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Showing papers on "Metamaterial published in 2021"


Journal ArticleDOI
TL;DR: This Review surveys the basic principles, recent advances and promising future directions for wave-based-metamaterial analogue computing systems, and describes some of the most exciting applications suggested for these Computing metamaterials, including image processing, edge detection, equation solving and machine learning.
Abstract: Despite their widespread use for performing advanced computational tasks, digital signal processors suffer from several restrictions, including low speed, high power consumption and complexity, caused by costly analogue-to-digital converters. For this reason, there has recently been a surge of interest in performing wave-based analogue computations that avoid analogue-to-digital conversion and allow massively parallel operation. In particular, novel schemes for wave-based analogue computing have been proposed based on artificially engineered photonic structures, that is, metamaterials. Such kinds of computing systems, referred to as computational metamaterials, can be as fast as the speed of light and as small as its wavelength, yet, impart complex mathematical operations on an incoming wave packet or even provide solutions to integro-differential equations. These much-sought features promise to enable a new generation of ultra-fast, compact and efficient processing and computing hardware based on light-wave propagation. In this Review, we discuss recent advances in the field of computational metamaterials, surveying the state-of-the-art metastructures proposed to perform analogue computation. We further describe some of the most exciting applications suggested for these computing systems, including image processing, edge detection, equation solving and machine learning. Finally, we provide an outlook for the possible directions and the key problems for future research. Metamaterials provide a platform to leverage optical signals for performing specific-purpose computational tasks with ultra-fast speeds. This Review surveys the basic principles, recent advances and promising future directions for wave-based-metamaterial analogue computing systems.

175 citations


Journal ArticleDOI
20 Jan 2021-Nature
TL;DR: In this paper, a tileable mechanical metamaterial with stable memory at the unit-cell level is presented, where each m-bit can be independently and reversibly switched between two stable states (acting as memory) using magnetic actuation to move between the equilibria of a bistable shell.
Abstract: Metamaterials are designed to realize exotic physical properties through the geometric arrangement of their underlying structural layout1,2. Traditional mechanical metamaterials achieve functionalities such as a target Poisson's ratio3 or shape transformation4-6 through unit-cell optimization7-9, often with spatial heterogeneity10-12. These functionalities are programmed into the layout of the metamaterial in a way that cannot be altered. Although recent efforts have produced means of tuning such properties post-fabrication13-19, they have not demonstrated mechanical reprogrammability analogous to that of digital devices, such as hard disk drives, in which each unit can be written to or read from in real time as required. Here we overcome this challenge by using a design framework for a tileable mechanical metamaterial with stable memory at the unit-cell level. Our design comprises an array of physical binary elements (m-bits), analogous to digital bits, with clearly delineated writing and reading phases. Each m-bit can be independently and reversibly switched between two stable states (acting as memory) using magnetic actuation to move between the equilibria of a bistable shell20-25. Under deformation, each state is associated with a distinctly different mechanical response that is fully elastic and can be reversibly cycled until the system is reprogrammed. Encoding a set of binary instructions onto the tiled array yields markedly different mechanical properties; specifically, the stiffness and strength can be made to range over an order of magnitude. We expect that the stable memory and on-demand reprogrammability of mechanical properties in this design paradigm will facilitate the development of advanced forms of mechanical metamaterials.

165 citations


Journal ArticleDOI
TL;DR: In this article, a four-band terahertz tunable narrow-band perfect absorber based on a bulk Dirac semi-metallic (BDS) metamaterial with a microstructure is designed.
Abstract: A four-band terahertz tunable narrow-band perfect absorber based on a bulk Dirac semi-metallic (BDS) metamaterial with a microstructure is designed. The three-layer structure of this absorber from top to bottom is the Dirac semi-metallic layer, the dielectric layer and the metal reflector layer. Based on the Finite Element Method (FEM), we use the simulation software CST STUDIO SUITE to simulate the absorption characteristics of the designed absorber. The simulation results show that the absorption rate of the absorber is over 93% at frequencies of 1.22, 1.822, 2.148 and 2.476 THz, and three of them have achieved a perfect absorption rate of more than 95%. We use the localized surface plasmon resonance (LSPR), impedance matching and other theories to analyze its physical mechanism in detail. The influence of the geometric structure parameters of the absorber and the incident angle of electromagnetic waves on the absorption performance has also been studied in detail. Due to the rotational symmetry of the structure, the designed absorber has excellent polarization insensitivity. In addition, the maximum adjustable range of absorption frequency is 0.051 THz, which can be achieved by changing the Fermi energy of BDS. We also define the refractive index sensitivity (S), which is 39.1, 75.4, 119.1 and 122.0 GHz RIU−1 for the four absorption modes when the refractive index varies in the range of 1 to 1.9. This high-performance absorber has a very good development prospect in the frontier fields of bio-chemical sensing and special environmental detection.

155 citations


Journal ArticleDOI
TL;DR: In this paper, the authors investigated a technique for broadband vibration suppression using a graded metamaterial beam, where a series of local resonators with the same mass but different natural frequencies are attached to the beam, and a design strategy was proposed, and used to tune the frequency spacing to get a wide attenuation region.

118 citations


Journal ArticleDOI
TL;DR: In this paper, the authors used dielectric metasurfaces as a powerful platform for novel optical biosensors, due to their low optical loss and strong light-matter interaction.
Abstract: Dielectric metasurfaces have emerged as a powerful platform for novel optical biosensors. Due to their low optical loss and strong light–matter interaction, they demonstrate several exotic optical ...

112 citations


Journal ArticleDOI
TL;DR: In this paper, the authors review recent advances in meta-structured waveguides that synergize various functional subwavelength photonic architectures with diverse waveguide platforms, such as dielectric or plasmonic waveguide and optical fibers.
Abstract: The growing maturity of nanofabrication has ushered massive sophisticated optical structures available on a photonic chip. The integration of subwavelength-structured metasurfaces and metamaterials on the canonical building block of optical waveguides is gradually reshaping the landscape of photonic integrated circuits, giving rise to numerous meta-waveguides with unprecedented strength in controlling guided electromagnetic waves. Here, we review recent advances in meta-structured waveguides that synergize various functional subwavelength photonic architectures with diverse waveguide platforms, such as dielectric or plasmonic waveguides and optical fibers. Foundational results and representative applications are comprehensively summarized. Brief physical models with explicit design tutorials, either physical intuition-based design methods or computer algorithms-based inverse designs, are cataloged as well. We highlight how meta-optics can infuse new degrees of freedom to waveguide-based devices and systems, by enhancing light-matter interaction strength to drastically boost device performance, or offering a versatile designer media for manipulating light in nanoscale to enable novel functionalities. We further discuss current challenges and outline emerging opportunities of this vibrant field for various applications in photonic integrated circuits, biomedical sensing, artificial intelligence and beyond.

108 citations


Journal ArticleDOI
TL;DR: The use of mechanophores to chemically transform polymers dates back decades as mentioned in this paper and has resulted in a range of engineered molecular responses that span optical, mechanical, electronic and thermal properties.
Abstract: The use of mechanical forces to chemically transform polymers dates back decades. In recent years, the use of mechanochemistry to direct constructive transformations in polymers has resulted in a range of engineered molecular responses that span optical, mechanical, electronic and thermal properties. The chemistry that has been developed is now well positioned for use in materials science, polymer physics, mechanics and additive manufacturing. Here, we review the historical backdrop of polymer mechanochemistry, give an overview of the existing toolbox of mechanophores and associated theoretical methods, and speculate as to emerging opportunities in materials science for which current capabilities are seemingly well suited. Non-linear mechanical responses and internal, amplifying stimulus–response feedback loops, including those enabled by, or coupled to, microstructured metamaterial architectures, are seen as particularly promising. Polymer mechanochemistry converts mechanical forces in materials to chemical reactions through the response of functional groups known as mechanophores. This Review discusses the colorimetric, mechanical, chemical and electronic responses of mechanophores that may be useful in materials for strain sensing and strengthening, soft devices and additive manufacturing.

106 citations


Journal ArticleDOI
TL;DR: In this paper, a composite porous metamaterial (CPM) consisting in a porous polyurethane sponge with embedded multi-layer I-plates is proposed to mitigate the slow wave phenomenon and/or insufficient sub-wavelength sound absorption.

106 citations


Journal ArticleDOI
TL;DR: This review is focused on the fabrication of metamaterials and the application status of AM technology in them, and discusses the limits of present metammaterials in the aspect of design method and the disadvantages of existing AM technology.

102 citations


Journal ArticleDOI
TL;DR: In this paper, a multi-band ideal absorber of monolayer graphene was designed and analyzed through impedance matching and coupled mode theory, and a new method based on critical coupling and guided resonance was proposed theoretically and numerically.

99 citations


Journal ArticleDOI
TL;DR: In this paper, the authors present a new magneto-mechanical metamaterial that allows great tunability through a novel concept of deformation mode branching, which can be incorporated with magnetic shape memory polymers with global stiffness tunability, which further enables the global shift of the acoustic behaviors.
Abstract: Mechanical metamaterials are architected manmade materials that allow for unique behaviors not observed in nature, making them promising candidates for a wide range of applications. Existing metamaterials lack tunability as their properties can only be changed to a limited extent after the fabrication. In this paper, we present a new magneto-mechanical metamaterial that allows great tunability through a novel concept of deformation mode branching. The architecture of this new metamaterial employs an asymmetric joint design using hard-magnetic soft active materials that permits two distinct actuation modes (bending and folding) under opposite-direction magnetic fields. The subsequent application of mechanical forces leads to the deformation mode branching where the metamaterial architecture transforms into two distinctly different shapes, which exhibit very different deformations and enable great tunability in properties such as mechanical stiffness and acoustic bandgaps. Furthermore, this metamaterial design can be incorporated with magnetic shape memory polymers with global stiffness tunability, which further enables the global shift of the acoustic behaviors. The combination of magnetic and mechanical actuations, as well as shape memory effects, imbue unmatched tunable properties to a new paradigm of metamaterials.

Journal ArticleDOI
Shuai Yang1, Jun Wang1, Gaole Dai2, Fubao Yang1, Jiping Huang1 
TL;DR: In this article, a review of thermal metamaterials and their associated theories is presented, including transformation theories and their extended theories, which are called theoretical thermotics for convenience.

Journal ArticleDOI
TL;DR: In this article, a dual-functional metamaterial for low-frequency vibration isolation and energy harvesting is proposed, where a rolling-ball with coils into a spherical magnetic cavity is used to isolate mechanical wave and simultaneously harvest electrical energy.

Journal ArticleDOI
TL;DR: This work develops a multimaterial printing technology for the complex structural integration of MSMs and M-SMPs to explore their enhanced multimodal shape transformation and tunable properties and demonstrates multiple deformation modes with distinct shape configurations that further enable active metamaterials with tunable physical properties such as sign-change Poisson's ratio.
Abstract: Magnetic soft materials (MSMs) have shown potential in soft robotics, actuators, metamaterials, and biomedical devices because they are capable of untethered, fast, and reversible shape reconfigurations as well as controllable dynamic motions under applied magnetic fields. Recently, magnetic shape memory polymers (M-SMPs) that incorporate hard magnetic particles in shape memory polymers demonstrated superior shape manipulation performance by realizing reprogrammable, untethered, fast, and reversible shape transformation and shape locking in one material system. In this work, we develop a multimaterial printing technology for the complex structural integration of MSMs and M-SMPs to explore their enhanced multimodal shape transformation and tunable properties. By cooperative thermal and magnetic actuation, we demonstrate multiple deformation modes with distinct shape configurations, which further enable active metamaterials with tunable physical properties such as sign-change Poisson's ratio. Because of the multiphysics response of the M-MSP/MSM metamaterials, one distinct feature is their capability of shifting between various global mechanical behaviors such as expansion, contraction, shear, and bending. We anticipate that the multimaterial printing technique opens new avenues for the fabrication of multifunctional magnetic materials.

Journal ArticleDOI
TL;DR: A review of metamaterials and origami-based structures as well as their applications to vibration and sound control and possible future research directions are elaborated for this emerging and promising interdisciplinary research field.

Journal ArticleDOI
TL;DR: In this paper, the authors present the results of a study on improving the performance parameters such as impedance bandwidth, radiation gain and efficiency, as well as suppressing substrate loss of an innovative antenna for on-chip implementation for millimetre-wave and terahertz integrated-circuits.
Abstract: This paper presents the results of a study on improving the performance parameters such as the impedance bandwidth, radiation gain and efficiency, as well as suppressing substrate loss of an innovative antenna for on-chip implementation for millimetre-wave and terahertz integrated-circuits. This was achieved by using the metamaterial and the substrate-integrated waveguide (SIW) technologies. The on-chip antenna structure comprises five alternating layers of metallization and silicon. An array of circular radiation patches with metamaterial-inspired crossed-shaped slots are etched on the top metallization layer below which is a silicon layer whose bottom surface is metalized to create a ground plane. Implemented in the silicon layer below is a cavity above which is no ground plane. Underneath this silicon layer is where an open-ended microstrip feedline is located which is used to excite the antenna. The feed mechanism is based on the coupling of the electromagnetic energy from the bottom silicon layer to the top circular patches through the cavity. To suppress surface waves and reduce substrate loss, the SIW concept is applied at the top silicon layer by implementing the metallic via holes at the periphery of the structure that connect the top layer to the ground plane. The proposed on-chip antenna has an average measured radiation gain and efficiency of 6.9 dBi and 53%, respectively, over its operational frequency range from 0.285–0.325 THz. The proposed on-chip antenna has dimensions of 1.35 × 1 × 0.06 mm3. The antenna is shown to be viable for applications in millimetre-waves and terahertz integrated-circuits.

Journal ArticleDOI
TL;DR: In this paper, the tunable propagation properties of 3D Dirac semimetal (DSM) patterned metamaterial (MM) structures have been symmetrically investigated in the terahertz (THz) regime.
Abstract: The tunable propagation properties of 3D Dirac semimetal (DSM) patterned metamaterial (MM) structures have been symmetrically investigated in the terahertz (THz) regime. The results demonstrate that the resonant properties are very sensitive to the thicknesses of DSM MMs, and hundreds of nanometers are required to excite strong resonant curves. The DSM MMs support both strong LC and dipolar resonances, quite different from graphene MM patterns which mainly depend on dipolar resonance. As the Fermi level increases, the resonant strength becomes stronger, and significant modulation can be achieved, e.g. the amplitude and frequency modulation depths of transmission curves are more than 99% and 80%, respectively. In addition, by utilizing asymmetrical resonators, a very sharp Fano resonant peak is achieved with a large Q-factor of more than 25, for which the figure of merit is about 20. The results are very helpful to understand the tunable mechanisms of DSM devices and design novel THz plasmonic components, such as modulators, filters, and sensors.

Journal ArticleDOI
TL;DR: The earliest microwave absorbing materials (MAMs) are fabricated in the early 20th century for military purpose to inhibit radar detection as mentioned in this paper, and the application of MAMs has been existing in every part of human's life to prevent radiation and interference.
Abstract: The earliest microwave absorbing materials (MAMs) are fabricated in the early 20th century for military purpose to inhibit radar detection. Currently, the application of MAMs has been existing in every part of human's life to prevent radiation and interference. The microwave absorbant and microwave absorbing coatings classified by composition including alloys, metal oxides, conductive polymers, carbon materials, ceramic materials both in traditional and innovative forms are introduced in this work. Considering the harsh and complex application environment, MAMs with high temperature resistance and infrared-compatible stealth performance are involved. Metamaterials, showing excellent electromagnetic properties which are far beyond that of the materials can achieve, including perfect absorber, digitally coded control metamaterials, bionic structural materials, and adjustable smart metamaterials, are also introduced specifically in this work. In addition, to investigate electromagnetic response of absorbant, the first-principles calculations works are overviewed. The electromagnetic properties, loss mechanisms, structure, fabrication method, regulation approaches, designing principles, current applications, and future prospects of MAMs are involved in this work. This work gives a comprehensively overview over the MAMs for their theoretical and experimental advances in recent years including the military radar (frequency range of 2–18 GHz) stealth materials, relevant infrared compatible (infrared-visible, infrared-radar, infrared-laser) stealth materials, and other stealth materials with multifrequency adaptability.

Journal ArticleDOI
TL;DR: In this article, two types of ultra-broadband metamaterials absorbers with high absorption, ultrathin thickness and easy configurations are designed and demonstrated, which pave the way for enhancing the optical performance in applications of infrared thermal emitters, imaging and photodetectors.
Abstract: Broadband metamaterials absorbers with high absorption, ultrathin thickness and easy configurations are in great demand for many potential applications. In this paper, we first analyse the coupling resonances in a Ti/Ge/Ti three-layer absorber, which can realise broadband absorption from 8 to 12 μm. Then we experimentally demonstrate two types of absorbers based on the Ti/Ge/Si3N4/Ti configuration. By taking advantage of coupling surface plasmon resonances and intrinsic absorption of lossy material Si3N4, the average absorptions of two types of absorbers achieve almost 95% from 8 to 14 μm (experiment result: 78% from 6.5 to 13.5 μm). In order to expand the absorption bandwidth, we further propose two Ti/Si/SiO2/Ti absorbers which can absorb 92% and 87% of ultra-broadband light in the 14–30 μm and 8–30 μm spectral range, respectively. Our findings establish general and systematic strategies for guiding the design of metamaterial absorbers with excellent broadband absorption and pave the way for enhancing the optical performance in applications of infrared thermal emitters, imaging and photodetectors. Ultra-broadband metamaterials absorbers with high absorption, ultrathin thickness and easy configurations are designed and demonstrated, which pave the way for enhancing the optical performance in applications of infrared thermal emitters, imaging and photodetectors.

Journal ArticleDOI
TL;DR: In this article, a switchable bi-functional metamaterial device based on a hybrid gold-vanadium dioxide (VO2) nanostructure was proposed, which can be thermally switched for circularly polarized light in the near-infrared region.
Abstract: In this paper, we propose a switchable bi-functional metamaterial device based on a hybrid gold-vanadium dioxide (VO2) nanostructure. Utilizing the property of a metal-to-insulator transition in VO2, perfect absorption and asymmetric transmission (AT) can be thermally switched for circularly polarized light in the near-infrared region. When VO2 is in the metallic state, the designed metamaterial device behaves as a chiral-selective plasmonic perfect absorber, which can result in an optical circular dichroism (CD) response with a maximum value ∼ 0.7. When VO2 is in the insulating state, the proposed metamaterial device exhibits a dual-band AT effect. The combined hybridization model and electromagnetic field distributions are presented to explain the physical mechanisms of chiral-selective perfect absorption and AT effect, respectively. The influences of structure parameters on CD response and AT effect are also discussed. Moreover, the proposed switchable bi-functional device is robust against the incident angle for obtaining perfect absorption and strong CD response as well as the AT effect. Our work may provide a promising path for the development of multifunctional optoelectronic devices, such as thermal emitters, optical modulators, CD spectroscopy, optical isolator, etc.

Journal ArticleDOI
TL;DR: In this paper, the progress of the research on metasurfaces is illustrated, and the development of soft metamaterials opens up a new dimension of application zone in conformal or wearable photonics.
Abstract: Metamaterials are composed of periodic subwavelength metal/dielectric structures that resonantly couple to the electric and magnetic fields of the incident electromagnetic waves, exhibiting unprecedented properties which are most typical within the context of the electromagnetic domain. However, the practical application of metamaterials was found critical due to the high losses, strong dispersion associated with the resonant responses, and the difficulty in the fabrication of nanoscale 3D structures. The optical metasurface is termed as 2D metamaterials that inherent all of the properties of metamaterials and also provide a solution to the limitation of the conventional metamaterials. Over the past few years, metasurfaces have been employed for the design and fabrication of optical elements and systems with abilities that surpass the performance of conventional diffractive optical elements. Metasurfaces can be fabricated using standard lithography and nanoimprinting methods which is easier in terms of fabrication of its counterpart 3d metamaterials. In this review article, the progress of the research on metasurfaces is illustrated. Concepts of anomalous reflection and refraction, applications of metasurfaces with the Pancharatanm-Berry Phase, and Huygens metasurface are discussed. The development of soft metasurface opens up a new dimension of application zone in conformal or wearable photonics, the progress of soft metasurface also been discussed in this review. Meta-devices that are being developed with the principle of the shaping of wavefronts are elucidated in this review. Furthermore, it was established that properties of novel optical metasurface can be modulated by the change in mechanical, electrical, or optical stimuli which leads to the development of dynamic metasurface. Research thrust over the area of tunable metasurface has been reviewed in this article. Over the recent year, it has been found that optical fibers and metasurface are coagulated for the development of optical devices with the advantage of both domains. The metasurface with lab-on fiber-based devices is being discussed in this review paper. Finally, research trends, challenges, and future scope of the work are summarized in the conclusion part of the article.

Journal ArticleDOI
TL;DR: In this article, it was demonstrated that a nanometric dielectric or semiconductor layer, 1000 times thinner than the resonant wavelength (λ/1000), induces a dynamically controllable quasi-bound state in the continuum (QBIC) with ultrahigh quality factor in a symmetric metallic metasurface at terahertz frequencies.
Abstract: A bound state in the continuum (BIC) is a nonradiating state of light embedded in the continuum of propagating modes providing drastic enhancement of the electromagnetic field and its localization at micro-nanoscale. However, access to such modes in the far-field requires symmetry breaking. Here, it is demonstrated that a nanometric dielectric or semiconductor layer, 1000 times thinner than the resonant wavelength (λ/1000), induces a dynamically controllable quasi-bound state in the continuum (QBIC) with ultrahigh quality factor in a symmetric metallic metasurface at terahertz frequencies. Photoexcitation of nanostrips of germanium activates ultrafast switching of a QBIC resonance with 200% transmission intensity modulation and complete recovery within 7 ps on a low-loss flexible substrate. The nanostrips also form microchannels that provide an opportunity for BIC-based refractive index sensing. An optimization model is presented for (switchable) QBIC resonances of metamaterial arrays of planar symmetric resonators modified with any (active) dielectric for inverse metamaterial design that can serve as an enabling platform for active micro-nanophotonic devices.

Journal ArticleDOI
TL;DR: In this article, a novel type of 2D metamaterial composed of auxetic foam and steel is proposed to attenuate seismic waves at ultra-low frequencies, and a parametric study of the SM with auxiliary foam-coated hollow steel columns is carried out to achieve a wide bandgap coverage for the seismic peak spectrum of 2.

Journal ArticleDOI
TL;DR: The history and development of pillared materials are overviewed, a detailed synopsis of a selection of key research topics that involve the utilization of pillars or similar branching substructures in different contexts are provided, and some perspectives on the state of the field are provided.
Abstract: The introduction of engineered resonance phenomena on surfaces has opened a new frontier in surface science and technology. Pillared phononic crystals, metamaterials, and metasurfaces are an emerging class of artificial structured media, featuring surfaces, that consist of pillars–or branching substructures–standing on a plate or a substrate. A pillared phononic crystal exhibits Bragg band gaps while a pillared metamaterial may feature both Bragg band gaps and local-resonance hybridization band gaps. These two band-gap phenomena, along with other unique wave dispersion characteristics, have been exploited for a variety of applications spanning a range of length scales and covering multiple disciplines in applied physics and engineering, particularly in elastodynamics and acoustics. The intrinsic placement of pillars on a semi-infinite surface–yielding a metasurface–has similarly provided new avenues for the control and manipulation of wave propagation. Classical waves are admitted in pillared media, including Lamb waves in plates and Rayleigh and Love waves along the surface of substrates, ranging in frequencies from Hz to several GHz. With the presence of the pillars, these waves couple with surface resonances richly creating new phenomena and properties in the subwavelength regime and in some applications at higher frequencies as well. At the nanoscale, it was shown that atomic-scale resonances–stemming from nanopillars–alter the fundamental nature of conductive thermal transport by reducing the group velocities and generating mode localizations across the entire spectrum of the constituent material well into the THz regime. In this article, we first overview the history and development of pillared materials, then provide a detailed synopsis of a selection of key research topics that involve the utilization of pillars or similar branching substructures in different contexts. Finally, we conclude by providing a short summary and some perspectives on the state of the field and its promise for further future development.

Journal ArticleDOI
TL;DR: A high-performance plasmonic metamaterial selective absorber developed by facile solution-based processes via assembling an ultrathin (≈120 nm) titanium nitride (TiN) nanoparticle film on a TiN mirror achieves high, full-spectrum solar absorption, low mid-IR emission, and excellent stability over a temperature range of 100-727 °C.
Abstract: Low-cost and large-area solar-thermal absorbers with superior spectral selectivity and excellent thermal stability are vital for efficient and large-scale solar-thermal conversion applications, such as space heating, desalination, ice mitigation, photothermal catalysis, and concentrating solar power. Few state-of-the-art selective absorbers are qualified for both low- ( 600 °C) applications due to insufficient spectral selectivity or thermal stability over a wide temperature range. Here, a high-performance plasmonic metamaterial selective absorber is developed by facile solution-based processes via assembling an ultrathin (≈120 nm) titanium nitride (TiN) nanoparticle film on a TiN mirror. Enabled by the synergetic in-plane plasmon and out-of-plane Fabry-Perot resonances, the all-ceramic plasmonic metamaterial simultaneously achieves high, full-spectrum solar absorption (95%), low mid-IR emission (3% at 100 °C), and excellent stability over a temperature range of 100-727 °C, even outperforming most vacuum-deposited absorbers at their specific operating temperatures. The competitive performance of the solution-processed absorber is accompanied by a significant cost reduction compared with vacuum-deposited absorbers. All these merits render it a cost-effective, universal solution to offering high efficiency (89-93%) for both low- and high-temperature solar-thermal applications.


Journal ArticleDOI
TL;DR: A bifunctional metamaterial is proposed based on a hybrid graphene and vanadium dioxide (VO2) configuration, which can realize a dynamic switch between beam steering and broadband absorption, which may show great potential in applications such as terahertz switching and modulation.
Abstract: A bifunctional metamaterial is proposed based on a hybrid graphene and vanadium dioxide (VO2) configuration, which can realize a dynamic switch between beam steering and broadband absorption. The structure consists of a VO2 square, graphene patch, topas spacer, VO2 film, topas spacer, and metal substrate. When VO2 is in the metallic state, the structure serves as a coding metamaterial. By engineering different sizes of the top VO2 square and adjusting the Fermi energy level of graphene, the incident wave is scattered in different patterns. When VO2 is in the dielectric state, the structure serves as a broadband absorber. By changing the Fermi energy level of graphene from 0.0 eV to 0.9 eV, absorptance can be gradually changed and working bandwidth widens. There is an absorption band with near 100% absorptance from 0.9 THz to 1.35 THz when the Fermi energy level is 0.73 eV. And the designed broadband absorber is polarization-insensitive within the incident angle of 50°. Our work may show great potential in applications such as terahertz switching and modulation.

Journal ArticleDOI
TL;DR: In this article, an anisotropic graphene-based meta-filter was proposed to enable versatile beam behaviors and low reflection loss under orthogonal polarization, which is a promising candidate for future electronic applications in special scenarios calling for excellent environmental resistance and superb flexibility.


Journal ArticleDOI
26 Jan 2021-ACS Nano
TL;DR: Grating-graphene metamaterials constitute an outstanding platform for commercially viable, CMOS-compatible, room-temperature, chip-integrated, THz nonlinear conversion applications.
Abstract: Nonlinear optics is an increasingly important field for scientific and technological applications, owing to its relevance and potential for optical and optoelectronic technologies. Currently, there is an active search for suitable nonlinear material systems with efficient conversion and a small material footprint. Ideally, the material system should allow for chip integration and room-temperature operation. Two-dimensional materials are highly interesting in this regard. Particularly promising is graphene, which has demonstrated an exceptionally large nonlinearity in the terahertz regime. Yet, the light-matter interaction length in two-dimensional materials is inherently minimal, thus limiting the overall nonlinear optical conversion efficiency. Here, we overcome this challenge using a metamaterial platform that combines graphene with a photonic grating structure providing field enhancement. We measure terahertz third-harmonic generation in this metamaterial and obtain an effective third-order nonlinear susceptibility with a magnitude as large as 3 × 10-8 m2/V2, or 21 esu, for a fundamental frequency of 0.7 THz. This nonlinearity is 50 times larger than what we obtain for graphene without grating. Such an enhancement corresponds to a third-harmonic signal with an intensity that is 3 orders of magnitude larger due to the grating. Moreover, we demonstrate a field conversion efficiency for the third harmonic of up to ∼1% using a moderate field strength of ∼30 kV/cm. Finally, we show that harmonics beyond the third are enhanced even more strongly, allowing us to observe signatures of up to the ninth harmonic. Grating-graphene metamaterials thus constitute an outstanding platform for commercially viable, CMOS-compatible, room-temperature, chip-integrated, THz nonlinear conversion applications.