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Organic Non-Volatile Memory Based on Pentacene Field-Effect Transistors Using a Polymeric Gate Electret**

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TLDR
In this paper, a poly(a-methylstyrene) (PaMS) layer was added to the SiO2 gate insulator and the pentacene channel in the typical OFET structure, and the results indicated reasonably good OFET behavior, suggesting the additional PaMS layer does not degrade the performance of the devices.
Abstract
electrets. In this Communication, we report on OFET memory devices built on silicon wafers and based on films of pentacene and an SiO2 gate insulator that are separated by a thin layer of poly(a-methylstyrene) (PaMS), which acts as a polymeric gate dielectric. This OFET memory device displayed reversible shifts in the threshold voltage (VTh) when an appropriate gate voltage (Vg) was applied above a certain threshold via a relatively short switching time. Based on these reversible shifts in VTh, a non-volatile organic memory was demonstrated that takes advantage of the simple configuration of a typical OFET. This device showed a large memory window (about 90 V), a high on/off ratio (IOn/IOff) (10 5 ), a short switching time (less than 1 ls), and a long retention time (more than 100 h). These memory characteristics were obtained only when an appropriate polymeric gate electret layer (e.g., PaMS) was inserted between the SiO2 gate insulator and the pentacene channel in the typical OFET structure. Therefore, it is possible that this behavior originates from the modulation of the gate field by stored charges in the polymeric gate electret. Detailed reasons for these results and a possible operating mechanism for our OFET memory device are discussed. A cross-sectional view of the fabricated device structure is shown in Figure 1a. Further details concerning the fabrication of this device are discussed in the Experimental section. Figure 1b and c shows the output and transfer characteristics of the devices, respectively. The results indicate reasonably good OFET behavior, suggesting the additional PaMS layer does not degrade the performance of the devices. [14] From the conventional characterization equation, [15] the measured values of the typical field-effect mobility (lFET), VTh, and IOn/IOff were 0.51 cm 2 V –1 s –1 (maximum value, 0.89 cm 2 V –1 s –1 ), – 19 V, and 10 5 , respectively. These transistor properties could

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Citations
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Silicon ion implanted PMMA for soft electronics

TL;DR: In this article, the electrical conductivity and field-effect transconductance of polymethylmethacrylate (PMMA) subjected to implantation with 50 keV silicon ions at doses in the range from 10 14 to 10 17 ions/cm 2 were examined.
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Artificial electrical dipole in polymer multilayers for nonvolatile thin film transistor memory

TL;DR: In this article, an organic nonvolatile thin-film transistor (TFT) memory on a plastic substrate is reported, where the cross-linked poly-4-vinyl phenol (PVP) is used as a polymer dielectric layer in the form of a triple layer structure to achieve the memory function.
Journal ArticleDOI

Solution processed non-volatile top-gate polymer field-effect transistors

TL;DR: In this paper, the authors describe the development of a top gate solution processable organic memory solution, which operates at voltages between 20 and 30 V with memory on-off ratios close to 103 at programming speeds of 1 ms.
Journal ArticleDOI

Polycyclic arene-based D–A polyimide electrets for high-performance n-type organic field effect transistor memory devices

TL;DR: In this article, the memory characteristics of n-type N,N-bis(2-phenylethyl)-perylene-3,4:9,10-tetracarboxylic diimide-based organic field effect transistors (OFET) using a series of donor-acceptor (D-A) polyimide electrets of poly[4,4′-diamino-4″-methyltriphenylamine-hexafluoroisopropylidenediphthal imide] (PI(AMT
Journal ArticleDOI

Optical memory characteristics of solution-processed organic transistors with self-organized organic floating gates for printable multi-level storage devices

TL;DR: In this article, a solution process was used to fabricate top-gate/bottom-contact (TG/BC) OFET devices with organic floating-gate structures and investigate their memory characteristics under light illumination.
References
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Proceedings Article

Physics of semiconductor devices

S. M. Sze
Journal ArticleDOI

The path to ubiquitous and low-cost organic electronic appliances on plastic

TL;DR: The future holds even greater promise for this technology, with an entirely new generation of ultralow-cost, lightweight and even flexible electronic devices in the offing, which will perform functions traditionally accomplished using much more expensive components based on conventional semiconductor materials such as silicon.
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Organic Thin Film Transistors for Large Area Electronics

TL;DR: In this article, the authors present new insight into conduction mechanisms and performance characteristics, as well as opportunities for modeling properties of organic thin-film transistors (OTFTs) and discuss progress in the growing field of n-type OTFTs.
Journal ArticleDOI

Device Physics of Solution‐Processed Organic Field‐Effect Transistors

TL;DR: In this article, the materials, charge-transport, and device physics of solution-processed organic field-effect transistors are reviewed, focusing in particular on the physics of the active semiconductor/dielectric interface.
Journal ArticleDOI

The Physics of Ferroelectric Memories

TL;DR: In this article, the authors describe a scenario where they are in the last stages of typing their thesis, the year is 1980, and it's a hot, hazy summer afternoon, a thunderstorm brews on the horizon.
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