Harbin Institute of Technology

About: Harbin Institute of Technology is a education organization based out in Harbin, China. It is known for research contribution in the topics: Microstructure & Control theory. The organization has 88259 authors who have published 109297 publications receiving 1603393 citations. The organization is also known as: HIT.

Atomically dispersed manganese catalysts for oxygen reduction in proton-exchange membrane fuel cells

Abstract: Platinum group metal (PGM)-free catalysts that are also iron free are highly desirable for the oxygen reduction reaction (ORR) in proton-exchange membrane fuel cells, as they avoid possible Fenton reactions. Here we report an efficient ORR catalyst that consists of atomically dispersed nitrogen-coordinated single Mn sites on partially graphitic carbon (Mn-N-C). Evidence for the embedding of the atomically dispersed MnN4 moieties within the carbon surface-exposed basal planes was established by X-ray absorption spectroscopy and their dispersion was confirmed by aberration-corrected electron microscopy with atomic resolution. The Mn-N-C catalyst exhibited a half-wave potential of 0.80 V versus the reversible hydrogen electrode, approaching that of Fe-N-C catalysts, along with significantly enhanced stability in acidic media. The encouraging performance of the Mn-N-C catalyst as a PGM-free cathode was demonstrated in fuel cell tests. First-principles calculations further support the MnN4 sites as the origin of the ORR activity via a 4e− pathway in acidic media. Platinum group metal- and iron-free catalysts are highly desirable for the oxygen reduction reaction in proton-exchange membrane fuel cells. Now, Wu and co-workers show a carbon catalyst with atomically dispersed single Mn sites as an efficient catalyst with enhanced stability in acidic media.

Target-dependent Twitter Sentiment Classification

Abstract: Sentiment analysis on Twitter data has attracted much attention recently. In this paper, we focus on target-dependent Twitter sentiment classification; namely, given a query, we classify the sentiments of the tweets as positive, negative or neutral according to whether they contain positive, negative or neutral sentiments about that query. Here the query serves as the target of the sentiments. The state-of-the-art approaches for solving this problem always adopt the target-independent strategy, which may assign irrelevant sentiments to the given target. Moreover, the state-of-the-art approaches only take the tweet to be classified into consideration when classifying the sentiment; they ignore its context (i.e., related tweets). However, because tweets are usually short and more ambiguous, sometimes it is not enough to consider only the current tweet for sentiment classification. In this paper, we propose to improve target-dependent Twitter sentiment classification by 1) incorporating target-dependent features; and 2) taking related tweets into consideration. According to the experimental results, our approach greatly improves the performance of target-dependent sentiment classification.

Photoredox functionalization of C–H bonds adjacent to a nitrogen atom

Abstract: The functionalization of C–H bonds and the visible light photoredox catalysis represent two prominent challenges in organic chemistry. In this regard, the combination of visible-light catalysis and C–H bond functionalization adjacent to a tertiary amine has been successfully developed in the past three years. In this tutorial review, we aim to give a brief overview of this issue and state the main results obtained in the reactions.

Activation of Peroxymonosulfate by Benzoquinone: A Novel Nonradical Oxidation Process

Abstract: The reactions between peroxymonosulfate (PMS) and quinones were investigated for the first time in this work, where benzoquinone (BQ) was selected as a model quinone. It was demonstrated that BQ could efficiently activate PMS for the degradation of sulfamethoxazole (SMX; a frequently detected antibiotic in the environments), and the degradation rate increased with solution pH from 7 to 10. Interestingly, quenching studies suggested that neither hydroxyl radical (•OH) nor sulfate radical (SO4•–) was produced therein. Instead, the generation of singlet oxygen (1O2) was proved by using two chemical probes (i.e., 2,2,6,6-tetramethyl-4-piperidinol and 9,10-diphenylanthracene) with the appearance of 1O2 indicative products detected by electron paramagnetic resonance spectrometry and liquid chromatography mass spectrometry, respectively. A catalytic mechanism was proposed involving the formation of a dioxirane intermediate between PMS and BQ and the subsequent decomposition of this intermediate into 1O2. Accordi...