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Showing papers by "University of Massachusetts Amherst published in 2008"


01 Oct 2008
TL;DR: The database contains labeled face photographs spanning the range of conditions typically encountered in everyday life, and exhibits “natural” variability in factors such as pose, lighting, race, accessories, occlusions, and background.
Abstract: Most face databases have been created under controlled conditions to facilitate the study of specific parameters on the face recognition problem. These parameters include such variables as position, pose, lighting, background, camera quality, and gender. While there are many applications for face recognition technology in which one can control the parameters of image acquisition, there are also many applications in which the practitioner has little or no control over such parameters. This database, Labeled Faces in the Wild, is provided as an aid in studying the latter, unconstrained, recognition problem. The database contains labeled face photographs spanning the range of conditions typically encountered in everyday life. The database exhibits “natural” variability in factors such as pose, lighting, race, accessories, occlusions, and background. In addition to describing the details of the database, we provide specific experimental paradigms for which the database is suitable. This is done in an effort to make research performed with the database as consistent and comparable as possible. We provide baseline results, including results of a state of the art face recognition system combined with a face alignment system. To facilitate experimentation on the database, we provide several parallel databases, including an aligned version.

5,742 citations


Book
07 Mar 2008
TL;DR: Applied Survival Analysis, Second Edition is an ideal book for graduate-level courses in biostatistics, statistics, and epidemiologic methods and serves as a valuable reference for practitioners and researchers in any health-related field or for professionals in insurance and government.
Abstract: THE MOST PRACTICAL, UP-TO-DATE GUIDE TO MODELLING AND ANALYZING TIME-TO-EVENT DATANOW IN A VALUABLE NEW EDITION Since publication of the first edition nearly a decade ago, analyses using time-to-event methods have increase considerably in all areas of scientific inquiry mainly as a result of model-building methods available in modern statistical software packages. However, there has been minimal coverage in the available literature to9 guide researchers, practitioners, and students who wish to apply these methods to health-related areas of study. Applied Survival Analysis, Second Edition provides a comprehensive and up-to-date introduction to regression modeling for time-to-event data in medical, epidemiological, biostatistical, and other health-related research. This book places a unique emphasis on the practical and contemporary applications of regression modeling rather than the mathematical theory. It offers a clear and accessible presentation of modern modeling techniques supplemented with real-world examples and case studies. Key topics covered include: variable selection, identification of the scale of continuous covariates, the role of interactions in the model, assessment of fit and model assumptions, regression diagnostics, recurrent event models, frailty models, additive models, competing risk models, and missing data. Features of the Second Edition include: Expanded coverage of interactions and the covariate-adjusted survival functions The use of the Worchester Heart Attack Study as the main modeling data set for illustrating discussed concepts and techniques New discussion of variable selection with multivariable fractional polynomials Further exploration of time-varying covariates, complex with examples Additional treatment of the exponential, Weibull, and log-logistic parametric regression models Increased emphasis on interpreting and using results as well as utilizing multiple imputation methods to analyze data with missing values New examples and exercises at the end of each chapter Analyses throughout the text are performed using Stata Version 9, and an accompanying FTP site contains the data sets used in the book. Applied Survival Analysis, Second Edition is an ideal book for graduate-level courses in biostatistics, statistics, and epidemiologic methods. It also serves as a valuable reference for practitioners and researchers in any health-related field or for professionals in insurance and government.

3,507 citations


Journal ArticleDOI
TL;DR: An algorithm which automates the purposeful selection of covariates within which an analyst makes a variable selection decision at each step of the modeling process and has the capability of retaining important confounding variables, resulting potentially in a slightly richer model.
Abstract: Background The main problem in many model-building situations is to choose from a large set of covariates those that should be included in the "best" model. A decision to keep a variable in the model might be based on the clinical or statistical significance. There are several variable selection algorithms in existence. Those methods are mechanical and as such carry some limitations. Hosmer and Lemeshow describe a purposeful selection of covariates within which an analyst makes a variable selection decision at each step of the modeling process.

2,577 citations


Journal ArticleDOI
TL;DR: Gold nanoparticles provide non-toxic carriers for drug and gene delivery applications and their interaction with thiols is an effective and selective means of controlled intracellular release.

2,383 citations


Journal ArticleDOI
TL;DR: The authors evaluate participants from the 2003-2004 National Health and Nutrition Examination Survey aged >/=6 years who wore an activity monitor for up to 7 days to provide the first objective measure of the amount of time spent in sedentary behavior in the US population.
Abstract: Sedentary behaviors are linked to adverse health outcomes, but the total amount of time spent in these behaviors in the United States has not been objectively quantified. The authors evaluated participants from the 2003-2004 National Health and Nutrition Examination Survey aged >/=6 years who wore an activity monitor for up to 7 days. Among 6,329 participants with at least one 10-hour day of monitor wear, the average monitor-wearing time was 13.9 hours/day (standard deviation, 1.9). Overall, participants spent 54.9% of their monitored time, or 7.7 hours/day, in sedentary behaviors. The most sedentary groups in the United States were older adolescents and adults aged >/=60 years, and they spent about 60% of their waking time in sedentary pursuits. Females were more sedentary than males before age 30 years, but this pattern was reversed after age 60 years. Mexican-American adults were significantly less sedentary than other US adults, and White and Black females were similarly sedentary after age 12 years. These data provide the first objective measure of the amount of time spent in sedentary behavior in the US population and indicate that Americans spend the majority of their time in behaviors that expend very little energy.

2,380 citations


Journal ArticleDOI
TL;DR: In this article, the authors test meta-analytically the three most studied mediators: contact reduces prejudice by enhancing knowledge about the outgroup, reducing anxiety about intergroup contact, and increasing empathy and perspective taking.
Abstract: Recent years have witnessed a renewal of interest in intergroup contact theory. A meta-analysis of more than 500 studies established the theory's basic contention that intergroup contact typically reduces prejudices of many types. This paper addresses the issue of process: just how does contact diminish prejudice? We test meta-analytically the three most studied mediators: contact reduces prejudice by (1) enhancing knowledge about the outgroup, (2) reducing anxiety about intergroup contact, and (3) increasing empathy and perspective taking. Our tests reveal mediational effects for all three of these mediators. However, the mediational value of increased knowledge appears less strong than anxiety reduction and empathy. Limitations of the study and implications of the results are discussed. Copyright © 2008 John Wiley & Sons, Ltd.

1,886 citations


Journal ArticleDOI
TL;DR: A mathematical model of random viral evolution and phylogenetic tree construction is developed and used to analyze 3,449 complete env sequences derived by single genome amplification from 102 subjects with acute HIV-1 (clade B) infection, suggesting a finite window of potential vulnerability of HIV- 1 to vaccine-elicited immune responses, although phenotypic properties of transmitted Envs pose a formidable defense.
Abstract: The precise identification of the HIV-1 envelope glycoprotein (Env) responsible for productive clinical infection could be instrumental in elucidating the molecular basis of HIV-1 transmission and in designing effective vaccines. Here, we developed a mathematical model of random viral evolution and, together with phylogenetic tree construction, used it to analyze 3,449 complete env sequences derived by single genome amplification from 102 subjects with acute HIV-1 (clade B) infection. Viral env genes evolving from individual transmitted or founder viruses generally exhibited a Poisson distribution of mutations and star-like phylogeny, which coalesced to an inferred consensus sequence at or near the estimated time of virus transmission. Overall, 78 of 102 subjects had evidence of productive clinical infection by a single virus, and 24 others had evidence of productive clinical infection by a minimum of two to five viruses. Phenotypic analysis of transmitted or early founder Envs revealed a consistent pattern of CCR5 dependence, masking of coreceptor binding regions, and equivalent or modestly enhanced resistance to the fusion inhibitor T1249 and broadly neutralizing antibodies compared with Envs from chronically infected subjects. Low multiplicity infection and limited viral evolution preceding peak viremia suggest a finite window of potential vulnerability of HIV-1 to vaccine-elicited immune responses, although phenotypic properties of transmitted Envs pose a formidable defense.

1,880 citations


Journal ArticleDOI
TL;DR: In this article, the authors performed the largest ever particle simulation of a Milky Way sized dark matter halo, and presented the most comprehensive convergence study for an individual dark mass halo carried out thus far.
Abstract: We have performed the largest ever particle simulation of a Milky Way sized dark matter halo, and present the most comprehensive convergence study for an individual dark matter halo carried out thus far We have also simulated a sample of six ultrahighly resolved Milky Way sized haloes, allowing us to estimate the halo-to-halo scatter in substructure statistics In our largest simulation, we resolve nearly 300 000 gravitationally bound subhaloes within the virialized region of the halo Simulations of the same object differing in mass resolution by factors of up to 1800 accurately reproduce the largest subhaloes with the same mass, maximum circular velocity and position, and yield good convergence for the abundance and internal properties of dark matter substructures We detect up to four generations of subhaloes within subhaloes, but contrary to recent claims, we find less substructure in subhaloes than in the main halo when regions of equal mean overdensity are compared The overall substructure mass fraction is much lower in subhaloes than in the main halo Extrapolating the main halo's subhalo mass spectrum down to an Earth mass, we predict the mass fraction in substructure to be well below 3 per cent within 100 kpc, and to be below 01 per cent within the solar circle The inner density profiles of subhaloes show no sign of converging to a fixed asymptotic slope and are well fitted by gently curving profiles of Einasto form The mean concentrations of isolated haloes are accurately described by the fitting formula of Neto et al down to maximum circular velocities of 15 km s(-1), an extrapolation over some five orders of magnitude in mass However, at equal maximum circular velocity, subhaloes are more concentrated than field haloes, with a characteristic density that is typically similar to 26 times larger and increases with decreasing distance from halo centre

1,862 citations


Journal ArticleDOI
TL;DR: In this paper, the authors performed the largest ever particle simulation of a Milky Way-sized dark matter halo, and presented the most comprehensive convergence study for an individual dark matter Halo carried out thus far.
Abstract: We have performed the largest ever particle simulation of a Milky Way-sized dark matter halo, and present the most comprehensive convergence study for an individual dark matter halo carried out thus far. We have also simulated a sample of 6 ultra-highly resolved Milky-way sized halos, allowing us to estimate the halo-to-halo scatter in substructure statistics. In our largest simulation, we resolve nearly 300,000 gravitationally bound subhalos within the virialized region of the halo. Simulations of the same object differing in mass resolution by factors up to 1800 accurately reproduce the largest subhalos with the same mass, maximum circular velocity and position, and yield good convergence for the abundance and internal properties of dark matter substructures. We detect up to four generations of subhalos within subhalos, but contrary to recent claims, we find less substructure in subhalos than in the main halo when regions of equal mean overdensity are compared. The overall substructure mass fraction is much lower in subhalos than in the main halo. Extrapolating the main halo's subhalo mass spectrum down to an Earth mass, we predict the mass fraction in substructure to be well below 3% within 100 kpc, and to be below 0.1% within the Solar Circle. The inner density profiles of subhalos show no sign of converging to a fixed asymptotic slope and are well fit by gently curving profiles of Einasto form. The mean concentrations of isolated halos are accurately described by the fitting formula of Neto et al. down to maximum circular velocities of 1.5 km/s, an extrapolation over some 5 orders of magnitude in mass. However, at equal maximum circular velocity, subhalos are more concentrated than field halos, with a characteristic density that is typically ~2.6 times larger and increases towards the halo centre.

1,575 citations


Journal ArticleDOI
TL;DR: This Review provides an introduction to nanoparticle–biomolecular interactions as well as recent applications of nanoparticles in biological sensing, delivery, and imaging of live cells and tissues.
Abstract: The wide variety of core materials available, coupled with tunable surface properties, make nanoparticles an excellent platform for a broad range of biological and biomedical applications. This Review provides an introduction to nanoparticle–biomolecular interactions as well as recent applications of nanoparticles in biological sensing, delivery, and imaging of live cells and tissues.

1,399 citations


Journal ArticleDOI
TL;DR: While proteins and peptides have excellent potential as food antioxidants, issues such as allergenicity and bitter off-flavors as well as their ability to alter food texture and color need to be addressed.
Abstract: Proteins can inhibit lipid oxidation by biologically designed mechanisms (e.g. antioxidant enzymes and iron-binding proteins) or by nonspecific mechanisms. Both of these types of antioxidative proteins contribute to the endogenous antioxidant capacity of foods. Proteins also have excellent potential as antioxidant additives in foods because they can inhibit lipid oxidation through multiple pathways including inactivation of reactive oxygen species, scavenging free radicals, chelation of prooxidative transition metals, reduction of hydroperoxides, and alteration of the physical properties of food systems. A protein's overall antioxidant activity can be increased by disruption of its tertiary structure to increase the solvent accessibility of amino acid residues that can scavenge free radicals and chelate prooxidative metals. The production of peptides through hydrolytic reactions seems to be the most promising technique to form proteinaceous antioxidants since peptides have substantially higher antioxidant activity than intact proteins. While proteins and peptides have excellent potential as food antioxidants, issues such as allergenicity and bitter off-flavors as well as their ability to alter food texture and color need to be addressed.

Journal ArticleDOI
TL;DR: The results extend previous conclusions that recent Northern Hemisphere surface temperature increases are likely anomalous in a long-term context to at least the past 1,700 years, but with additional strong caveats.
Abstract: Following the suggestions of a recent National Research Council report [NRC (National Research Council) (2006) Surface Temperature Reconstructions for the Last 2,000 Years (Natl Acad Press, Washington, DC).], we reconstruct surface temperature at hemispheric and global scale for much of the last 2,000 years using a greatly expanded set of proxy data for decadal-to-centennial climate changes, recently updated instrumental data, and complementary methods that have been thoroughly tested and validated with model simulation experiments. Our results extend previous conclusions that recent Northern Hemisphere surface temperature increases are likely anomalous in a long-term context. Recent warmth appears anomalous for at least the past 1,300 years whether or not tree-ring data are used. If tree-ring data are used, the conclusion can be extended to at least the past 1,700 years, but with additional strong caveats. The reconstructed amplitude of change over past centuries is greater than hitherto reported, with somewhat greater Medieval warmth in the Northern Hemisphere, albeit still not reaching recent levels.

Journal ArticleDOI
TL;DR: This review summarizes the research progress of organic chemical adsorption on CNTs, and will provide useful information for CNT application and risk assessment.
Abstract: Carbon nanotubes (CNTs) have drawn special research attention because of their unique properties and potential applications. This review summarizes the research progress of organic chemical adsorption on CNTs, and will provide useful information for CNT application and risk assessment. Adsorption heterogeneity and hysteresis are two widely recognized features of organic chemical−CNT interactions. However, because different mechanisms may act simultaneously, mainly hydrophobic interactions, π−π bonds, electrostatic interactions, and hydrogen bonds, the prediction of organic chemical adsorption on CNTs is not straightforward. The dominant adsorption mechanism is different for different types of organic chemicals (such as polar and nonpolar), thus different models may be needed to predict organic chemical−CNT interaction. Adsorption mechanisms will be better understood by investigating the effects of properties of both CNTs and organic chemicals along with environmental conditions. Another major factor affec...

Journal ArticleDOI
TL;DR: The phytotoxicity of ZnO nanoparticles was not directly from their limited dissolution in the bulk nutrient solution or rhizosphere, implying that little (if any) Zn O nanoparticles could translocate up in the ryegrass in this study.
Abstract: Increasing application of nanotechnology highlights the need to clarify nanotoxicity. However, few researches have focused on phytotoxicity of nanomaterials; it is unknown whether plants can uptake and transport nanoparticles. This study was to examine cell internalization and upward translocation of ZnO nanoparticles by Lolium perenne (ryegrass). The dissolution of ZnO nanoparticles and its contribution to the toxicity on ryegrass were also investigated. Zn2+ ions were used to compare and verify the root uptake and phytotoxicity of ZnO nanoparticles in a hydroponic culture system. The root uptake and phytotoxicity were visualized by light, scanning electron, and transmission electron microscopies. In the presence of ZnO nanoparticles, ryegrass biomass significantly reduced, root tips shrank, and root epidermal and cortical cells highly vacuolated or collapsed. Zn2+ ion concentrations in bulk nutrient solutions with ZnO nanoparticles were lower than the toxicity threshold of Zn2+ to the ryegrass; shoot Zn...

Journal ArticleDOI
TL;DR: It is reported that the mammalian homologs Ezh1 and Ezh2 form similar PRC2 complexes but exhibit contrasting repressive roles, and Ez h1 knockdown was ineffectual on global H3K27me2/3 levels, while Ezh 1 directly and robustly represses transcription from chromatinized templates and compacts chromatin in the absence of the methyltransferase cofactor SAM.

Journal ArticleDOI
TL;DR: Broad application of microbial fuel cells will require substantial increases in current density and a better understanding of the microbiology of these systems may help.

Proceedings ArticleDOI
18 May 2008
TL;DR: This paper is the first in the community to use general-purpose software radios to analyze and attack previously unknown radio communications protocols, and introduces three new zero-power defenses based on RF power harvesting.
Abstract: Our study analyzes the security and privacy properties of an implantable cardioverter defibrillator (ICD). Introduced to the U.S. market in 2003, this model of ICD includes pacemaker technology and is designed to communicate wirelessly with a nearby external programmer in the 175 kHz frequency range. After partially reverse-engineering the ICD's communications protocol with an oscilloscope and a software radio, we implemented several software radio-based attacks that could compromise patient safety and patient privacy. Motivated by our desire to improve patient safety, and mindful of conventional trade-offs between security and power consumption for resource-constrained devices, we introduce three new zero-power defenses based on RF power harvesting. Two of these defenses are human-centric, bringing patients into the loop with respect to the security and privacy of their implantable medical devices (IMDs). Our contributions provide a scientific baseline for understanding the potential security and privacy risks of current and future IMDs, and introduce human-perceptible and zero-power mitigation techniques that address those risks. To the best of our knowledge, this paper is the first in our community to use general-purpose software radios to analyze and attack previously unknown radio communications protocols.

Journal ArticleDOI
TL;DR: The authors studied the formation of galaxies in a (50 Mpc/h)^3 cosmological simulation (2x288^3 particles), evolved using the entropy conserving SPH code Gadget-2.
Abstract: We study the formation of galaxies in a (50 Mpc/h)^3 cosmological simulation (2x288^3 particles), evolved using the entropy conserving SPH code Gadget-2. Most of the baryonic mass in galaxies of all masses is originally acquired through filamentary "cold mode" accretion of gas that was never shock heated to its halo virial temperature, confirming the key feature of our earlier results obtained with a different SPH code (Keres et al. 2005). Atmospheres of hot, virialized gas develop in halos above ~2.5e11 Msun, a transition mass that is nearly constant from z=3 to z=0. Cold accretion persists in halos above the transition mass, especially at z>=2. It dominates the growth of galaxies in low mass halos at all times, and it is the main driver of the cosmic star formation history. Satellite galaxies have accretion rates similar to central galaxies of the same baryonic mass at high redshifts, but they have less accretion than comparable central galaxies at low redshift. Relative to our earlier results, the Gadget-2 simulations predict much lower rates of "hot mode" accretion from the virialized gas component of massive halos. At z<=1, typical hot accretion rates in halos above 5e12 Msun are below 1 Msun/yr, even though our simulation does not include AGN heating or other forms of "preventive" feedback. The inner density profiles of hot gas in these halos are shallow, with long associated cooling times. The cooling recipes typically used in semi-analytic models can overestimate the accretion rates in these halos by orders of magnitude, so such models may overemphasize the role of preventive feedback in producing observed galaxy masses and colors. A fraction of the massive halos develop cuspy profiles and significant cooling rates between z=1 and z=0, a redshift trend similar to the observed trend in the frequency of cooling flow clusters.

Journal ArticleDOI
TL;DR: In this paper, the authors present a review of the state of the art in the field of middle management and provide a critique necessary for charting directions and enhancing the cumulative nature of future research.

Journal ArticleDOI
TL;DR: In un analisis multitemporal mediante tecnicas de teledeteccion and sistemas de informacion geografica (SIG) as discussed by the authors, Tullparaju, Palcacocha, Arhuaycocha, Pacliash, Ocshpalca, 513, Artizon Alto, Quitacoche, and Safuna Alta; estudios batimetricos indican las caracteristicas morfometricas de evolucion of las lagunas in their

Journal ArticleDOI
TL;DR: In this paper, the level of air pollution removal by green roofs in Chicago was quantified using a dry deposition model and the results showed that a total of 1675 kg of air pollutants was removed by 19.8 × 19.6 × 8.8 square feet of green roofs with O 3 accounting for 52% of the total, NO 2 (27%), PM 10 (14%), and SO 2 (7%).

Book
22 Jul 2008
TL;DR: A review of semisimple Lie algebras with highest weight modules can be found in this paper, along with a survey of the most commonly used symbols in the literature.
Abstract: Review of semisimple Lie algebras Highest weight modules: Category $\mathcal{O}$: Basics Characters of finite dimensional modules Category $\mathcal{O}$: Methods Highest weight modules I Highest weight modules II Extensions and resolutions Translation functors Kazhdan-Lusztig theory Further developments: Parabolic versions of category $\mathcal{O}$ Projective functors and principal series Tilting modules Twisting and completion functors Complements Bibliography Frequently used symbols Index.

Posted Content
TL;DR: In this paper, the authors examine corporate responses to climate change in relation to the development of reporting mechanisms for greenhouse gases, more specifically carbon disclosure, and develop a conceptual framework using theories of global governance, institutional theory, and commensuration to understand the role of carbon disclosure in the emerging climate regime.
Abstract: This paper examines corporate responses to climate change in relation to the development of reporting mechanisms for greenhouse gases, more specifically carbon disclosure. It first presents some background and context on the evolution of carbon trading and disclosure, and then develops a conceptual framework using theories of global governance, institutional theory, and commensuration to understand the role of carbon disclosure in the emerging climate regime. Subsequently a closer look is taken at carbon disclosure and reporting mechanisms, with a particular focus on the Carbon Disclosure Project (CDP). Our analysis of responses shows that CDP has been successfully using institutional investors to urge firms to disclose extensive information about their climate change activities. However, although response rates in terms of numbers of disclosing firms are impressive and growing, neither the level of carbon disclosure that CDP promotes nor the more detailed carbon accounting provide information that is particularly valuable for investors, NGOs, or policymakers at this stage. As a project of commensuration, carbon disclosure has achieved some progress in technical terms, but much less with regard to the cognitive and value dimensions.

Journal ArticleDOI
TL;DR: A novel dynamic provisioning technique for multi-tier Internet applications that employs a flexible queuing model to determine how much of the resources to allocate to each tier of the application, and a combination of predictive and reactive methods that determine when to provision these resources, both at large and small time scales is proposed.
Abstract: Dynamic capacity provisioning is a useful technique for handling the multi-time-scale variations seen in Internet workloads. In this article, we propose a novel dynamic provisioning technique for multi-tier Internet applications that employs (1) a flexible queuing model to determine how much of the resources to allocate to each tier of the application, and (2) a combination of predictive and reactive methods that determine when to provision these resources, both at large and small time scales. We propose a novel data center architecture based on virtual machine monitors to reduce provisioning overheads. Our experiments on a forty-machine Xen/Linux-based hosting platform demonstrate the responsiveness of our technique in handling dynamic workloads. In one scenario where a flash crowd caused the workload of a three-tier application to double, our technique was able to double the application capacity within five minutes, thus maintaining response-time targets. Our technique also reduced the overhead of switching servers across applications from several minutes to less than a second, while meeting the performance targets of residual sessions.

Journal ArticleDOI
TL;DR: It was evident that electron-donating substitution on the aromatic rings strengthened the pi-pi interaction between the aromatics and CNTs and thus the adsorption affinity, which will advance the understanding of the sorption behavior of C NTs in the environmental systems.
Abstract: With increasing production and application of carbon nanotubes (CNTs), it becomes necessary to understand the interaction between CNTs and aromatic compounds, an important group of organic contaminants and structural components of large organic molecules in biological systems. However, so far few experimental studies have been conducted to systematically investigate the sorption mechanism of polar aromatics to CNTs. Therefore, cyclohexanol, phenol, catechol, pyrogallol, 2-phenylphenol, 1-naphthol, and naphthalene were selected to investigate the role of aromatic structure and -OH substitution in the polar aromatics-CNTs system. Sorption affinity of these compounds by CNTs increased with increasing number of aromatic rings, with an order of cyclohexanol < phenol < 2-phenylphenol < 1-naphthol, and was greatly enhanced by -OH substitution, with an order of phenol (1 -OH) < catechol (2 -OH) < pyrogallol(3-OH). Four possible solute-sorbent interactions, i.e., hydrophobic effect, electrostatic interaction, hydrogen bonding, and pi-pi bonds, were discussed to addressthe underlying mechanism of the enhanced sorption affinity by -OH substitution. It was evident that electron-donating substitution on the aromatic rings strengthened the pi-pi interaction between the aromatics and CNTs and thus the adsorption affinity. These results will advance the understanding of the sorption behavior of CNTs in the environmental systems.

Journal ArticleDOI
TL;DR: It is reported that gasoline-range aromatics can be produced from solid biomass feedstocks in a single reactor at short residence times (less than 2 min) and intermediate temperatures (400–600 8C) by a method the authors call catalytic fast pyrolysis.
Abstract: Owing to its low cost and large availability, lignocellulosic biomass is being studied worldwide as a feedstock for renewable liquid biofuels. Lignocellulosic biomass is not currently used as a liquid fuel because economical processes for its conversion have not yet been developed. Currently, there are several routes being studied to convert solid biomass into a liquid fuel which involve multiple steps thus greatly increasing the cost of biomass conversion. For example, ethanol production from lignocellulosic biomass involves multiple steps including pretreatment, enzymatic or acid hydrolysis, fermentation, and distillation. Dumesic and co-workers have demonstrated that diesel-range alkanes can be produced by aqueous-phase processing (APP) of aqueous carbohydrate solutions at low temperatures (100-300 8C). APP first requires that solid lignocellulosic biomass be converted into aqueous carbohydrates, which would require pretreatment and hydrolysis steps. At high temperatures (~800 8C), Dauenhauer et al. have shown that solid biomass can be reformed to produce synthesis gas through partial oxidation in an autothermal packed bed reactor over Rh catalysts. The ideal process for solid biomass conversion involves the production of liquid fuels from solid biomass in a single step at short residence times. Herein, we report that gasoline-range aromatics can be produced from solid biomass feedstocks in a single reactor at short residence times (less than 2 min) and intermediate temperatures (400–600 8C) by a method we call catalytic fast pyrolysis. Fast pyrolysis involves rapidly heating biomass (500 8Cs ) to intermediate temperatures (400–600 8C) followed by rapid cooling (vapor residence times 1–2 s). Fast pyrolysis produces a thermally unstable liquid product called bio-oil, which is an acidic combustible liquid containing more than 300 compounds. Bio-oils are not compatible with existing liquid transportation fuels including gasoline and diesel. To use bio-oil as a conventional liquid transportation fuel, it must be catalytically upgraded. As we show here, introduction of zeolite catalysts into the pyrolysis process can convert oxygenated compounds generated by pyrolysis of the biomass into gasolinerange aromatics. Catalytic fast pyrolysis first involves pyrolysis of solid biomass (e.g. cellulose) into volatile organics, gases, and solid coke. The organics then enter the zeolite catalyst where they are converted into aromatics, carbon monoxide, carbon dioxide, water, and coke. Inside the zeolite catalyst, the biomassderived species undergo a series of dehydration, decarbonylation, decarboxylation, isomerization, oligomerization, and dehydrogenation reactions that lead to aromatics, CO, CO2, and water. The challenge with selectively producing aromatics is to minimize the undesired formation of coke, which can be from homogeneous gas-phase thermal decomposition reactions or from heterogeneous reactions on the catalyst. The overall stoichiometry for the conversion of xylitol and glucose into toluene, CO, and H2O is shown in Equation (1) (76 and 24% carbon yields) and Equation (2) (63 and 36% carbon yields), respectively. Oxygen must be removed from the biomass-derived species as a combination of CO (or CO2) and H2O when aromatics are produced. The maximum theoretical yield of toluene from xylitol and glucose is 76 and 63%, respectively, when CO and H2O are produced as by-products.

Journal ArticleDOI
TL;DR: The results suggest that the previously observed disparity in power production in pure and mixed culture microbial fuel cell systems can be attributed more to differences in the fuel cell designs than to any inherent superior capability of mixed cultures to produce more power than pure cultures.
Abstract: Summary It has been previously noted that mixed communities typically produce more power in microbial fuel cells than pure cultures. If true, this has important implications for the design of microbial fuel cells and for studying the process of electron transfer on anode biofilms. To further evaluate this, Geobacter sulfurreducens was grown with acetate as fuel in a continuous flow ‘ministack’ system in which the carbon cloth anode and cathode were positioned in close proximity, and the cation-selective membrane surface area was maximized in order to overcome some of the electrochemical limitations that were inherent in fuel cells previously employed for the study of pure cultures. Reducing the size of the anode in order to eliminate cathode limitation resulted in maximum current and power densities per m 2

Journal ArticleDOI
TL;DR: The impact of variation in pit structure on water transport in plants from the level of individual pits to the whole plant is addressed, indicating that pits are an important factor in the overall hydraulic efficiency of plants.
Abstract: Bordered pits are cavities in the lignified cell walls of xylem conduits (vessels and tracheids) that are essential components in the water-transport system of higher plants. The pit membrane, which lies in the center of each pit, allows water to pass between xylem conduits but limits the spread of embolism and vascular pathogens in the xylem. Averaged across a wide range of species, pits account for > 50% of total xylem hydraulic resistance, indicating that they are an important factor in the overall hydraulic efficiency of plants. The structure of pits varies dramatically across species, with large differences evident in the porosity and thickness of pit membranes. Because greater porosity reduces hydraulic resistance but increases vulnerability to embolism, differences in pit structure are expected to correlate with trade-offs between efficiency and safety of water transport. However, trade-offs in hydraulic function are influenced both by pit-level differences in structure (e.g. average porosity of pit membranes) and by tissue-level changes in conduit allometry (average length, diameter) and the total surface area of pit membranes that connects vessels. In this review we address the impact of variation in pit structure on water transport in plants from the level of individual pits to the whole plant.

Journal ArticleDOI
TL;DR: In this paper, the density profiles of relaxed CDM dark halos depend on redshift and on halo mass, and they are better approximated by the empirical formula, dlog ρ/dlog r ∝ r �, first used by Einasto to fit star counts in the Milky Way.
Abstract: We use two very large cosmological simulations to study how the density profiles of relaxedCDM dark halos depend on redshift and on halo mass. We confirm that these profiles deviate slightly but systematically from the NFW form and are better approximated by the empirical formula, dlog ρ/dlog r ∝ r � , first used by Einasto to fit star counts in the Milky Way. The best-fit value of the additional shape parameter, α, increases gradually with mass, from α ∼ 0.16 for present-day galaxy halos to α ∼ 0.3 for the rarest and most massive clusters. Halo concentrations depend only weakly on mass at z = 0, and this dependence weakens further at earlier times. At z ∼ 3 the average concentration of relaxed halos does not vary appreciably over the mass range accessible to our simulations (M ∼3×10 11 h −1 M⊙). Furthermore, in our biggest simulation, the average concentration of the most massive, relaxed halos is constant at h c200i ∼ 3.5 to 4 for 0 ≤ z ≤ 3. These results agree well with those of Zhao et al (2003b) and support the idea that halo densities reflect the density of the universe at the time they formed, as proposed by Navarro, Frenk & White (1997). With their original parameters, the NFW prescription overpredicts halo concentrations at high redshift. This shortcoming can be reduced by modifying the definition of halo formation time, although the evolution of the concentrations of Milky Way mass halos is still not reproduced well. In contrast, the much-used revisions of the NFW prescription by Bullock et al. (2001) and Eke, Navarro & Steinmetz (2001) predict a steeper drop in concentration at the highest masses and stronger evolution with redshift than are compatible with our numerical data. Modifying the parameters of these models can reduce the discrepancy at high masses, but the overly rapid redshift evolution remains. These results have important implications for currently planned surveys of distant clusters.

Journal ArticleDOI
TL;DR: In this article, the authors reported the results of a 100 deg2 survey of the Taurus molecular cloud region in 12CO and 13CO and determined that half the mass of the cloud is in regions having column density below 2.1 × 1021 cm−2.
Abstract: We report the results of a 100 deg2 survey of the Taurus molecular cloud region in 12CO and 13CO -->J = 1→ 0. The image of the cloud in each velocity channel includes -->3 × 106 Nyquist-sampled pixels on a 20 -->'' grid. The high sensitivity and large spatial dynamic range of the maps reveal a very complex, highly structured cloud morphology, including filaments, cavities, and rings. The axes of the striations seen in the 12CO emission from relatively diffuse gas are aligned with the direction of the magnetic field. We have developed a statistical method for analyzing the pixels in which 12CO but not 13CO is detected, which allows us to determine the CO column in the diffuse portion of the cloud, as well as in the denser regions in which we detect both isotopologues. Using a column-density-dependent model for the CO fractional abundance, we derive the mass of the region mapped to be -->2.4 × 104 M☉, more than twice as large as would be obtained using a canonical fixed fractional abundance of 13CO, and a factor of 3 greater than would be obtained considering only the high column density regions. We determine that half the mass of the cloud is in regions having column density below -->2.1 × 1021 cm−2. The distribution of young stars in the region covered is highly nonuniform, with the probability of finding a star in a pixel with a specified column density rising sharply for -->N(H2) = 6 × 1021 cm−2. We determine a relatively low star formation efficiency (mass of young stars/mass of molecular gas), between 0.3% and 1.2%, and an average star formation rate during the past 3 Myr of -->8 × 10−5 stars yr−1.