Institution
King Abdullah University of Science and Technology
Education•Jeddah, Saudi Arabia•
About: King Abdullah University of Science and Technology is a education organization based out in Jeddah, Saudi Arabia. It is known for research contribution in the topics: Catalysis & Membrane. The organization has 6221 authors who have published 22019 publications receiving 625706 citations. The organization is also known as: KAUST.
Topics: Catalysis, Membrane, Computer science, Fading, Population
Papers published on a yearly basis
Papers
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TL;DR: In this article, the authors demonstrate continuous electrocatalytic conversion of CO2 to pure liquid fuel solutions in cells that utilize solid electrolytes, where electrochemically generated cations and anions are combined to form pure product solutions without mixing with other ions.
Abstract: Electrocatalytic CO2 reduction is often carried out in a solution electrolyte such as KHCO3(aq), which allows for ion conduction between electrodes. Therefore, liquid products that form are in a mixture with the dissolved salts, requiring energy-intensive downstream separation. Here, we report continuous electrocatalytic conversion of CO2 to pure liquid fuel solutions in cells that utilize solid electrolytes, where electrochemically generated cations (such as H+) and anions (such as HCOO−) are combined to form pure product solutions without mixing with other ions. Using a HCOOH-selective (Faradaic efficiencies > 90%) and easily scaled Bi catalyst at the cathode, we demonstrate production of pure HCOOH solutions with concentrations up to 12 M. We also show 100 h continuous and stable generation of 0.1 M HCOOH with negligible degradation in selectivity and activity. Production of other electrolyte-free C2+ liquid oxygenate solutions, including acetic acid, ethanol and n-propanol, are also demonstrated using a Cu catalyst. Finally, we show that our CO2 reduction cell with solid electrolytes can be modified to suit other, more complex practical applications. Liquid products from electrocatalytic CO2 reduction are often mixed with additional solutes in the electrolyte, meaning that downstream separation is required. Here, the authors design cells that use solid electrolytes to generate flows of CO2-derived liquid fuels with high concentrations that are free of extraneous ions.
380 citations
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TL;DR: New developments in spintronics based on antiferromagnetic materials show promise for improved fundamental understanding and applications in technology as mentioned in this paper, which is a promising area of research for spintronic applications.
Abstract: New developments in spintronics based on antiferromagnetic materials show promise for improved fundamental understanding and applications in technology.
379 citations
01 Apr 2016
TL;DR: The determination of band offsets in the heterostructure of transition metal dichalcogenides by using microbeam X-ray photoelectron spectroscopy and scanning tunnelling microscopy/spectroscopy shows that the electronic structures of WSe2 and MoS2 are well retained in their respective layers due to a weak interlayer coupling.
Abstract: The emergence of two-dimensional electronic materials has stimulated proposals of novel electronic and photonic devices based on the heterostructures of transition metal dichalcogenides. Here we report the determination of band offsets in the heterostructures of transition metal dichalcogenides by using microbeam X-ray photoelectron spectroscopy and scanning tunnelling microscopy/spectroscopy. We determine a type-II alignment between MoS2 and WSe2 with a valence band offset value of 0.83 eV and a conduction band offset of 0.76 eV. First-principles calculations show that in this heterostructure with dissimilar chalcogen atoms, the electronic structures of WSe2 and MoS2 are well retained in their respective layers due to a weak interlayer coupling. Moreover, a valence band offset of 0.94 eV is obtained from density functional theory, consistent with the experimental determination.
379 citations
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TL;DR: The read operation of memristor-based memories is investigated and a new technique for solving the sneak paths problem by gating the memory cell using a three-terminal memistor device is introduced.
378 citations
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TL;DR: The topology of a MOF has been used as an ideal blueprint for the deliberate design of a related MOF, by substitution of molecular building blocks with supermolecular building blocks.
Abstract: Metal-organic frameworks (MOFs) are a promising class of porous materials because it is possible to mutually control their porous structure, composition and functionality. However, it is still a challenge to predict the network topology of such framework materials prior to their synthesis. Here we use a new rare earth (RE) nonanuclear carboxylate-based cluster as an 18-connected molecular building block to form a gea-MOF (gea-MOF-1) based on a (3,18)-connected net. We then utilized this gea net as a blueprint to design and assemble another MOF (gea-MOF-2). In gea-MOF-2, the 18-connected RE clusters are replaced by metal-organic polyhedra, peripherally functionalized so as to have the same connectivity as the RE clusters. These metal-organic polyhedra act as supermolecular building blocks when they form gea-MOF-2. The discovery of a (3,18)-connected MOF followed by deliberate transposition of its topology to a predesigned second MOF with a different chemical system validates the prospective rational design of MOFs.
376 citations
Authors
Showing all 6430 results
Name | H-index | Papers | Citations |
---|---|---|---|
Jian-Kang Zhu | 161 | 550 | 105551 |
Jean M. J. Fréchet | 154 | 726 | 90295 |
Kevin Murphy | 146 | 728 | 120475 |
Jean-Luc Brédas | 134 | 1026 | 85803 |
Carlos M. Duarte | 132 | 1173 | 86672 |
Kazunari Domen | 130 | 908 | 77964 |
Jian Zhou | 128 | 3007 | 91402 |
Tai-Shung Chung | 119 | 879 | 54067 |
Donal D. C. Bradley | 115 | 652 | 65837 |
Lain-Jong Li | 113 | 627 | 58035 |
Hong Wang | 110 | 1633 | 51811 |
Peng Wang | 108 | 1672 | 54529 |
Juan Bisquert | 107 | 450 | 46267 |
Jian Zhang | 107 | 3064 | 69715 |
Karl Leo | 104 | 832 | 42575 |