Showing papers by "California State University, Long Beach published in 2016"

Ultrafine jagged platinum nanowires enable ultrahigh mass activity for the oxygen reduction reaction

Abstract: Improving the platinum (Pt) mass activity for the oxygen reduction reaction (ORR) requires optimization of both the specific activity and the electrochemically active surface area (ECSA). We found that solution-synthesized Pt/NiO core/shell nanowires can be converted into PtNi alloy nanowires through a thermal annealing process and then transformed into jagged Pt nanowires via electrochemical dealloying. The jagged nanowires exhibit an ECSA of 118 square meters per gram of Pt and a specific activity of 11.5 milliamperes per square centimeter for ORR (at 0.9 volts versus reversible hydrogen electrode), yielding a mass activity of 13.6 amperes per milligram of Pt, nearly double previously reported best values. Reactive molecular dynamics simulations suggest that highly stressed, undercoordinated rhombus-rich surface configurations of the jagged nanowires enhance ORR activity versus more relaxed surfaces.

SU2: An Open-Source Suite for Multiphysics Simulation and Design

Abstract: This paper presents the main objectives and a description of the SU2 suite, including the novel software architecture and open-source software engineering strategy. SU2 is a computational analysis and design package that has been developed to solve multiphysics analysis and optimization tasks using unstructured mesh topologies. Its unique architecture is well suited for extensibility to treat partial-differential-equation-based problems not initially envisioned. The common framework adopted enables the rapid implementation of new physics packages that can be tightly coupled to form a powerful ensemble of analysis tools to address complex problems facing many engineering communities. The framework is demonstrated on a number, solving both the flow and adjoint systems of equations to provide a high-fidelity predictive capability and sensitivity information that can be used for optimal shape design using a gradient-based framework, goal-oriented adaptive mesh refinement, or uncertainty quantification.

Characterization of collective ground states in single-layer NbSe 2

Abstract: What happens to correlated electronic phases—superconductivity and charge density wave ordering—as a material is thinned? Experiments show that both can remain intact in just a single layer of niobium diselenide.

The Mediterranean plastic soup: synthetic polymers in Mediterranean surface waters

Abstract: The Mediterranean Sea has been recently proposed as one of the most impacted regions of the world with regards to microplastics, however the polymeric composition of these floating particles is still largely unknown. Here we present the results of a large-scale survey of neustonic micro- and meso-plastics floating in Mediterranean waters, providing the first extensive characterization of their chemical identity as well as detailed information on their abundance and geographical distribution. All particles >700 μm collected in our samples were identified through FT-IR analysis (n = 4050 particles), shedding for the first time light on the polymeric diversity of this emerging pollutant. Sixteen different classes of synthetic materials were identified. Low-density polymers such as polyethylene and polypropylene were the most abundant compounds, followed by polyamides, plastic-based paints, polyvinyl chloride, polystyrene and polyvinyl alcohol. Less frequent polymers included polyethylene terephthalate, polyisoprene, poly(vinyl stearate), ethylene-vinyl acetate, polyepoxide, paraffin wax and polycaprolactone, a biodegradable polyester reported for the first time floating in off-shore waters. Geographical differences in sample composition were also observed, demonstrating sub-basin scale heterogeneity in plastics distribution and likely reflecting a complex interplay between pollution sources, sinks and residence times of different polymers at sea.

Key Questions in Marine Megafauna Movement Ecology

Abstract: It is a golden age for animal movement studies and so an opportune time to assess priorities for future work. We assembled 40 experts to identify key questions in this field, focussing on marine megafauna, which include a broad range of birds, mammals, reptiles, and fish. Research on these taxa has both underpinned many of the recent technical developments and led to fundamental discoveries in the field. We show that the questions have broad applicability to other taxa, including terrestrial animals, flying insects, and swimming invertebrates, and, as such, this exercise provides a useful roadmap for targeted deployments and data syntheses that should advance the field of movement ecology.

Geomorphic and geologic controls of geohazards induced by Nepal’s 2015 Gorkha earthquake

Abstract: The Gorkha earthquake (M 7.8) on 25 April 2015 and later aftershocks struck South Asia, killing ~9,000 and damaging a large region. Supported by a large campaign of responsive satellite data acquisitions over the earthquake disaster zone, our team undertook a satellite image survey of the earthquakes’ induced geohazards in Nepal and China and an assessment of the geomorphic, tectonic, and lithologic controls on quake-induced landslides. Timely analysis and communication aided response and recovery and informed decision makers. We mapped 4,312 co-seismic and post-seismic landslides. We also surveyed 491 glacier lakes for earthquake damage, but found only 9 landslide-impacted lakes and no visible satellite evidence of outbursts. Landslide densities correlate with slope, peak ground acceleration, surface downdrop, and specific metamorphic lithologies and large plutonic intrusions.

Systematic and Dramatic Tuning on Gas Sorption Performance in Heterometallic Metal–Organic Frameworks

Abstract: Despite their having much greater potential for compositional and structural diversity, heterometallic metal-organic frameworks (MOFs) reported so far have lagged far behind their homometallic counterparts in terms of CO2 uptake performance. Now the power of heterometallic MOFs is in full display, as shown by a series of new materials (denoted CPM-200s) with superior CO2 uptake capacity (up to 207.6 cm(3)/g at 273 K and 1 bar), close to the all-time record set by MOF-74-Mg. The isosteric heat of adsorption can also be tuned from -16.4 kJ/mol for CPM-200-Sc/Mg to -79.6 kJ/mol for CPM-200-V/Mg. The latter value is the highest reported for MOFs with Lewis acid sites. Some members of the CPM-200s family consist of combinations of metal ions (e.g., Mg/Ga, Mg/Fe, Mg/V, Mg/Sc) that have never been shown to coexist in any known crystalline porous materials. Such previously unseen combinations become reality through a cooperative crystallization process, which leads to the most intimate form of integration between even highly dissimilar metals, such as Mg(2+) and V(3+). The synergistic effects of heterometals bestow CPM-200s with the highest CO2 uptake capacity among known heterometallic MOFs and place them in striking distance of the all-time CO2 uptake record.

Hexagonal@Cubic CdS Core@Shell Nanorod Photocatalyst for Highly Active Production of H2 with Unprecedented Stability.

Abstract: A highly effective, low-cost strategy for improved photocatalytic efficiency and stability of CdS is described. Based on the integration of hexagonal-cubic core-shell architecture with nanorod morphology, the concentric CdS nanorod phase junctions (NRPJs) obtained demonstrate extremely high H2 production rate and unprecedented photocatalytic stability.

Caring for High-Need, High-Cost Patients—An Urgent Priority

Abstract: Five foundations aim to improve care for high-need, high-cost patients by building U.S. capabilities in three vital areas: clarifying the needs of such patients, elucidating the best ways of caring for them, and assisting with the spread of proven approaches.

Chiral chemistry of metal-camphorate frameworks.

Abstract: This critical review presents the various synthetic approaches and chiral chemistry of metal–camphorate frameworks (MCamFs), which are homochiral metal–organic frameworks (MOFs) constructed from a camphorate ligand. The interest in this unique subset of homochiral MOFs is derived from the many interesting chiral features for both materials and life sciences, such as asymmetrical synthesis or crystallization, homochiral structural design, chiral induction, absolute helical control and ligand handedness. Additionally, we discuss the potential applications of homochiral MCamFs. This review will be of interest to researchers attempting to design other homochiral MOFs and those engaged in the extension of MOFs for applications such as chiral recognition, enantiomer separation, asymmetric catalysis, nonlinear sensors and devices.

Relational energy at work: Implications for job engagement and job performance.

Abstract: Energy is emerging as a topic of importance to organizations, yet we have little understanding of how energy can be useful at an interpersonal level toward achieving workplace goals. We present the results of 4 studies aimed at developing, validating, and testing the relational energy construct. In Study 1, we report qualitative insights from 64 individuals about the experience and functioning of relational energy in the workplace. Study 2 draws from 3 employee samples to conduct exploratory and confirmatory factor analyses on a measure of relational energy, differentiating relational energy from related constructs. To test the predictive validity of the new relational energy scale, Study 3 comprises data from employees rating the level of relational energy they experienced during interactions with their leaders in a health services context. Results showed that relational energy employees experienced with their leaders at Time 1 predicted job engagement at Time 2 (1 month later), while controlling for the competing construct of perceived social support. Study 4 shows further differentiation of relational energy from leader-member exchange (LMX), replicates the positive relationship between relational energy (Time 1) and job engagement (Time 2), and shows that relational energy is positively associated with employee job performance (Time 3) through the mechanism of job engagement. We discuss the theoretical implications of our findings and highlight areas for future research.

An ultra-tunable platform for molecular engineering of high-performance crystalline porous materials

Abstract: Metal-organic frameworks are a class of crystalline porous materials with potential applications in catalysis, gas separation and storage, and so on. Of great importance is the development of innovative synthetic strategies to optimize porosity, composition and functionality to target specific applications. Here we show a platform for the development of metal-organic materials and control of their gas sorption properties. This platform can accommodate a large variety of organic ligands and homo- or hetero-metallic clusters, which allows for extraordinary tunability in gas sorption properties. Even without any strong binding sites, most members of this platform exhibit high gas uptake capacity. The high capacity is accomplished with an isosteric heat of adsorption as low as 20 kJ mol−1 for carbon dioxide, which could bring a distinct economic advantage because of the significantly reduced energy consumption for activation and regeneration of adsorbents. Synthetic design of crystalline porous materials is important for applications such as catalysis and adsorption. Here, the authors demonstrate a platform for the development of crystalline porous materials with a variety of organic ligands and metallic clusters, and control of their gas sorption properties.

Parallels with the Female Athlete Triad in Male Athletes

Abstract: Participation in sports offers many health benefits to athletes of both sexes. However, subsets of both female and male athletes are at increased risk of impaired bone health and bone stress injuries. The Female Athlete Triad (Triad) is defined as the interrelationship of low energy availability (with or without disordered eating), menstrual dysfunction, and low bone mineral density. The Triad may result in health consequences, including bone stress injuries. Our review presents evidence that an analogous process may occur in male athletes. Our review of the available literature indicates that a subset of male athletes may experience adverse health issues that parallel those associated with the Triad, including low energy availability (with or without disordered eating), hypogonadotropic hypogonadism, and low bone mineral density. Consequently, male athletes may be predisposed to developing bone stress injuries, and these injuries can be the first presenting feature of associated Triad conditions. We discuss the evidence for impaired nutrition, hormonal dysfunction, and low bone mineral density in a subset of male athletes, and how these health issues may parallel those of the Triad. With further research into the mechanisms and outcomes of these health concerns in active and athletic men, evidence-based guidelines can be developed that result in best practice.

Compassion Fatigue, Burnout, and Compassion Satisfaction Among Oncology Nurses in the United States and Canada.

Abstract: Purpose/objectives To examine the experiences of compassion fatigue, burnout, and compassion satisfaction among oncology nurses in the United States and Canada. . Design Quantitative, descriptive, nonexperimental. . Setting Online survey with members from the Canadian Association of Nursing Oncology and the Oncology Nursing Society. . Sample 486 American and 63 Canadian practicing oncology nurses. . Methods The Professional Quality of Life (ProQOL) scale, version 5, and modified Abendroth Demographic Questionnaire were administered through FluidSurveys™, an online data collection instrument. Chi-square tests of independence were used to investigate associations between demographic characteristics, health, personal stressors, and work-related characteristics to experiences of compassion fatigue, burnout, and compassion satisfaction. Compassion fatigue was measured using the subscales of secondary traumatic stress and burnout. . Main research variables Compassion fatigue, burnout, and compassion satisfaction. . Findings Demographic characteristics were similar in American and Canadian participants, and both cohorts reported comparable levels of compassion fatigue, burnout, and compassion satisfaction. Perception of team cohesiveness within the workplace environment was found to be significant for both groups, as indicated by significant relationships in all three subscales of secondary traumatic stress, burnout, and compassion satisfaction in the ProQOL. . Conclusions Healthy and supportive work environments are imperative to nurses' health, well-being, and satisfaction. Improvements in the workplace can help prevent negative sequelae, as well as improve health outcomes for patients and nurses, decrease nurse turnover, and reduce healthcare expenditures. . Implications for nursing Findings can be used to implement institutional changes, such as creating policies and guidelines for the development of preventive interventions and psychosocial support for nurses.

Requirements: The Key to Sustainability

Abstract: Software's critical role in society demands a paradigm shift in the software engineering mind-set. This shift's focus begins in requirements engineering. This article is part of a special issue on the Future of Software Engineering.

Sociolinguistics from the Periphery: Small Languages in New Circumstances

Abstract: This leading team of scholars presents a fascinating book about change: shifting political, economic and cultural conditions; ephemeral, sometimes even seasonal, multilingualism; and altered imaginaries for minority and indigenous languages and their users. The authors refer to this network of interlinked changes as the new conditions surrounding small languages (Sami, Corsican, Irish and Welsh) in peripheral sites. Starting from the conviction that peripheral sites can and should inform the sociolinguistics of globalisation, the book explores how new modes of reflexivity, more transactional frames for authenticity, commodification of peripheral resources, and boundary-transgression with humour, all carry forward change. These types of change articulate a blurring of binary oppositions between centre and periphery, old and new, and standard and non-standard. Such research is particularly urgent in multilingual small language contexts, where different conceptualisations of language(s), boundaries, and speakers impact on individuals' social, cultural, and economic capital, and opportunities.

Current and Potential Therapeutic Strategies for Hemodynamic Cardiorenal Syndrome

Abstract: Background: Cardiorenal syndrome (CRS) encompasses conditions in which cardiac and renal disorders co-exist and are pathophysiologically related. The newest class

Highly Selective and Rapid Uptake of Radionuclide Cesium Based on Robust Zeolitic Chalcogenide via Stepwise Ion-Exchange Strategy

Abstract: The safe use of nuclear energy requires the development of advanced adsorbent technology to address environment damage from nuclear waste or accidental release of radionuclides. Recently developed amine-directed chalcogenide frameworks have intrinsic advantages as ion-exchange materials to capture radionuclides, because their exceptionally negative framework charge can lead to high cation-uptake capacity and their 3-D multidimensional intersecting channel promotes rapid ion diffusion and offer a unique kinetic advantage. Prior to this work, however, such advantages could not be realized because organic cations in the as-synthesized materials are sluggish during ion exchange. Here we report an ingenious approach on the activation of amine-directed zeolitic chalcogenides through a stepwise ion-exchange strategy and their use in cesium adsorption. The activated porous chalcogenide exhibits highly enhanced cesium uptake compared to the pristine form and is comparable to the best metal chalcogenide sorbents so...

Chronic interstitial nephritis in agricultural communities: a worldwide epidemic with social, occupational and environmental determinants.

Abstract: Increase in the prevalence of chronic kidney disease (CKD) is observed in Central America, Sri Lanka and other tropical countries. It is named chronic interstitial nephritis in agricultural communities (CINAC). CINAC is defined as a form of CKD that affects mainly young men, occasionally women. Its aetiology is not linked to diabetes, hypertension, glomerulopathies or other known causes. CINAC patients live and work in poor agricultural communities located in CINAC endemic areas with a hot tropical climate, and are exposed to toxic agrochemicals through work, by ingestion of contaminated food and water, or by inhalation. The disease is characterized by low or absent proteinuria, small kidneys with irregular contours in CKD stages 3–4 presenting tubulo-interstitial lesions and glomerulosclerosis at renal biopsy. Although the aetiology of CINAC is unclear, it appears to be multifactorial. Two hypotheses emphasizing different primary triggers have been proposed: one related to toxic exposures in the agricultural communities, the other related to heat stress with repeated episodes of dehydration heath stress and dehydration. Existing evidence supports occupational and environmental toxins as the primary trigger. The heat stress and dehydration hypothesis, however, cannot explain: why the incidence of CINAC went up along with increasing mechanization of paddy farming in the 1990s; the non-existence of CINAC in hotter northern Sri Lanka, Cuba and Myanmar where agrochemicals are sparsely used; the mosaic geographical pattern in CINAC endemic areas; the presence of CINAC among women, children and adolescents who are not exposed to the harsh working conditions; and the observed extra renal manifestations of CINAC. This indicates that heat stress and dehydration may be a contributory or even a necessary risk factor, but which is not able to cause CINAC by itself.

Microbial response to simulated global change is phylogenetically conserved and linked with functional potential.

Abstract: The high diversity of microbial communities hampers predictions about their responses to global change Here we investigate the potential for using a phylogenetic, trait-based framework to capture the response of bacteria and fungi to global change manipulations Replicated grassland plots were subjected to 3+ years of drought and nitrogen fertilization The responses of leaf litter bacteria and fungi to these simulated changes were significantly phylogenetically conserved Proportional changes in abundance were highly correlated among related organisms, such that relatives with approximately 5% ribosomal DNA genetic distance showed similar responses to the treatments A microbe's change in relative abundance was significantly correlated between the treatments, suggesting a compromise between numerical abundance in undisturbed environments and resistance to change in general, independent of disturbance type Lineages in which at least 90% of the microbes shared the same response were circumscribed at a modest phylogenetic depth (τD 0014-0021), but significantly larger than randomized simulations predict In several clades, phylogenetic depth of trait consensus was higher Fungal response to drought was more conserved than was response to nitrogen fertilization, whereas bacteria responded equally to both treatments Finally, we show that a bacterium's response to the manipulations is correlated with its potential functional traits (measured here as the number of glycoside hydrolase genes encoding the capacity to degrade different types of carbohydrates) Together, these results suggest that a phylogenetic, trait-based framework may be useful for predicting shifts in microbial composition and functioning in the face of global change

Populations and Interventions for Palliative and End-of-Life Care: A Systematic Review

Abstract: Importance: Evidence supports palliative care effectiveness. Given workforce constraints and the costs of new services, payers and providers need help to prioritize their investments. They need to know which patients to target, which personnel to hire, and which services best improve outcomes. Objective: To inform how payers and providers should identify patients with “advanced illness” and the specific interventions they should implement, we reviewed the evidence to identify (1) individuals appropriate for palliative care and (2) elements of health service interventions (personnel involved, use of multidisciplinary teams, and settings of care) effective in achieving better outcomes for patients, caregivers, and the healthcare system. Evidence Review: Systematic searches of MEDLINE, EMBASE, PsycINFO, Web of Science, and Cochrane Database of Systematic Reviews databases (1/1/2001-1/8/2015). Results: Randomized controlled trials (124) met inclusion criteria. The majority of studies in cancer (49%, ...

Multivariable Modular Design of Pore Space Partition.

Abstract: Pore space partition, especially the one using C3-symmetric 2,4,6-tri(4-pyridyl)-1,3,5-triazine as pore-partition agent in MIL-88 type (the acs net), has been shown to dramatically enhance CO2 uptake to near-record values. The continued advance in property engineering via pore space partition would depend on intelligent design of both framework components and pore-partition agent. Here, we report a new advance in the design of pore-partition agent by demonstrating a symmetry-guided pathway to develop a large variety of di- and trinuclear 1,2,4-triazolate-based clusters for use as pore-partition agent. The use of metal–organic clusters (instead of organic ligands) as pore-partition agent gives rise to many new pore-partitioned materials with huge compositional variety. The full assembly involves the simultaneous formation of two separate coordination architectures (i.e., the 3-D acs framework and 0-D triazolate clusters) and the eventual welding between the acs framework and triazolate clusters. The wide r...

Framework Cationization by Preemptive Coordination of Open Metal Sites for Anion-Exchange Encapsulation of Nucleotides and Coenzymes.

Abstract: Cationic frameworks can selectively trap anions through ion exchange, and have applications in ion chromatography and drug delivery. However, cationic frameworks are much rarer than anionic or neutral ones. Herein, we propose a concept, preemptive coordination (PC), for targeting positively charged metal-organic frameworks (P-MOFs). PC refers to proactive blocking of metal coordination sites to preclude their occupation by neutralizing ligands such as OH(-) . We use 20 MOFs to show that this PC concept is an effective approach for developing P-MOFs whose high stability, porosity, and anion-exchange capability allow immobilization of anionic nucleotides and coenzymes, in addition to charge- and size-selective capture or separation of organic dyes. The CO2 and C2 H2 uptake capacity of 117.9 cm(3) g(-1) and 148.5 cm(3) g(-1) , respectively, at 273 K and 1 atm, is exceptionally high among cationic framework materials.

Phase 2 study of concurrent radiotherapy and temozolomide followed by temozolomide and lomustine in the treatment of children with high-grade glioma: a report of the Children's Oncology Group ACNS0423 study

Abstract: Background The prognosis for children with malignant glioma is poor. This study was designed to determine whether lomustine and temozolomide following radiotherapy and concurrent temozolomide improves event-free survival (EFS) compared with historical controls with anaplastic astrocytoma (AA) or glioblastoma (GBM) and whether survival is influenced by the expression of O6-methylguanine-DNA-methyltransferase (MGMT).

Adverse Childhood Experiences and Suicide Attempts: The Mediating Influence of Personality Development and Problem Behaviors

Abstract: Adverse childhood experiences, comprised of forms of maltreatment and certain dysfunctional household environments, can affect the development of a child in a variety of different ways. This multitude of developmental changes may subsequently produce compounding harmful effects on the child’s life and increase acutely maladaptive outcomes, including adolescent suicidal behavior. This study uses data collected from 2007 to 2012 for 64,329 Florida Department of Juvenile Justice youth (21.67 % female, 42.88 % African American, and 15.37 % Hispanic) to examine the direct and indirect effects of adverse childhood experiences on suicide attempts. Using a generalized structural equation model, the effects of adverse childhood experience scores are estimated on suicidal behavior through pathways of certain aspects of a child’s personality development (aggression and impulsivity), as well as adolescent problem behaviors (school difficulties and substance abuse). The results show that a large proportion of the relationship between childhood adversity and suicide is mediated by the aforementioned individual characteristics, specifically through the youth’s maladaptive personality development. These results suggest that, if identified early enough, the developmental issues for these youth could potentially be addressed in order to thwart potential suicidal behavior.

Sustainability design in requirements engineering: state of practice

Abstract: Sustainability is now a major concern in society, but there is little understanding of how it is perceived by software engineering professionals and how sustainability design can become an embedded part of software engineering process. This paper presents the results of a qualitative study exploring requirements engineering practitioners' perceptions and attitudes towards sustainability. It identifies obstacles and mitigation strategies regarding the application of sustainability design principles in daily work life. The results of this study reveal several factors that can prevent sustainability design from becoming a first class citizen in software engineering: software practitioners tend to have a narrow understanding of the concept of sustainability; organizations show limited awareness of its potential opportunities and benefits; and the norms in the discipline are not conducive to sustainable outcomes. These findings suggest the need for focused efforts in sustainability education, but also a need to rethink professional norms and practices.