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Journal ArticleDOI

Carbon Materials for Chemical Capacitive Energy Storage

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TLDR
In order to further improve the power and energy densities of the capacitors, carbon-based composites combining electrical double layer capacitors (EDLC)-capacitance and pseudo-Capacitance have been explored and show not only enhanced capacitance, but as well good cyclability.
Abstract
Carbon materials have attracted intense interests as electrode materials for electrochemical capacitors, because of their high surface area, electrical conductivity, chemical stability and low cost. Activated carbons produced by different activation processes from various precursors are the most widely used electrodes. Recently, with the rapid growth of nanotechnology, nanostructured electrode materials, such as carbon nanotubes and template-synthesized porous carbons have been developed. Their unique electrical properties and well controlled pore sizes and structures facilitate fast ion and electron transportation. In order to further improve the power and energy densities of the capacitors, carbon-based composites combining electrical double layer capacitors (EDLC)-capacitance and pseudo-capacitance have been explored. They show not only enhanced capacitance, but as well good cyclability. In this review, recent progresses on carbon-based electrode materials are summarized, including activated carbons, carbon nanotubes, and template-synthesized porous carbons, in particular mesoporous carbons. Their advantages and disadvantages as electrochemical capacitors are discussed. At the end of this review, the future trends of electrochemical capacitors with high energy and power are proposed.

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Citations
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Needle-like polyaniline nanowires on graphite nanofibers: hierarchical micro/nano-architecture for high performance supercapacitors

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Improved electrochemical performances of CuCo2O4/CuO nanocomposites for asymmetric supercapacitors

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Hierarchical porous carbon microrods derived from albizia flowers for high performance supercapacitors

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Photoluminescent Carbon Nanostructures

TL;DR: In this paper, a critical review of photoluminescence properties, their control, and origin in various carbon allotropes and their composites is presented, involving excitonic PL in carbon nanotubes, thermally activated delayed fluorescence in spherical fullerenes, the presence of impurity-vacancy color centers in nanodiamonds, aromatic sp2 domains in reduced graphene oxide, and surface chromophores or defect-related PL in Carbon dots.
References
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Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
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