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Carbon Materials for Chemical Capacitive Energy Storage

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TLDR
In order to further improve the power and energy densities of the capacitors, carbon-based composites combining electrical double layer capacitors (EDLC)-capacitance and pseudo-Capacitance have been explored and show not only enhanced capacitance, but as well good cyclability.
Abstract
Carbon materials have attracted intense interests as electrode materials for electrochemical capacitors, because of their high surface area, electrical conductivity, chemical stability and low cost. Activated carbons produced by different activation processes from various precursors are the most widely used electrodes. Recently, with the rapid growth of nanotechnology, nanostructured electrode materials, such as carbon nanotubes and template-synthesized porous carbons have been developed. Their unique electrical properties and well controlled pore sizes and structures facilitate fast ion and electron transportation. In order to further improve the power and energy densities of the capacitors, carbon-based composites combining electrical double layer capacitors (EDLC)-capacitance and pseudo-capacitance have been explored. They show not only enhanced capacitance, but as well good cyclability. In this review, recent progresses on carbon-based electrode materials are summarized, including activated carbons, carbon nanotubes, and template-synthesized porous carbons, in particular mesoporous carbons. Their advantages and disadvantages as electrochemical capacitors are discussed. At the end of this review, the future trends of electrochemical capacitors with high energy and power are proposed.

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Citations
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Twisted yarns for fiber-shaped supercapacitors based on wetspun PEDOT:PSS fibers from aqueous coagulation

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Condiment-Derived 3D Architecture Porous Carbon for Electrochemical Supercapacitors

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Recent advances on multi-component hybrid nanostructures for electrochemical capacitors

TL;DR: In this article, a review summarizes the most recent progress in the development of nanostructured electrode materials for energy storage, with a particular focus on these nanostructure that integrate carbon materials, metal oxides/hydroxides and conducting polymers for enhancing energy storage performances.
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A novel strategy for the synthesis of highly stable ternary SiOx composites for Li-ion-battery anodes

TL;DR: In this paper, a 3D interconnected SiOx/nitrogen-doped carbon (SC) framework provides sufficient void spaces for relieving the volume change during the lithiation process while facilitating electrolyte infiltration and lithium ion diffusion processes.
Journal ArticleDOI

High electrochemical capacitor performance of oxygen and nitrogen enriched activated carbon derived from the pyrolysis and activation of squid gladius chitin

TL;DR: In this article, the authors reported the synthesis of microporous oxygen and nitrogen doped activated carbon utilizing chitin from the gladius of squid fish, which has large surface area of 1129m2m2g−1 with microporus network and possess ∼4.04% of nitrogen content in the form of pyridinic/pyrrolic-N, graphitic-N and Noxide groups along with oxygen and carbon species.
References
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Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
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