Nagoya Institute of Technology

About: Nagoya Institute of Technology is a education organization based out in Nagoya, Japan. It is known for research contribution in the topics: Thin film & Catalysis. The organization has 10766 authors who have published 19140 publications receiving 255696 citations. The organization is also known as: Nagoya Kōgyō Daigaku & Nitech.

Electromechanical coupling and gigahertz elastic properties of ScAlN films near phase boundary

Abstract: The electromechanical coupling, elastic properties, and temperature coefficient of elastic constant c33D of ScxAl(1−x)N films with high Sc concentration (x) of 0–0.70 were experimentally investigated. Near the phase boundary, a Sc0.41Al0.59N film exhibited a maximum thickness extensional mode electromechanical coupling coefficient kt2 of 12% (kt = 0.35), which is almost double the value of 6.4% for typical pure AlN films. In the region of 0 < x < 0.2, the electromechanical coupling was confirmed to increase without any detectable deterioration in the temperature stability of c33D (=−54.5 ppm/ °C). This region is favorable in terms of temperature stability and is suitable for wideband resonator filter applications.

In Situ Spectroscopic, Electrochemical, and Theoretical Studies of the Photoinduced Host-Guest Electron Transfer that Precedes Unusual Host-Mediated Alkane Photooxidation

Abstract: In the unusual photooxidation of alkanes within the cavity of a self-assembled M6L4 cage complex (1), the proposed reaction mechanism involves the generation of the host anion radical and guest cation radical via guest-to-host photoinduced electron transfer (PET). In the present study, the postulated host anion radical was elucidated by in situ IR spectroscopy. The difference IR spectrum before and after the irradiation of the clathrate complex 1a⊃(2)4 (2 = adamantane) features a dominant negative peak at ∼1500 cm−1, which is attributed to the decrease in the C═N stretching vibration and thus indicative of the structural change in the triazine core of the cage. Electrochemical measurements and theoretical calculations show the remarkably great electron-accepting ability of the triazine core. These results strongly support the proposal of guest-to-host PET.