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Physical and electrical properties of metal gate electrodes on HfO2 gate dielectrics

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TLDR
In this article, the authors evaluated the performance of metal-oxide-semiconductor field effect transistor (MOSFET) gate lengths for the dual-metal gate complementary metaloxide semiconductor using HfO2 as the gate dielectric.
Abstract
As the metal–oxide–semiconductor field-effect transistor (MOSFET) gate lengths scale down to 50 nm and below, the expected increase in gate leakage will be countered by the use of a high dielectric constant (high-k) gate oxide. The series capacitance from polysilicon gate electrode depletion significantly reduces the gate capacitance as the dielectric thickness is scaled to 10 A equivalent oxide thickness (EOT) or below. Metal gates promise to solve this problem and address other gate stack scaling concerns like boron penetration and elevated gate resistance. Extensive simulations have shown that the optimal gate work functions for the sub-50 nm channel lengths should be 0.2 eV below (above) the conduction (valence) band edge of silicon for n-type MOSFETs (p-type MOSFETs). This study summarizes the evaluations of TiN, Ta–Si–N, WN, TaN, TaSi, Ir, and IrO2 as candidate metals for dual-metal gate complementary metal–oxide semiconductor using HfO2 as the gate dielectric. The gate work function was determined ...

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Citations
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Journal ArticleDOI

Atomic Layer Deposition of Iridium Thin Films

TL;DR: In this paper, thin films of metallic iridium were grown by atomic layer deposition (ALD) in a wide temperature range of 225-375°C from tris(2,4-pentanedionato)iridium and oxygen.
Journal ArticleDOI

Effects of catalyst material and atomic layer deposited TiO2 oxide thickness on the water oxidation performance of metal–insulator–silicon anodes

TL;DR: In this article, the effects on water oxidation performance of varying nanoscale TiO2 thickness and the catalyst material in catalyst/TiO2/SiO 2/Si anodes were investigated.
Journal ArticleDOI

Fermi pinning-induced thermal instability of metal-gate work functions

TL;DR: In this article, a metal-dielectric interface model that takes the role of extrinsic states into account is proposed to explain the work function thermal instability, showing that increased Fermi-level pinning of the metal-gate work function with increased annealing temperature is more significant for SiO/ sub 2/ than for HfO/sub 2/ gate dielectric.
Journal ArticleDOI

Low-Temperature Deposition of TiN by Plasma-Assisted Atomic Layer Deposition

TL;DR: In this article, a plasma-assisted atomic layer deposition (PA-ALD) process was used for low-temperature deposition of high-quality TiN films at temperatures ranging from 100 to 400°C.
Journal ArticleDOI

The electrical and material characterization of hafnium oxynitride gate dielectrics with TaN-gate electrode

TL;DR: In this paper, the electrical and material characteristics of HfON gate dielectrics have been studied in comparison with HfO/sub 2/ by secondary ion mass spectroscopy (SIMS).
References
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Journal ArticleDOI

Tantalum‐based diffusion barriers in Si/Cu VLSI metallizations

TL;DR: In this article, sputter-deposited Ta, Ta36Si14, and Ta36 Si14N50 thin films are used as diffusion barriers between Cu overlayers and Si substrates.
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Impact of gate workfunction on device performance at the 50 nm technology node

TL;DR: In this paper, the optimal gate electrode work function was determined for the 50 nm technology node using a simulation strategy that takes into account the impact of short-channel effects on device performance in uniformly doped and super-steep-retrograde doped channels in conventional and dynamic threshold operation.
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Compatibility of polycrystalline silicon gate deposition with HfO2 and Al2O3/HfO2 gate dielectrics

TL;DR: In this paper, the same authors reported that chemical vapor deposition (CVD) silicon gates using silane deposited directly onto HfO2 results in electrical properties much worse compared to similar Hf O2 films using platinum metal gates.
Journal ArticleDOI

A dual-metal gate CMOS technology using nitrogen-concentration-controlled TiNx film

TL;DR: In this paper, a dual-metal gate CMOSFET with nitrogen-concentration-controlled TiNx film is described. Butler et al. found that threshold voltage (V/sub th/) depends on the concentration of nitrogen in theTiNx gate electrode.
Journal ArticleDOI

Atomic diameters, atomic volumes and solid solubility relations in alloys

TL;DR: In this paper, the use of the concepts of favourable and unfavourable size factor in predicting solid solubilities in metallic systems is discussed and it is shown that the atomic volumes do not correlate well with the solid solUBilities in alloy systems.
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