Showing papers on "Solar energy published in 2015"

Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway

Abstract: The use of solar energy to produce molecular hydrogen and oxygen (H2 and O2) from overall water splitting is a promising means of renewable energy storage. In the past 40 years, various inorganic and organic systems have been developed as photocatalysts for water splitting driven by visible light. These photocatalysts, however, still suffer from low quantum efficiency and/or poor stability. We report the design and fabrication of a metal-free carbon nanodot-carbon nitride (C3N4) nanocomposite and demonstrate its impressive performance for photocatalytic solar water splitting. We measured quantum efficiencies of 16% for wavelength λ = 420 ± 20 nanometers, 6.29% for λ = 580 ± 15 nanometers, and 4.42% for λ = 600 ± 10 nanometers, and determined an overall solar energy conversion efficiency of 2.0%. The catalyst comprises low-cost, Earth-abundant, environmentally friendly materials and shows excellent stability.

Solar Cell Efficiency Tables (Version 45)

Abstract: Consolidated tables showing an extensive listing of the highest independently confirmed efficiencies for solar cells and modules are presented. Guidelines for inclusion of results into these tables are outlined and new entries since July 2014 are reviewed. URI: http://onlinelibrary.wiley.com/doi/10.1002/pip.2573/pdf [1] Authors: GREEN Martin A. EMERY Keith HISHIKAWA Y. WARTA W. DUNLOP Ewan Publication Year: 2015 Type: Articles in Journals

Engineering heterogeneous semiconductors for solar water splitting

Abstract: There is a growing interest in the conversion of water and solar energy into clean and renewable H2 fuels using earth-abundant materials due to the depletion of fossil fuel and its serious environmental impact. This critical review highlights some key factors influencing the efficiency of heterogeneous semiconductors for solar water splitting (i.e. improved charge separation and transfer, promoted optical absorption, optimized band gap position, lowered cost and toxicity, and enhanced stability and water splitting kinetics). Moreover, different engineering strategies, such as band structure engineering, micro/nano engineering, bionic engineering, co-catalyst engineering, surface/interface engineering of heterogeneous semiconductors are summarized and discussed thoroughly. The synergistic effects of the different engineering strategies, especially for the combination of co-catalyst loading and other strategies seem to be more promising for the development of highly efficient photocatalysts. A thorough understanding of electron and hole transfer thermodynamics and kinetics at the fundamental level is also important for elucidating the key efficiency-limiting step and designing highly efficient solar-to-fuel conversion systems. In this review, we provide not only a summary of the recent progress in the different engineering strategies of heterogeneous semiconductors for solar water splitting, but also some potential opportunities for designing and optimizing solar cells, photocatalysts for the reduction of CO2 and pollutant degradation, and electrocatalysts for water splitting.

Halide perovskite materials for solar cells: a theoretical review

Abstract: Halide perovskites have recently emerged as promising materials for low-cost, high-efficiency solar cells. The efficiency of perovskite-based solar cells has increased rapidly, from 3.8% in 2009 to 19.3% in 2014, by using the all-solid-state thin-film architecture and engineering cell structures with mixed-halide perovskites. The emergence of perovskite solar cells revolutionized the field not only because of their rapidly increased efficiency, but also flexibility in material growth and architecture. The superior performance of the perovskite solar cells suggested that perovskite materials possess intrinsically unique properties. In this review, we summarize recent theoretical investigations into the structural, electrical, and optical properties of halide perovskite materials in relation to their applications in solar cells. We also discuss some current challenges of using perovskites in solar cells, along with possible theoretical solutions.

Hydrogen from photo-catalytic water splitting process: A review

Abstract: Recently, great attention has been focused on hydrogen as a potential energy vector and on the use of water-splitting technology as a clean and renewable means to generate hydrogen using solar energy. Numerous attempts have been made to develop photo-catalysts that work not only under UV light but also under visible-light illumination to efficiently utilize solar energy. One of the most well-known photo-catalysts used in the past forty years is TiO 2 . Despite having excellent characteristics as a photo-catalyst, TiO 2 also has some limitations. This paper presents modification techniques that can be used to improve the drawbacks of TiO 2 , such as the addition of sacrificial agents into the solution. The role of sacrificial agents, such as methanol and several recent achievements by previous researchers have also been included.

Research progress of perovskite materials in photocatalysis- and photovoltaics-related energy conversion and environmental treatment.

Abstract: Meeting the growing global energy demand is one of the important challenges of the 21st century. Currently over 80% of the world's energy requirements are supplied by the combustion of fossil fuels, which promotes global warming and has deleterious effects on our environment. Moreover, fossil fuels are non-renewable energy and will eventually be exhausted due to the high consumption rate. A new type of alternative energy that is clean, renewable and inexpensive is urgently needed. Several candidates are currently available such as hydraulic power, wind force and nuclear power. Solar energy is particularly attractive because it is essentially clean and inexhaustible. A year's worth of sunlight would provide more than 100 times the energy of the world's entire known fossil fuel reserves. Photocatalysis and photovoltaics are two of the most important routes for the utilization of solar energy. However, environmental protection is also critical to realize a sustainable future, and water pollution is a serious problem of current society. Photocatalysis is also an essential route for the degradation of organic dyes in wastewater. A type of compound with the defined structure of perovskite (ABX3) was observed to play important roles in photocatalysis and photovoltaics. These materials can be used as photocatalysts for water splitting reaction for hydrogen production and photo-degradation of organic dyes in wastewater as well as for photoanodes in dye-sensitized solar cells and light absorbers in perovskite-based solar cells for electricity generation. In this review paper, the recent progress of perovskites for applications in these fields is comprehensively summarized. A description of the basic principles of the water splitting reaction, photo-degradation of organic dyes and solar cells as well as the requirements for efficient photocatalysts is first provided. Then, emphasis is placed on the designation and strategies for perovskite catalysts to improve their photocatalytic activity and/or light adsorption capability. Comments on current and future challenges are also provided. The main purpose of this review paper is to provide a current summary of recent progress in perovskite materials for use in these important areas and to provide some useful guidelines for future development in these hot research areas.

Solar photocatalysis: Materials, reactors, some commercial, and pre-industrialized applications. A comprehensive approach

Abstract: In the future, solar energy, along with other renewable resources, could play a key role in mass production of fine chemicals. It could also potentially solve environmental problems, as demonstrated by recent developments in the use of solar energy, such as solar photocatalysis. The solar photocatalytic technology has been demonstrated to be effective for: • Treating groundwater, drinking water, industrial wastewater, and air and soil pollution, • Water disinfection, and • Industrial production of fine chemicals. This report summarizes the current status of solar photocatalysis and identifies future opportunities for research and industry in this field, including recent relevant bibliography. The main commercial solar photocatalytic applications are described, included the technologies based on sunlight for antifogging and self-cleaning of coating materials, glass, and concrete. An overview of several different solar photoreactors and the main operating process parameters are also provided. For the estimation of capital costs, it is suggested the use of appropriate “figures of merit”. The present review would be of interest for researchers, technologists, engineers, and industrialists.

Global Prospects, Progress, Policies and Environmental Impact of Solar Photovoltaic Power Generation

Abstract: Global energy demand and environmental concerns are the driving force for use of alternative, sustainable, and clean energy sources. Solar energy is the inexhaustible and CO2-emission-free energy source worldwide. The Sun provides 1.4 � 10 5 TW power as received on the surface of the Earth and about 3.6 � 10 4 TW of this power is usable. In 2012, world power consumption was 17 TW, which is less than 3.6 � 10 4 TW. Photovoltaic (PV) cells are the basic element for converting solar energy into electricity. PV cell technologies, energy conversion efficiency, economic analysis, energy policies, environmental impact, various applications, prospects, and progress have been comprehensively reviewed and presented in this paper. This work compiles the latest literature (i.e. journal articles, conference proceedings, and reports, among others) on PV power generation, economic analysis, environmental impact, and policies to increase public awareness. From the review, it was found that PV is an easy way to capture solar energy where PV based power generation has also rapidly increased.

Molecular helices as electron acceptors in high-performance bulk heterojunction solar cells

Abstract: Despite numerous organic semiconducting materials synthesized for organic photovoltaics in the past decade, fullerenes are widely used as electron acceptors in highly efficient bulk-heterojunction solar cells. None of the non-fullerene bulk heterojunction solar cells have achieved efficiencies as high as fullerene-based solar cells. Design principles for fullerene-free acceptors remain unclear in the field. Here we report examples of helical molecular semiconductors as electron acceptors that are on par with fullerene derivatives in efficient solar cells. We achieved an 8.3% power conversion efficiency in a solar cell, which is a record high for non-fullerene bulk heterojunctions. Femtosecond transient absorption spectroscopy revealed both electron and hole transfer processes at the donor-acceptor interfaces. Atomic force microscopy reveals a mesh-like network of acceptors with pores that are tens of nanometres in diameter for efficient exciton separation and charge transport. This study describes a new motif for designing highly efficient acceptors for organic solar cells.

Overgeneration from Solar Energy in California - A Field Guide to the Duck Chart

Abstract: In 2013, the California Independent System Operator published the "duck chart,"" which shows a significant drop in mid-day net load on a spring day as solar photovoltaics (PV) are added to the system. The chart raises concerns that the conventional power system will be unable to accommodate the ramp rate and range needed to fully utilize solar energy, particularly on days characterized by the duck shape. This could result in "overgeneration"" and curtailed renewable energy, increasing its costs and reducing its environmental benefits. This paper explores the duck chart in detail, examining how much PV might need to be curtailed if additional grid flexibility measures are not taken, and how curtailment rates can be decreased by changing grid operational practices. It finds that under business-as-usual types of assumptions and corresponding levels of grid flexibility in California, solar penetrations as low as 20 percent of annual energy could lead to marginal curtailment rates that exceed 30 percent. However, by allowing (or requiring) distributed PV and storage (including new installations that are part of the California storage mandate) to provide grid services, system flexibility could be greatly enhanced. Doing so could significantly reduce curtailment and allow much greater penetration of variable generationmore » resources in achieving a 50 percent renewable portfolio standard. Overall, the work described in this paper points to the need to fully integrate distributed resources into grid system planning and operations to allow maximum use of the solar resource.« less

Pathways for solar photovoltaics

Abstract: Solar energy is one of the few renewable, low-carbon resources with both the scalability and the technological maturity to meet ever-growing global demand for electricity. Among solar power technologies, solar photovoltaics (PV) are the most widely deployed, providing 0.87% of the world's electricity in 2013 and sustaining a compound annual growth rate in cumulative installed capacity of 43% since 2000. Given the massive scale of deployment needed, this article examines potential limits to PV deployment at the terawatt scale, emphasizing constraints on the use of commodity and PV-critical materials. We propose material complexity as a guiding framework for classifying PV technologies, and we analyze three core themes that focus future research and development: efficiency, materials use, and manufacturing complexity and cost.

Review of solar photovoltaic water pumping system technology for irrigation and community drinking water supplies

Abstract: The deficit in electricity and high diesel costs affects the pumping requirements of community water supplies and irrigation; so using solar energy for water pumping is a promising alternative to conventional electricity and diesel based pumping systems. Solar water pumping is based on photovoltaic (PV) technology that converts solar energy into electrical energy to run a DC or AC motor based water pump. The main objective of the study is to present a comprehensive literature review of solar pumping technology, evaluate the economic viability, identify research gaps and impediments in the widespread propagation of solar water pumping systems and technology. The study focuses on update on solar water pumping technology, performance analysis, optimum sizing, degradation of PV generator supplying power to pump, economic and environmental aspects and advances in PV materials and efficiency improvements. An update on the current state of research and utilization of solar water pumping technology is presented. Factors affecting performance of PV water pumping system, degradation of PV modules and efficiency improving techniques of PV water pumping systems are identified. Solar water pumping is found to be economically viable in comparison to electricity or diesel based systems for irrigation and water supplies in rural, urban and remote regions. The investment payback for some PV water pumping systems is found to be 4–6 years. The recent Indian incentives for PV pumping and policy initiatives for the promotion of solar water pumping in developing countries are also discussed. Potential follow-up research areas are also identified.

Aqueous dye-sensitized solar cells

Abstract: Nowadays, dye-sensitized solar cells (DSSCs) are the most extensively investigated systems for the conversion of solar energy into electricity, particularly for implementation in devices where low cost and good performance are required. Nevertheless, a key aspect is still to be addressed, being considered strongly harmful for a long time, which is the presence of water in the cell, either in the electrolyte or at the electrode/electrolyte interface. Here comes the present review, in the course of which we try our best to address the highly topical role of water in DSSCs, trying to figure out if it is a poisoner or the keyword to success, by means of a thoroughly detailed analysis of all the established phenomena in an aqueous environment. Actually, in the last few years the scientific community has suddenly turned its efforts in the direction of using water as a solvent, as demonstrated by the amount of research articles being published in the literature. Indeed, by means of DSSCs fabricated with water-based electrolytes, reduced costs, non-flammability, reduced volatility and improved environmental compatibility could be easily achieved. As a result, an increasing number of novel electrodes, dyes and electrolyte components are continuously proposed, being highly challenging from the materials science viewpoint and with the golden thread of producing truly water-based DSSCs. If the initial purpose of DSSCs was the construction of an artificial photosynthetic system able to convert solar light into electricity, the use of water as the key component may represent a great step forward towards their widespread diffusion in the market.

One-dimension-based spatially ordered architectures for solar energy conversion

Abstract: The severe consequences of fossil fuel consumption have resulted in a need for alternative sustainable sources of energy. Conversion and storage of solar energy via a renewable method, such as photocatalysis, holds great promise as such an alternative. One-dimensional (1D) nanostructures have gained attention in solar energy conversion because they have a long axis to absorb incident sunlight yet a short radial distance for separation of photogenerated charge carriers. In particular, well-ordered spatially high dimensional architectures based on 1D nanostructures with well-defined facets or anisotropic shapes offer an exciting opportunity for bridging the gap between 1D nanostructures and the micro and macro world, providing a platform for integration of nanostructures on a larger and more manageable scale into high-performance solar energy conversion applications. In this review, we focus on the progress of photocatalytic solar energy conversion over controlled one-dimension-based spatially ordered architecture hybrids. Assembly and classification of these novel architectures are summarized, and we discuss the opportunity and future direction of integration of 1D materials into high-dimensional, spatially organized architectures, with a perspective toward improved collective performance in various artificial photoredox applications.

Types of Solar Cells and Application

Abstract: A solar cell is an electronic device which directly converts sunlight into electricity. Light shining on the solar cell produces both a current and a voltage to generate electric power. This process requires firstly, a material in which the absorption of light raises an electron to a higher energy state, and secondly, the movement of this higher energy electron from the solar cell into an external circuit. The electron then dissipates its energy in the external circuit and returns to the solar cell. A variety of materials and processes can potentially satisfy the requirements for photovoltaic energy conversion, but in practice nearly all photovoltaic energy conversion uses semiconductor materials in the form of a p-n junction. With regard to the development of sustainable energy, such as solar energy, in this article we will Study types of solar cells and their applications

Modelling solar potential in the urban environment: State-of-the-art review

Abstract: Cityscapes provide a complex environment, where solar radiation is unevenly distributed, especially since urban features started to propagate more and more vertically. Due to the dynamic overshadowing effects present on building surfaces, quantifying these phenomena is essential for predicting reductions in solar radiation availability that can significantly affect potential for solar energy use. Numerical radiation algorithms coupled with GIS tools are a pathway to evaluate those complex effects. Accurate representation of the terrain, vegetation canopy and building structures allows better estimation of shadow patterns. Higher spatial and temporal resolutions deliver more detailed results, but models must compromise between accuracy and computation time. In this paper, models ranging from simple 2D visualization and solar constant methods, to more sophisticated 3D representation and analysis, are reviewed. Web-based solar maps, which rely on the previous features to successfully communicate the benefits of the solar resource to the public and support in the policy-making process, are also addressed.

A review on the applications of nanofluids in solar energy systems

Abstract: The negative impact of human activities on the environment receives tremendous attention, especially on the increased global temperature. To combat climate change, clean and sustainable energy sources need to be rapidly developed. Solar energy technology is considered as one of the ideal candidates, which directly converts solar energy into electricity and heat without any greenhouse gas emissions. In both areas, high-performance cooling, heating and electricity generation is one of the vital needs. Modern nanotechnology can produce metallic or nonmetallic particles of nanometer dimensions which have unique mechanical, optical, electrical, magnetic, and thermal properties. Studies in this field indicate that exploiting nanofluid in solar systems, offers unique advantages over conventional fluids. In this paper, the applications of nanofluids on different types of solar collectors, photovoltaic systems and solar thermoelectrics are reviewed. Beside the wide range of energy conversion, the efforts done on the energy storage system (ESS) have been reviewed. In the field of economics, nanotech reduces manufacturing costs as a result of using a low temperature process.

Particle suspension reactors and materials for solar-driven water splitting

Abstract: Reactors based on particle suspensions for the capture, conversion, storage, and use of solar energy as H2 are projected to be cost-competitive with fossil fuels. In light of this, this review paper summarizes state-of-the-art particle light absorbers and cocatalysts as suspensions (photocatalysts) that demonstrate visible-light-driven water splitting on the laboratory scale. Also presented are reactor descriptions, theoretical considerations particular to particle suspension reactors, and efficiency and performance characterization metrics. Opportunities for targeted research, analysis, and development of reactor designs are highlighted.

Efficient photosynthesis of carbon monoxide from CO2 using perovskite photovoltaics

Abstract: Artificial photosynthesis, mimicking nature in its efforts to store solar energy, has received considerable attention from the research community. Most of these attempts target the production of H2 as a fuel and our group recently demonstrated solar-to-hydrogen conversion at 12.3% efficiency. Here, in an effort to take this approach closer to real photosynthesis, which is based on the conversion of CO2, we demonstrate the efficient reduction of CO2 to carbon monoxide driven solely by simulated sunlight using water as the electron source. Employing series-connected perovskite photovoltaics and high-performance catalyst electrodes, we reach a solar-to-CO efficiency exceeding 6.5%, which represents a new benchmark in sunlight-driven CO2 conversion. Considering hydrogen as a secondary product, an efficiency exceeding 7% is observed. Furthermore, this study represents one of the first demonstrations of extended, stable operation of perovskite photovoltaics, whose large open-circuit voltage is shown to be particularly suited for this process.

A study on global solar PV energy developments and policies with special focus on the top ten solar PV power producing countries

Abstract: The mitigations of global energy demands, climate change and energy related greenhouse gas effects are the most important factors in the modern days. However, renewable energy is one of the alternative sources which has the capacity to mitigate all the above. Among all the renewable energy sources, solar energy is one of the most abundant and the cleanest energy source. Different laboratories of the world have achieved different solar cell efficiencies, which are also discussed in the present paper. This paper presents the global solar PV developments, per capita values, government supportive invectives and policies of the top ten solar power producing countries. This paper also presents the investments of the global solar energy among the countries. Finally, through the study, it is found that these top ten leading countries are following fulfilment of their projections, supportive tariff rates, net metering, green certificates and government incentive policies as their instruments.

Performance enhancement of solar collectors—A review

Abstract: Given rapid depletion of conventional energy sources and environmental degradation caused by their over exploitation, the renewable energy sources are believed to be the future. Technologies utilizing renewable energy sources differ significantly from one another, not only with regard to technical and economic aspects but also in relation to their reliability, maturity, and operational experience in utility scale conditions. Technologies used to harness solar energy have emerged as the most promising and mature since solar energy is abundant, freely available, and it has commercial potential too. This paper presents a review of advancements made in the field of solar thermal technology with a focus on techniques employed for its performance enhancement. It also covers the description of different types of solar collectors to facilitate the systematic understanding of solar thermal technology and the novel modifications realized in each category of solar collectors have been highlighted to promote the use of solar energy in routine activities. Performance enhancement techniques such as geometrical modifications on the absorber plate, use of solar selective coatings and nanofluids have been given a special attention.

Solar Cells: In Research and Applications—A Review

Abstract: The light from the Sun is a non-vanishing renewable source of energy which is free from environmental pollution and noise. It can easily compensate the energy drawn from the non-renewable sources of energy such as fossil fuels and petroleum deposits inside the earth. The fabrication of solar cells has passed through a large number of improvement steps from one generation to another. Silicon based solar cells were the first generation solar cells grown on Si wafers, mainly single crystals. Further development to thin films, dye sensitized solar cells and organic solar cells enhanced the cell efficiency. The development is basically hindered by the cost and efficiency. In order to choose the right solar cell for a specific geographic location, we are required to understand fundamental mechanisms and functions of several solar technologies that are widely studied. In this article, we have reviewed a progressive development in the solar cell research from one generation to other, and discussed about their future trends and aspects. The article also tries to emphasize the various practices and methods to promote the benefits of solar energy.

Progress and latest developments of evacuated tube solar collectors

Abstract: Solar energy is the most available, environmental friendly energy source and renewable to sustain the growing energy demand. Solar energy is captured by solar collectors and an evacuated solar collector is the most efficient and convenient collector among various kinds of solar collectors. In this paper, a comprehensive literature on why evacuated collector is preferable, types of evacuated collectors, their structure, applications and challenges have been reviewed. Latest up to date literature based on journal articles, web materials, reports, conference proceedings and thesis have been compiled and reported. Applications of evacuated solar collectors in water heating, heat engines, air conditioning, swimming pool heating, solar cooker, steam generation and solar drying for residential and industrial sectors have been summarized and presented. Collector efficiency of different types of evacuated collectors and their performance based on different working fluids have been reported as well. Based on the available literature, it has been found that an evacuated tube collector has higher efficiency than the other collector. An evacuated tube collector is also very efficient to be used at higher operating temperature. There are few challenges that have been identified and need to be addressed carefully before installing an evacuated tube solar collector. However, after critically analyzing the available literature, authors have presented some future recommendations to overcome the barriers and for enhanced performance of an evacuated tube solar collector.

A general framework for the assessment of solar fuel technologies

Abstract: The conversion of carbon dioxide and water into fuels in a solar refinery presents a potential solution for reducing greenhouse gas emissions, while providing a sustainable source of fuels and chemicals. Towards realizing such a solar refinery, there are many technological advances that must be met in terms of capturing and sourcing the feedstocks (namely CO2, H2O, and solar energy) and in catalytically converting CO2 and H2O. In the first part of this paper, we review the state-of-the-art in solar energy collection and conversion to solar utilities (heat, electricity, and as a photon source for photo-chemical reactions), CO2 capture and separation technology, and non-biological methods for converting CO2 and H2O to fuels. The two principal methods for CO2 conversion include (1) catalytic conversion using solar-derived hydrogen and (2) direct reduction of CO2 using H2O and solar energy. Both hydrogen production and direct CO2 reduction can be performed electro-catalytically, photo-electrochemically, photo-catalytically, and thermochemically. All four of these methods are discussed. In the second part of this paper, we utilize process modeling to assess the energy efficiency and economic feasibility of a generic solar refinery. The analysis demonstrates that the realization of a solar refinery is contingent upon significant technological improvements in all areas described above (solar energy capture and conversion, CO2 capture, and catalytic conversion processes).