (GS) 2 could not be reversed by sodium diethyldithiocarbamate (Na(ddtc)) and thiourea.

TL;DR: Electrophilic attack, being common to the particular catalytic system studied in this paper and the well-known biotic and abiotic oxidation catalysis by heme and non-heme complexes of the ferryl (Fe(IV)O(2+)) ion, appears to be a unifying electronic structure principle of C-H(alpha) hydroxylation and oxidation reactions.