scispace - formally typeset
Journal ArticleDOI

Carbon Materials for Chemical Capacitive Energy Storage

TLDR
In order to further improve the power and energy densities of the capacitors, carbon-based composites combining electrical double layer capacitors (EDLC)-capacitance and pseudo-Capacitance have been explored and show not only enhanced capacitance, but as well good cyclability.
Abstract
Carbon materials have attracted intense interests as electrode materials for electrochemical capacitors, because of their high surface area, electrical conductivity, chemical stability and low cost. Activated carbons produced by different activation processes from various precursors are the most widely used electrodes. Recently, with the rapid growth of nanotechnology, nanostructured electrode materials, such as carbon nanotubes and template-synthesized porous carbons have been developed. Their unique electrical properties and well controlled pore sizes and structures facilitate fast ion and electron transportation. In order to further improve the power and energy densities of the capacitors, carbon-based composites combining electrical double layer capacitors (EDLC)-capacitance and pseudo-capacitance have been explored. They show not only enhanced capacitance, but as well good cyclability. In this review, recent progresses on carbon-based electrode materials are summarized, including activated carbons, carbon nanotubes, and template-synthesized porous carbons, in particular mesoporous carbons. Their advantages and disadvantages as electrochemical capacitors are discussed. At the end of this review, the future trends of electrochemical capacitors with high energy and power are proposed.

read more

Citations
More filters
Journal ArticleDOI

Leaf-inspired interwoven carbon nanosheet/nanotube homostructures for supercapacitors with high energy and power densities

TL;DR: In this article, an environmentally friendly one-pot strategy for the synthesis of interwoven carbon nanotube (CNT)/carbon nanosheet (CNS) sandwiches in a molten salt was reported.
Journal ArticleDOI

Scalable fabrication of exceptional 3D carbon networks for supercapacitors

TL;DR: In this article, a facile and exclusive approach is presented toward the scalable preparation of novel 3D porous carbon networks using relatively low-cost commercial cotton, which can be directly utilized in flexible all-solid-state supercapacitors, which exhibit considerably satisfactory energy storage performance and excellent cycling stability.
Journal ArticleDOI

Blue energy harvesting on nanostructured carbon materials

TL;DR: In this article, the authors focus on the concept of harvesting energy from water-carbon interfaces and summarize the materials, structural design and electricity harvesting mechanism of devices, and discuss three promising mechanisms of nanogenerators, namely, sliding droplets, flowing water and phase change processes.
Journal ArticleDOI

Synthesis of honeycomb MnO 2 nanospheres/carbon nanoparticles/graphene composites as electrode materials for supercapacitors

TL;DR: In this article, a novel honeycomb MnO 2 nanospheres/carbon nanoparticles/graphene composites has been fabricated through freeze-drying method, and the honeycomb NMO 2 nanopheres are well inserted and dispersed on the graphene.
Journal ArticleDOI

Homogenous incorporation of SnO2 nanoparticles in carbon cryogels via the thermal decomposition of stannous sulfate and their enhanced lithium-ion intercalation properties

TL;DR: An impregnation-calcination method based on the thermal decomposition of stannous sulfate is developed to prepare carbon cryogel-tin oxide nanocomposites with less impurity for anode materials of lithium-ion batteries as discussed by the authors.
References
More filters
Journal ArticleDOI

Electric Field Effect in Atomically Thin Carbon Films

TL;DR: Monocrystalline graphitic films are found to be a two-dimensional semimetal with a tiny overlap between valence and conductance bands and they exhibit a strong ambipolar electric field effect.
Journal ArticleDOI

The rise of graphene

TL;DR: Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed-matter physics, where quantum relativistic phenomena can now be mimicked and tested in table-top experiments.
Journal ArticleDOI

The electronic properties of graphene

TL;DR: In this paper, the basic theoretical aspects of graphene, a one-atom-thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations, are discussed.
Journal ArticleDOI

Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)

TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
Journal ArticleDOI

Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
Related Papers (5)