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Enhanced catalytic activity in strained chemically exfoliated WS 2 nanosheets for hydrogen evolution

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TLDR
Analyses indicate that the enhanced electrocatalytic activity of WS₂ is associated with the high concentration of the strained metallic 1T (octahedral) phase in the as-exfoliated nanosheets.
Abstract
Efficient evolution of hydrogen via electrocatalysis at low overpotentials is promising for clean energy production. Monolayered nanosheets of chemically exfoliated WS2 are shown to be efficient catalysts for hydrogen evolution at very low overpotentials. The enhanced catalytic performance is associated with the high concentration of the strained metallic octahedral phase in the exfoliated nanosheets.

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Photoelectrocatalytic Materials for Solar Water Splitting

TL;DR: In this paper, a review of the advances in the development of efficient photoelectrocatalytic materials for water splitting is presented, and some strategies that can be employed in material screening and optimization for the construction of highly efficient photo-electrochemical devices for the water splitting are also discussed.
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Molybdenum Carbide-Embedded Nitrogen-Doped Porous Carbon Nanosheets as Electrocatalysts for Water Splitting in Alkaline Media.

TL;DR: In this work, Mo2C-embedded nitrogen-doped porous carbon nanosheets (Mo2C@2D-NPCs) were successfully achieved with the help of a convenient interfacial strategy and outperforming the state-of-the-art metal-carbide-based electrocatalysts in alkaline media.
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Strain engineering of metal-based nanomaterials for energy electrocatalysis.

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Enabling silicon for solar-fuel production

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Separating hydrogen and oxygen evolution in alkaline water electrolysis using nickel hydroxide

TL;DR: Using nickel hydroxide as a redox mediator, this work decouple the hydrogen and oxygen production in alkaline water electrolysis, which overcomes the gas-mixing issue and may increase the use of renewable energy.
References
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Journal ArticleDOI

Generalized Gradient Approximation Made Simple

TL;DR: A simple derivation of a simple GGA is presented, in which all parameters (other than those in LSD) are fundamental constants, and only general features of the detailed construction underlying the Perdew-Wang 1991 (PW91) GGA are invoked.
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Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set.

TL;DR: An efficient scheme for calculating the Kohn-Sham ground state of metallic systems using pseudopotentials and a plane-wave basis set is presented and the application of Pulay's DIIS method to the iterative diagonalization of large matrices will be discussed.
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Projector augmented-wave method

TL;DR: An approach for electronic structure calculations is described that generalizes both the pseudopotential method and the linear augmented-plane-wave (LAPW) method in a natural way and can be used to treat first-row and transition-metal elements with affordable effort and provides access to the full wave function.
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Atomically thin MoS2: a new direct-gap semiconductor

TL;DR: The electronic properties of ultrathin crystals of molybdenum disulfide consisting of N=1,2,…,6 S-Mo-S monolayers have been investigated by optical spectroscopy and the effect of quantum confinement on the material's electronic structure is traced.
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Single-layer MoS2 transistors

TL;DR: Because monolayer MoS(2) has a direct bandgap, it can be used to construct interband tunnel FETs, which offer lower power consumption than classical transistors, and could also complement graphene in applications that require thin transparent semiconductors, such as optoelectronics and energy harvesting.
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