Nagoya Institute of Technology

About: Nagoya Institute of Technology is a education organization based out in Nagoya, Japan. It is known for research contribution in the topics: Thin film & Catalysis. The organization has 10766 authors who have published 19140 publications receiving 255696 citations. The organization is also known as: Nagoya Kōgyō Daigaku & Nitech.

Development of Ruthenium−Hydroxyapatite-Encapsulated Superparamagnetic γ-Fe2O3 Nanocrystallites as an Efficient Oxidation Catalyst by Molecular Oxygen

Abstract: Magnetic γ-Fe2O3 nanocrystallites dispersed in a hydroxyapatite matrix (HAP-γ-Fe2O3) have been synthesized for the first time as a new catalyst support. The cation-exchange ability of the external HAP surface enables an equimolar substitution of Ru for Ca to form a catalytically active center (RuHAP-γ-Fe2O3). Characterization by several spectroscopic methods demonstrated the formation of γ-Fe2O3 nanocrystallites within the HAP matrix having a mean diameter of 8.0 nm (σ = 18.4 A, σ/d = 21.7%). The Ru species was proven to exist in the monomeric form in a highly dispersed manner. The RuHAP-γ-Fe2O3 exhibits superior catalytic activity for the oxidation of various alcohols to the corresponding carbonyl compounds using molecular oxygen as a primary oxidant. The magnetic properties of the RuHAP-γ-Fe2O3 provided a convenient route for separation of the catalyst from the reaction mixture by application of an external permanent magnet. No metal leaching was detected, and the spent catalyst could be recycled withou...

Speaker interpolation for HMM-based speech synthesis system.

Abstract: This paper describes an approach to voice characteristics conversion for an HMM-based text-to-speech synthesis system using speaker interpolation.Although most text-to-speech synthesis systems which synthesize speech by concatenating speech units can synthesize speech with acceptable quality, they still cannot synthesize speech with various voice quality such as speaker individualities and emotions;In order to control speaker individualities and emotions, therefore, they need a large database, which records speech units with various voice characteristics in sythesis phase.On the other hand, our system synthesize speech with untrained speaker’s voice quality by interpolating HMM parameters among some representative speakers’ HMM sets.Accordingly, our system can synthesize speech with various voice quality without large database in synthesis phase.An HMM interpolation technique is derived from a probabilistic similarity measure for HMMs, and used to synthesize speech with untrained speaker’s voice quality by interpolating HMM parameters among some representative speakers’ HMM sets.The results of subjective experiments show that we can gradually change the voice quality of synthesized speech from one’s to the other’s by changing the interpolation ratio.

Effects of coil orientation on the electric field induced by TMS over the hand motor area.

Abstract: Responses elicited by transcranial magnetic stimulation (TMS) over the hand motor area depend on the position and orientation of the stimulating coil. In this work, we computationally investigate the induced electric field for multiple coil orientations and locations in order to determine which parts of the brain are affected and how the sensitivity of motor cortical activation depends on the direction of the electric field. The finite element method is used for calculating the electric field induced by TMS in two individual anatomical models of the head and brain. The orientation of the coil affects both the strength and depth of penetration of the electric field, and the field strongly depends on the direction of the sulcus, where the target neurons are located. The coil position that gives the strongest electric field in the target cortical region may deviate from the closest scalp location by a distance on the order of 1 cm. Together with previous experimental data, the results support the hypothesis that the cortex is most sensitive to fields oriented perpendicular to the cortical layers, while it is relatively insensitive to fields parallel to them. This has important implications for targeting of TMS. To determine the most effective coil position and orientation, it is essential to consider both biological (the direction of the targeted axons) and physical factors (the strength and direction of the electric field).

Creating Elastic Organic Crystals of π-Conjugated Molecules with Bending Mechanofluorochromism and Flexible Optical Waveguide.

Abstract: To create low band-gap, fluorescent, and elastic organic crystal emitters, we focused on an extended π-conjugated system based on: a) a planar conformation,b) a rigid structure, and c) controlled intermolecular interactions. Herein, we report on two fluorescent and highly flexible organic crystals (1 and 2) which could bend under an applied stress. The bent crystals rapidly recover their straight shape upon release of the stress. Crystal 1 with a tetrafluoropyridyl terminal unit and a lower band-gap energy (orange emission, λem =573 nm, ΦF =0.50), showed no bending mechanofluorochromism and had superior performance as an optical waveguide with reddish orange emission. The waveguide performance of the crystal did not decrease under bending stress. For crystal 2 with a pentafluorophenyl terminal unit (green emission, λem =500 nm, ΦF =0.38), the original waveguide performance decreased under an applied bending stress; however, this crystal showed a unique bending mechanofluorochromism.