Journal ArticleDOI
Unraveling Nanotubes: Field Emission from an Atomic Wire
Andrew G. Rinzler,Jason H. Hafner,Pavel Nikolaev,Peter Nordlander,Daniel T. Colbert,Richard E. Smalley,Liang Lou,Seong-Gon Kim,David Tománek +8 more
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TLDR
Field emission of electrons from individually mounted carbon nanotubes has been found to be dramatically enhanced when the nanotube tips are opened by laser evaporation or oxidative etching, in a process that resembles unraveling the sleeve of a sweater.Abstract:
Field emission of electrons from individually mounted carbon nanotubes has been found to be dramatically enhanced when the nanotube tips are opened by laser evaporation or oxidative etching. Emission currents of 0.1 to 1 microampere were readily obtained at room temperature with bias voltages of less than 80 volts. The emitting structures are concluded to be linear chains of carbon atoms, Cn, (n = 10 to 100), pulled out from the open edges of the graphene wall layers of the nanotube by the force of the electric field, in a process that resembles unraveling the sleeve of a sweater.read more
Citations
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Carbon Nanotubes--the Route Toward Applications
TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Journal ArticleDOI
Crystalline Ropes of Metallic Carbon Nanotubes
Andreas Thess,R. S. Lee,Pavel Nikolaev,Hongjie Dai,Pierre Petit,J. Robert,Chunhui Xu,Young Hee Lee,Seong-Gon Kim,Andrew G. Rinzler,Daniel T. Colbert,Gustavo E. Scuseria,David Tománek,John E. Fischer,Richard E. Smalley +14 more
TL;DR: X-ray diffraction and electron microscopy showed that fullerene single-wall nanotubes (SWNTs) are nearly uniform in diameter and that they self-organize into “ropes,” which consist of 100 to 500 SWNTs in a two-dimensional triangular lattice with a lattice constant of 17 angstroms.
Journal ArticleDOI
Nanometre diameter fibres of polymer, produced by electrospinning
Darrell H. Reneker,Iksoo Chun +1 more
TL;DR: More than 20 polymers, including polyethylene oxide, nylon, polyimide, DNA, polyaramid, and polyaniline, have been electrospun in this paper.
Journal ArticleDOI
Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems
Andrea C. Ferrari,Francesco Bonaccorso,Francesco Bonaccorso,Vladimir I. Fal'ko,Konstantin S. Novoselov,Stephan Roche,Peter Bøggild,Stefano Borini,Frank H. L. Koppens,Vincenzo Palermo,Nicola M. Pugno,Nicola M. Pugno,Nicola M. Pugno,Jose A. Garrido,Roman Sordan,Alberto Bianco,Laura Ballerini,Maurizio Prato,Elefterios Lidorikis,Jani Kivioja,Claudio Marinelli,Tapani Ryhänen,Alberto F. Morpurgo,Jonathan N. Coleman,Valeria Nicolosi,Luigi Colombo,Albert Fert,Albert Fert,Mar García-Hernández,Adrian Bachtold,Grégory F. Schneider,Francisco Guinea,Cees Dekker,Matteo Barbone,Zhipei Sun,Costas Galiotis,Alexander N. Grigorenko,Gerasimos Konstantatos,Andras Kis,Mikhail I. Katsnelson,Lieven M. K. Vandersypen,A. Loiseau,Vittorio Morandi,Daniel Neumaier,Emanuele Treossi,Vittorio Pellegrini,Vittorio Pellegrini,Marco Polini,Alessandro Tredicucci,Gareth M. Williams,Byung Hee Hong,Jong Hyun Ahn,Jong Min Kim,Herbert Zirath,Bart J. van Wees,Herre S. J. van der Zant,Luigi Occhipinti,Andrea di Matteo,Ian A. Kinloch,Thomas Seyller,Etienne Quesnel,Xinliang Feng,K.B.K. Teo,Nalin Rupesinghe,Pertti Hakonen,Simon R. T. Neil,Quentin Tannock,Tomas Löfwander,Jari M. Kinaret +68 more
TL;DR: An overview of the key aspects of graphene and related materials, ranging from fundamental research challenges to a variety of applications in a large number of sectors, highlighting the steps necessary to take GRMs from a state of raw potential to a point where they might revolutionize multiple industries are provided.
Journal ArticleDOI
Anomalous thermal conductivity enhancement in nanotube suspensions
TL;DR: In this paper, the authors have produced nanotube-in-oil suspensions and measured their effective thermal conductivity, which is anomalously greater than theoretical predictions and is nonlinear with nanotubes loadings.
References
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Journal ArticleDOI
Self-assembly of tubular fullerenes
Ting Guo,Pavel Nikolaev,Andrew G. Rinzler,David Tománek,Daniel T. Colbert,Richard E. Smalley +5 more
TL;DR: In this article, it was shown that carbon nanotubes self-assemble under homogeneous gas-phase conditions of carbon condensation in an inert atmosphere heated to 1200$DGR@C-conditions previously thought to be optimal only for the annealing and growth of C{sub 60} and other spheroidal shells.
Journal ArticleDOI
Structure, stability, and fragmentation of small carbon clusters
TL;DR: In this article, the structures and energies of small carbon clusters (Cn, n=2-10) were analyzed and the effects of polarization functions and electron correlation were included in these calculations.
Journal ArticleDOI
Structural properties of a carbon-nanotube crystal.
Jerry Tersoff,Rodney S. Ruoff +1 more
TL;DR: The ordered condensed phase of carbon nanotubes is examined, finding that as the tube diameter varies, the structural properties show a clear transition between two regimes with qualitatively different behavior.
Journal ArticleDOI
Large molecules in carbon vapor
TL;DR: In this article, the molecular orbital theory is used in appropriate semi-empirical forms to predict the properties of carbon vapor, and the results indicate that linear polyatomic molecules: C = C =C - - - C = c: are the important species.
Journal ArticleDOI
Growth and sintering of fullerene nanotubes.
Daniel T. Colbert,Jinshui Zhang,S. M. McClure,Pavel Nikolaev,Z. Chen,Jason H. Hafner,D. W. Owens,Paul G. Kotula,C. B. Carter,J. H. Weaver,Andrew G. Rinzler,Richard E. Smalley +11 more
TL;DR: A detailed mechanism that features the high electric field at (and field-emission from) open nanotube tips exposed to the arc plasma, and consequent positive feedback effects from the neutral gas and plasma, is proposed for tube growth in such arcs.