Polytechnic University of Catalonia

About: Polytechnic University of Catalonia is a education organization based out in Barcelona, Spain. It is known for research contribution in the topics: Finite element method & Population. The organization has 16006 authors who have published 45325 publications receiving 949306 citations. The organization is also known as: UPC - BarcelonaTECH & Technical University of Catalonia.

Exceptional oxidation activity with size-controlled supported gold clusters of low atomicity

Abstract: The catalytic activity of gold depends on particle size, with the reactivity increasing as the particle diameter decreases. However, investigations into behaviour in the subnanometre regime (where gold exists as small clusters of a few atoms) began only recently with advances in synthesis and characterization techniques. Here we report an easy method to prepare isolated gold atoms supported on functionalized carbon nanotubes and their performance in the oxidation of thiophenol with O2. We show that single gold atoms are not active, but they aggregate under reaction conditions into gold clusters of low atomicity that exhibit a catalytic activity comparable to that of sulfhydryl oxidase enzymes. When clusters grow into larger nanoparticles, catalyst activity drops to zero. Theoretical calculations show that gold clusters are able to activate thiophenol and O2 simultaneously, and larger nanoparticles are passivated by strongly adsorbed thiolates. The combination of both reactants activation and facile product desorption makes gold clusters excellent catalysts.

Virtual Hand Illusion Induced by Visuomotor Correlations

Abstract: Background Our body schema gives the subjective impression of being highly stable. However, a number of easily-evoked illusions illustrate its remarkable malleability. In the rubber-hand illusion, illusory ownership of a rubber-hand is evoked by synchronous visual and tactile stimulation on a visible rubber arm and on the hidden real arm. Ownership is concurrent with a proprioceptive illusion of displacement of the arm position towards the fake arm. We have previously shown that this illusion of ownership plus the proprioceptive displacement also occurs towards a virtual 3D projection of an arm when the appropriate synchronous visuotactile stimulation is provided. Our objective here was to explore whether these illusions (ownership and proprioceptive displacement) can be induced by only synchronous visuomotor stimulation, in the absence of tactile stimulation. Methodology/Principal Findings To achieve this we used a data-glove that uses sensors transmitting the positions of fingers to a virtually projected hand in the synchronous but not in the asynchronous condition. The illusion of ownership was measured by means of questionnaires. Questions related to ownership gave significantly larger values for the synchronous than for the asynchronous condition. Proprioceptive displacement provided an objective measure of the illusion and had a median value of 3.5 cm difference between the synchronous and asynchronous conditions. In addition, the correlation between the feeling of ownership of the virtual arm and the size of the drift was significant. Conclusions/Significance We conclude that synchrony between visual and proprioceptive information along with motor activity is able to induce an illusion of ownership over a virtual arm. This has implications regarding the brain mechanisms underlying body ownership as well as the use of virtual bodies in therapies and rehabilitation.

Process Variation Tolerant 3T1D-Based Cache Architectures

Abstract: Process variations will greatly impact the stability, leakage power consumption, and performance of future microprocessors. These variations are especially detrimental to 6T SRAM (6-transistor static memory) structures and will become critical with continued technology scaling. In this paper, we propose new on-chip memory architectures based on novel 3T1D DRAM (3-transistor, 1-diode dynamic memory) cells. We provide a detailed comparison between 6T and 3T1D designs in the context of a L1 data cache. The effects of physical device variation on a 3T1D cache can be lumped into variation of data retention times. This paper proposes a range of cache refresh and placement schemes that are sensitive to reten- tion time, and we show that most of the retention time variations can be masked by the microarchitecture when using these schemes. We have performed detailed circuit and architectural simulations assuming different degrees of variability in advanced technology nodes, and we show that the resulting memory architecture can tol- erate large process variations with little or even no impact on per- formance when compared to ideal 6T SRAM designs. Furthermore, these designs are robust to memory cell stability issues and can achieve large power savings. These advantages make the new mem- ory architectures a promising choice for on-chip variation-tolerant cache structures required for next generation microprocessors.

Business model innovation in entrepreneurship

Abstract: The goal of this paper is to advance the understanding of emerging developments in business model design within the field of entrepreneurship. It is widely known that during the start-up process, entrepreneurs need to set up the boundaries of the business and define the product/service to offer. This is a very complex task, especially for new technology-based companies which usually require large investments and have a limited time span (avoiding product obsolescence) to turn the idea into a full-time venture. Although business model design within the entrepreneurship field is a recent topic, it is gaining a growing attention in the literature. The usefulness and predictable power of business models are expected to help entrepreneurs make more informed decisions, thus increasing the chances of success. This article first tackles the specific problems faced by new technology-based firms, linking their needs with the advantages of having a flexible and well-designed business model. Second, different innovative practices aimed at improving business model design are discussed. The paper ends with some recommendations, stressing the need for future empirical work.