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Carbon Materials for Chemical Capacitive Energy Storage

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TLDR
In order to further improve the power and energy densities of the capacitors, carbon-based composites combining electrical double layer capacitors (EDLC)-capacitance and pseudo-Capacitance have been explored and show not only enhanced capacitance, but as well good cyclability.
Abstract
Carbon materials have attracted intense interests as electrode materials for electrochemical capacitors, because of their high surface area, electrical conductivity, chemical stability and low cost. Activated carbons produced by different activation processes from various precursors are the most widely used electrodes. Recently, with the rapid growth of nanotechnology, nanostructured electrode materials, such as carbon nanotubes and template-synthesized porous carbons have been developed. Their unique electrical properties and well controlled pore sizes and structures facilitate fast ion and electron transportation. In order to further improve the power and energy densities of the capacitors, carbon-based composites combining electrical double layer capacitors (EDLC)-capacitance and pseudo-capacitance have been explored. They show not only enhanced capacitance, but as well good cyclability. In this review, recent progresses on carbon-based electrode materials are summarized, including activated carbons, carbon nanotubes, and template-synthesized porous carbons, in particular mesoporous carbons. Their advantages and disadvantages as electrochemical capacitors are discussed. At the end of this review, the future trends of electrochemical capacitors with high energy and power are proposed.

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Citations
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Ultrafinely dispersed Pd nanoparticles on a CN@MgO hybrid as a bifunctional catalyst for upgrading bioderived compounds

TL;DR: In this paper, a novel and sustainable synthesis of a Pd/CN@MgO catalyst is presented, offering a bifunctional catalyst with high catalytic activity towards a tandem aldol condensation-hydrogenation reaction of furfural with acetone in a one-pot reactor.
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Natural Cellulose Materials for Supercapacitors

TL;DR: In this paper, a two-stage carbonisation process was used to convert cellulose from cotton pulp into high-quality carbon-based materials for supercapacitor applications, and the resultant materials were characterized using a range of physical methods, along with cyclic voltammetry and galvanostatic discharge techniques to measure the specific capacitance of the materials formed.
Journal ArticleDOI

Preparation of hierarchical porous carbon from waste printed circuit boards for high performance electric double-layer capacitors

TL;DR: In this paper, a hierarchical porous carbons (ACs) were synthesized from non-metallic fractions (NMF) of waste printed circuit boards (PCB) to offer a great potential for applications of electrochemical double-layer capacitors (EDLCs).
Journal ArticleDOI

Walnut shell-derived hierarchical porous carbon with high performances for electrocatalytic hydrogen evolution and symmetry supercapacitors

TL;DR: In this article, a hierarchical porous carbon material was successfully synthesized by the efficient KOH activation process, which has the specific micropore area of 1037.31m2g−1 and micropores volume of 0.51cm3g− 1, which leads to have electrochemical performances of the hydrogen evolution reaction and supercapacitors.
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Polybenzoxazine-based nitrogen-containing porous carbons for high-performance supercapacitor electrodes and carbon dioxide capture

TL;DR: In this paper, a supercapacitor electrode material and CO2 adsorbents were synthesized from a novel nitrile-functional polybenzoxazine through a soft-templating method and KOH chemical activation.
References
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Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
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