University of Jyväskylä

About: University of Jyväskylä is a education organization based out in Jyvaskyla, Finland. It is known for research contribution in the topics: Population & Context (language use). The organization has 8066 authors who have published 25168 publications receiving 725033 citations. The organization is also known as: Jyväskylän yliopisto & Kasvatusopillinen korkeakoulu.

Electron Transfer from the Singlet and Triplet Excited States of Ru(dcbpy)2(NCS)2 into Nanocrystalline TiO2 Thin Films

Abstract: Time-resolved absorption spectroscopy was used to study the femtosecond and picosecond time scale electron injection from the excited singlet and triplet states of Ru(dcbpY)(2)(NCS)(2) (RuN3) into titanium dioxide (TiO2) nanocrystalline particle film in acetonitrile. The fastest resolved time constant of similar to30 fs was shown to reflect a sum of two parallel ultrafast processes, nonergodic electron transfer (ET) from the initially excited singlet state of RuN3 to the conduction band of TiO2 and intersystem crossing (ISC). The branching ratio of 1.5 between the two competing processes gives rate constants of 1/50 fs(-1) for ET and 1/75 fs(-1) for ISC. Following the ultrafast processes, a minor part of the electron injection (40%) occurs from the thermalized triplet state of RuN3 on the picosecond time scale. The kinetics of this slower phase of electron injection is nonexponential and can be fitted with time constants ranging from similar to1 to similar to60 ps.

Gas-filled recoil separator for studies of heavy elements

Abstract: A gas-filled recoil separator for the study of heavy elements has been constructed. The separator is of type QDQQ with the first, vertically focusing, quadrupole providing improved matching to the acceptance of the dipole magnet. The separator has been designed also for use in vacuum mode in which case a mass resolving power of ≈ 100 is estimated. The deflection angle is 25° and the radius of curvature is 1850 mm. Maximum beam rigidity is 2.2 T m. In the first experiments, new isotopes in the region Z = 85–90 have been synthesized.