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Journal ArticleDOI

Carbon Materials for Chemical Capacitive Energy Storage

TLDR
In order to further improve the power and energy densities of the capacitors, carbon-based composites combining electrical double layer capacitors (EDLC)-capacitance and pseudo-Capacitance have been explored and show not only enhanced capacitance, but as well good cyclability.
Abstract
Carbon materials have attracted intense interests as electrode materials for electrochemical capacitors, because of their high surface area, electrical conductivity, chemical stability and low cost. Activated carbons produced by different activation processes from various precursors are the most widely used electrodes. Recently, with the rapid growth of nanotechnology, nanostructured electrode materials, such as carbon nanotubes and template-synthesized porous carbons have been developed. Their unique electrical properties and well controlled pore sizes and structures facilitate fast ion and electron transportation. In order to further improve the power and energy densities of the capacitors, carbon-based composites combining electrical double layer capacitors (EDLC)-capacitance and pseudo-capacitance have been explored. They show not only enhanced capacitance, but as well good cyclability. In this review, recent progresses on carbon-based electrode materials are summarized, including activated carbons, carbon nanotubes, and template-synthesized porous carbons, in particular mesoporous carbons. Their advantages and disadvantages as electrochemical capacitors are discussed. At the end of this review, the future trends of electrochemical capacitors with high energy and power are proposed.

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Citations
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Journal ArticleDOI

Tailoring Polymer Colloids Derived Porous Carbon Spheres Based on Specific Chemical Reactions.

TL;DR: The perspectives for the development of polymer derived porous carbon spheres are provided based on the controlled synthesis of polymer colloids and optimization over the carbonization process to achieve highly functionalized carbon spheres for practical applications.
Journal ArticleDOI

Naturally derived porous carbon with selective metal- and/or nitrogen-doping for efficient CO2 capture and oxygen reduction

TL;DR: A heterogeneously porous green carbon structure was derived from abundant London plane leaves and showed excellent performance for both CO2 capture and Oxygen Reduction Reaction (ORR) as mentioned in this paper.
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Nitrogen-doped porous carbon/graphene nanosheets derived from two-dimensional conjugated microporous polymer sandwiches with promising capacitive performance

TL;DR: In this paper, the authors used 4-iodophenyl-substituted graphene (RGO-I) as a building block and a structure directing template for the construction of nitrogen-rich graphene-CMP (GMP) sandwiches.
Journal ArticleDOI

A review on the use of carbon nanostructured materials in electrochemical capacitors

TL;DR: In this paper, a review of the current status of carbon nanomaterials, such as carbon nanotubes, nanofibers, nano-onions, nanorods, fullerenes and graphene nanosheets, in ECs is reviewed.
Journal ArticleDOI

Recent Advances in Cobalt Based Heterogeneous Catalysts for Oxygen Evolution Reaction

TL;DR: Cobalt-based catalysts are the state-of-the-art catalyst used for OER currently as mentioned in this paper, which has received massive appreciation for performing as an excellent OER catalyst and has shown low overpotential with high long-term stability.
References
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Journal ArticleDOI

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TL;DR: In this paper, the basic theoretical aspects of graphene, a one-atom-thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations, are discussed.
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Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)

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Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
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