J
Jan Reedijk
Researcher at Leiden University
Publications - 1165
Citations - 45902
Jan Reedijk is an academic researcher from Leiden University. The author has contributed to research in topics: Ligand & Crystal structure. The author has an hindex of 80, co-authored 1163 publications receiving 43747 citations. Previous affiliations of Jan Reedijk include Nagoya City University & University of Münster.
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A remarkable anion effect on the crystal packing of two analogous copper complexes from a thiophene-containing phenol-based ligand
Iryna A. Koval,Maila Sgobba,Mieke Huisman,Matthias Lüken,Eric Saint-Aman,Patrick Gamez,Bernt Krebs,Jan Reedijk +7 more
TL;DR: The asymmetric phenol-based N,O,S-ligand Hpy2th1as was prepared by the straightforward reductive amination of 3-{[bis(pyridin-2-ylmethyl)amino]methyl with 2-hydroxybenzaldehyde as discussed by the authors.
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Alkoxo-bridged dinuclear copper(II) compounds with 2-amino-picolines as ligands: Synthesis, spectroscopy, magnetism and X-ray crystal structures
TL;DR: In this article, the synthesis, spectroscopic, magnetic and structural characterisation of four new alkoxo-bridged dinuclear copper(II) compounds are described, in which the dinuclear units are stabilized by intramolecular H-bonds between the amino hydrogens and Omethoxo and/or Oanion atoms, providing a square planar CuN2O2 unit.
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New Antitumor Platinum Compounds Linked to Amino Phosphonic Acids Which Lose the Phosphonate and Tertiary Amine Ligand upon Binding to Nucleic Acids
TL;DR: In this paper, the interaction of the antitumor active platinum phosphonato complexes with (oligo)nucleotides has been investigated using 1 H NMR and 31 P NMR spectroscopy.
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Dinuclear alkyldiamine platinum antitumor compounds: a structure-activity relationship study.
TL;DR: Six related dinuclear trans-platinum complexes, with the formula [[trans-PtCl(2)(NH(3))(L)], are compared with known cytotoxic dinuclear compounds (L = NH(3); n = 4, 6) that overcome cisplatin resistance and show comparable binding, except for the sterically hindered 2-picoline compounds that bind significantly less.
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Dinuclear CuII Complexes with a New Phenol-Based Ligand Bearing Pyridine and Thiophene Substituents: Synthesis, Characterization and Interaction with Catechol Substrates
Iryna A. Koval,Mieke Huisman,Arno F. Stassen,Patrick Gamez,Olivier Roubeau,Catherine Belle,Jean-Louis Pierre,Eric Saint-Aman,Matthias Lüken,Bernt Krebs,Martin Lutz,Anthony L. Spek,Jan Reedijk +12 more
TL;DR: In this article, the reaction of the phenol-based ligand 4-methyl-2,6-bis{[(2-methylpyridyl)( 2-methylthiophenyl)amino]methyl}phenol(Hpy2th2s), containing pyridine and thiophene substituents, with copper(II) chloride and bromide yields two new dinuclear complexes with the composition [Cu2(py 2th 2s)X3], where X = Cl or Br.