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Carbon Materials for Chemical Capacitive Energy Storage

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TLDR
In order to further improve the power and energy densities of the capacitors, carbon-based composites combining electrical double layer capacitors (EDLC)-capacitance and pseudo-Capacitance have been explored and show not only enhanced capacitance, but as well good cyclability.
Abstract
Carbon materials have attracted intense interests as electrode materials for electrochemical capacitors, because of their high surface area, electrical conductivity, chemical stability and low cost. Activated carbons produced by different activation processes from various precursors are the most widely used electrodes. Recently, with the rapid growth of nanotechnology, nanostructured electrode materials, such as carbon nanotubes and template-synthesized porous carbons have been developed. Their unique electrical properties and well controlled pore sizes and structures facilitate fast ion and electron transportation. In order to further improve the power and energy densities of the capacitors, carbon-based composites combining electrical double layer capacitors (EDLC)-capacitance and pseudo-capacitance have been explored. They show not only enhanced capacitance, but as well good cyclability. In this review, recent progresses on carbon-based electrode materials are summarized, including activated carbons, carbon nanotubes, and template-synthesized porous carbons, in particular mesoporous carbons. Their advantages and disadvantages as electrochemical capacitors are discussed. At the end of this review, the future trends of electrochemical capacitors with high energy and power are proposed.

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Citations
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Journal ArticleDOI

Nanocomposites of palladium nanoparticle-loaded mesoporous carbon nanospheres for the electrochemical determination of hydrogen peroxide.

TL;DR: By using Pd/MCNs as the catalyst matrices to modify the surface of glassy carbon electrode, a nonenzymatic sensor was developed for the determination of hydrogen peroxide and shows excellent stability and anti-interference capability for the detection of H(2)O(2).
Journal ArticleDOI

Fabrication of Nitrogen-Doped Hollow Mesoporous Spherical Carbon Capsules for Supercapacitors.

TL;DR: A novel "dissolution-capture" method for the fabrication of nitrogen-doped hollow mesoporous spherical carbon capsules (N-HMSCCs) with high capability for supercapacitor is developed and should give a useful enlightenment for the design of electrode materials for super capacitor.
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Gamma-Irradiated Carbon Nanotube Yarn As Substrate for High-Performance Fiber Supercapacitors

TL;DR: When coated with high-performance polyaniline nanowires, the gamma-irradiated carbon nanotube yarn acts as a high-strength reinforcement and high-efficiency current collector in two-ply yarn supercapacitors for transporting charges generated along the long electrodes.
Journal ArticleDOI

2D Redox-Active Covalent Organic Frameworks for Supercapacitors: Design, Synthesis, and Challenges

TL;DR: In this article, a review summarizes the design principles and synthetic methods of redox-active COFs, with a focus on surveying the representative advances in supercapacitors, highlighting the key progress, major challenges and future directions in this promising field.
Journal ArticleDOI

Rational design of reduced graphene oxide for superior performance of supercapacitor electrodes

TL;DR: In this article, the authors analyzed how diverse oxidation-reduction strategies commonly used can result in considerable performance differences of reduced graphene oxide (rGO) for supercapacitor applications.
References
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Journal ArticleDOI

Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
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